Natural rubber/styrene-butadiene rubber blends prepared by solution mixing: Influence of vulcanization temperature using a Semi-EV sulfur curing system on the microstructural properties

Blends of natural rubber (NR) and styrene-butadiene rubber (SBR) were prepared by solution mixing and vulcanized with sulfur and accelerator in a Semi-EV system at 433 K and 443 K in order to study the vulcanization kinetic and the influence of vulcanization temperature on final structure of the blends. The vulcanization kinetic studied through the variation in rheometer curves was analyzed using the Ding and Leonov model, which takes into account the reversion effect during the cure process. The average free nanohole volume and the fractional free volume of samples with different NR/SBR ratio were estimated using positron annihilation lifetime spectroscopy (PALS). Also, the crosslink density was determined by means of swelling tests in a solvent. For all the compounds, a correlation between the free nanohole volume and the delta torque obtained from the respective rheometer curves was established.Fil: Mansilla, Marcela Angela. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto Nacional de Tecnología Industrial. Instituto Nacional de Tecnología Industrial - Caucho; ArgentinaFil: Marzocca, Angel José. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; ArgentinaFil: Macchi, Carlos Eugenio. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; ArgentinaFil: Somoza, Alberto Horacio. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentin

How to design browser security and privacy alerts

Browser security and privacy alerts must be designed to ensure they are of value to the end-user, and communicate risks efficiently. We performed a systematic literature review, producing a list of guidelines from the research. Papers were analysed quantitatively and qualitatively to formulate a comprehensive set of guidelines. Our findings seek to provide developers and designers with guidance as to how to construct security and privacy alerts. We conclude by providing an alert template, highlighting its adherence to the derived guidelines

The LaTeX project: A case study of open-source software

This is a case study of TeX, a typesetting software that was developed by Donald E. Knuth in the late 70's. Released with an open source license, it has become a reference in scientific publishing. TeX is now used to typeset and publish much of the world's scientific literature in physics and mathematics. This case study is part of a wider effort by academics to understand the open-source phenomenon. That development model is similar to the organization of the production of knowledge in academia; there is no set organization with a hierarchy, but free collaboration that is coordinated spontaneously and winds up generating complex products that are the property of all who can understand its functioning. The case study was led by gathering qualitative data via interviews with TeX developers and quantitative data on the TeX community -- the program's code, the software that is part of the TeX distribution, the newsgroups dedicated to the software, and many other indicators of the evolution and activity in that open-source project. The case study is aimed at economists who want to develop models to understand and analyze the open-source phenomenon. It is also geared towards policy-makers who would like to encourage or regulate open- source, and towards open-source developers who wonder what are the efficient strategies to make an open-source project successful.TeX, LaTeX, case study, open source, software, innovation, organisational structure, economic history, knowledge production, knowledge diffusion.

Reflections on the Journal of Cooperatives 1986-2003

The Journal of Cooperatives (formally titled the Journal of Agricultural Cooperation) was published as a print journal from 1986 to 2003. The journal resumed publication as an electronic journal in 2007. This article provides a short history of the journal, analyzes trends in authorship, institution, content, research method and intended audience, and considers issues relating to electronic publication. The journal’s historical and current mission statements are also discussed, and a future thrust for the journal is presented.Cooperative, academic journal, electronic publishing, Teaching/Communication/Extension/Profession,

Solar wind collisional heating

To properly describe heating in weakly collisional turbulent plasmas such as the solar wind, inter-particle collisions should be taken into account. Collisions can convert ordered energy into heat by means of irreversible relaxation towards the thermal equilibrium. Recently, Pezzi et al. (Phys. Rev. Lett., vol. 116, 2016, p. 145001) showed that the plasma collisionality is enhanced by the presence of fine structures in velocity space. Here, the analysis is extended by directly comparing the effects of the fully nonlinear Landau operator and a linearized Landau operator. By focusing on the relaxation towards the equilibrium of an out of equilibrium distribution function in a homogeneous force-free plasma, here it is pointed out that it is significant to retain nonlinearities in the collisional operator to quantify the importance of collisional effects. Although the presence of several characteristic times associated with the dissipation of different phase space structures is recovered in both the cases of the nonlinear and the linearized operators, the influence of these times is different in the two cases. In the linearized operator case, the recovered characteristic times are systematically larger than in the fully nonlinear operator case, this suggesting that fine velocity structures are dissipated slower if nonlinearities are neglected in the collisional operator

