4 research outputs found
The aqueous Triton X-100 â dodecyltrimethylammonium bromidemicellar mixed system. Experimental results and thermodynamic analysis
The micellization process of the aqueous mixed system triton X-100 (TX100) â dodecyltrimethylammonium bromide (DTAB) has been studied with a battery of techniques: surface tension, static and dynamic light scattering and ion-selective electrodes. Results have been also analysed with two thermodynamic procedures: the Regular Solution Theory or Rubingh's model and the recently developed Equation Oriented Mixed Micellization Model (EOMMM). For α DTAB †0.40 (α DTAB : total molar fraction of the system without considering the water), the micelles are predominantly TX100 with scarce solubilized DTA + ions, with TX100 acting as a nearly ideal solvent. In the range 0.50 †α DTAB †0.75, it seems that none of the components acts as a solvent. Above α DTAB â 0.75 there are noticeable changes in the size and electrophoretic mobility of the micelles. These phenomena have been interpreted in the light of the thermodynamic results and literature on some TX100-ionic surfactant mixtures. The case under study is an almost ideal but very asymmetric mixed surfactants system, what is very interesting in view of the very different nature and structures of the components.Fil: Serafini, Patricio. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - BahĂa Blanca. Instituto de FĂsica del Sur. Universidad Nacional del Sur. Departamento de FĂsica. Instituto de FĂsica del Sur; ArgentinaFil: FernĂĄndez Leyes, Marcos Daniel. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - BahĂa Blanca. Instituto de FĂsica del Sur. Universidad Nacional del Sur. Departamento de FĂsica. Instituto de FĂsica del Sur; ArgentinaFil: SĂĄnchez Morales, Jhon Freddy. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - BahĂa Blanca. Instituto de FĂsica del Sur. Universidad Nacional del Sur. Departamento de FĂsica. Instituto de FĂsica del Sur; ArgentinaFil: Pereyra, Romina BelĂ©n. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - BahĂa Blanca. Instituto de QuĂmica del Sur. Universidad Nacional del Sur. Departamento de QuĂmica. Instituto de QuĂmica del Sur; ArgentinaFil: Schulz, Erica Patricia. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - BahĂa Blanca. Instituto de QuĂmica del Sur. Universidad Nacional del Sur. Departamento de QuĂmica. Instituto de QuĂmica del Sur; ArgentinaFil: Durand, Guillermo AndrĂ©s. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - BahĂa Blanca. Planta Piloto de IngenierĂa QuĂmica. Universidad Nacional del Sur. Planta Piloto de IngenierĂa QuĂmica; ArgentinaFil: Schulz, Pablo Carlos. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - BahĂa Blanca. Instituto de QuĂmica del Sur. Universidad Nacional del Sur. Departamento de QuĂmica. Instituto de QuĂmica del Sur; ArgentinaFil: Ritacco, HernĂĄn Alejandro. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - BahĂa Blanca. Instituto de FĂsica del Sur. Universidad Nacional del Sur. Departamento de FĂsica. Instituto de FĂsica del Sur; Argentin
Equation oriented mixed micellization modeling based on asymmetric Margules-type formulations
The determination of the composition of mixed micellar systems is a major problem since only the composition ofthe total micellar solution is accessible to the experimenter. A new approach is introduced in the present work based on Equation Oriented Optimization and Margules asymmetric formulations whichisnot restricted to thenumber of components and guarantees the applicability ofthe GibbsâDuhem relation. The method is validated through its application to systems from literature and the quality of the solutions is tested with already published data and by comparison with other approaches. We do also show how excess properties can be predicted and that the excess entropy is not zero as assumed by the original regular and sub-regular solution theories.Fil: Schulz, Erica Patricia. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - BahĂa Blanca. Instituto de QuĂmica del Sur. Universidad Nacional del Sur. Departamento de QuĂmica. Instituto de QuĂmica del Sur; ArgentinaFil: Durand, Guillermo AndrĂ©s. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - BahĂa Blanca. Planta Piloto de IngenierĂa QuĂmica. Universidad Nacional del Sur. Planta Piloto de IngenierĂa QuĂmica; Argentin
Proceedings of the 10th International Chemical and Biological Engineering Conference - CHEMPOR 2008
This volume contains full papers presented at the 10th International Chemical and Biological
Engineering Conference - CHEMPOR 2008, held in Braga, Portugal, between September 4th and
6th, 2008.FC