Consensus disturbance rejection for Lipschitz nonlinear multi-agent systems with input delay: a DOBC approach

In this paper, a new predictor-based consensus disturbance rejection method is proposed for high-order multi agent systems with Lipschitz nonlinearity and input delay. First, a distributed disturbance observer for consensus control is developed for each agent to estimate the disturbance under the delay constraint. Based on the conventional predictor feedback approach, a non-ideal predictor based control scheme is constructed for each agent by utilizing the estimate of the disturbance and the prediction of the relative state information. Then, rigorous analysis is carried out to ensure that the extra terms associated with disturbances and nonlinear functions are properly considered. Sufficient conditions for the consensus of the multi-agent systems with disturbance rejection are derived based on the analysis in the framework of Lyapunov-Krasovskii functionals. A simulation example is included to demonstrate the performance of the proposed control scheme. (C) 2016 The Franklin Institute. Published by Elsevier Ltd. All rights reserved.National Natural Science Foundation of China [61673034]SCI(E)ARTICLE1,SI298-31535

Anticipation of Tennis Shot Direction from Whole-body Movement: The role of movement amplitude and dynamics

International audienceWhile recent studies indicate that observers are able to use dynamic information to anticipate whole-body actions like tennis shots, it is less clear whether the action's amplitude may also allow for anticipation. We therefore examined the role of movement dynamics and amplitude for the anticipation of tennis shot direction. In a previous study, movement dynamics and amplitude were separated from the kinematics of tennis players' forehand groundstrokes. In the present study, these were manipulated and tennis shots were simulated. Three conditions were created in which shot direction differences were either preserved or removed: Dynamics-Present-Amplitude-Present (DA), Dynamics-Present-Amplitude-Absent (DA), and Dynamics-Absent-Amplitude-Present (DA). Nineteen low-skill and fifteen intermediate-skill tennis players watched the simulated shots and predicted shot direction from movements prior to ball-racket contact only. Percent of correctly predicted shots per condition was measured. On average, both groups' performance was superior when the dynamics were present (the DA and DA conditions) compared to when it was absent (the DA condition). However, the intermediate-skill players performed above chance independent of amplitude differences in shots (i.e., both the DA and DA conditions), whereas the low-skill group only performed above chance when amplitude differences were absent (the DA condition). These results suggest that the movement's dynamics but not their amplitude provides information from which tennis-shot direction can be anticipated. Furthermore, the successful extraction of dynamical information may be hampered by amplitude differences in a skill dependent manner

suppression of dc link voltage unbalance in three level neutral point clamped converters

Abstract Two different control approaches for suppressing DC-link voltage unbalance in Three-Level Neutral-Point Clamped Converters (NPCs) are presented in this paper. They both guarantee DC-link voltage equalization over any NPC operating conditions, i.e. when the NPC feeds or is supplied by the main AC grid at different active and/or reactive power rates. The proposed control approaches consist of either a hysteresis or a proportional regulator, each of which synthesizes the most suitable control action based on the actual DC-link voltage unbalance. Particularly, two different PWM techniques have been developed in order to achieve DC-link voltage equalization successfully, preserving NPC voltage and current waveforms at the same time. The performances achievable by means of both the proposed control approaches have been compared to each other through an extensive simulation study in order to highlight their most important advantages and drawbacks, as well as their effectiveness over any operating conditions. Particularly, both control approaches are validated in the Matlab-Simulink environment referring to DC-link voltage equalization of an NPC that represents the point of common coupling between a DC microgrid and the main AC grid

Quantifying spatial correlations of general quantum dynamics

Understanding the role of correlations in quantum systems is both a fundamental challenge as well as of high practical relevance for the control of multi-particle quantum systems. Whereas a lot of research has been devoted to study the various types of correlations that can be present in the states of quantum systems, in this work we introduce a general and rigorous method to quantify the amount of correlations in the dynamics of quantum systems. Using a resource-theoretical approach, we introduce a suitable quantifier and characterize the properties of correlated dynamics. Furthermore, we benchmark our method by applying it to the paradigmatic case of two atoms weakly coupled to the electromagnetic radiation field, and illustrate its potential use to detect and assess spatial noise correlations in quantum computing architectures