Damage Management of Concrete Structures with Engineered Cementitious Materials and Natural Fibers: A Review of Potential Uses

The importance of the safety and sustainability of structures has attracted more attention to the development of smart materials. The presence of small cracks (<300 µm in width) in concrete is approximately inevitable. These cracks surely damage the functionality of structures, increase their degradation, and decrease their sustainability and service life. Self-sensing cement-based materials have been widely assessed in recent decades. Engineers can apply piezoresistivity for structural health monitoring that provides timely monitoring of structures, such as damage detection and reliability analysis, which consequently guarantees the service life with low maintenance costs. However, concrete piezoresistivity is limited to compressive stress sensing due to the brittleness of concrete. In contrast, engineered cementitious composites (ECC) present excellent tensile ductility and deformation capabilities, making them able to sense tensile stress/strain. Therefore, in this paper, first, the ability of ECC to partly replace transverse reinforcements and enhance the joint shear resistance, the energy absorption capacity, and the cracking response of concrete structures in seismic areas is reviewed. Then, the potential use of natural fibers and cellulose nanofibers in cementitious materials is investigated. Moreover, steel and carbon fibers and carbon black, carbon nanotubes, and graphene, all added as conductive fillers, are also presented. Finally, among the conductive carbonaceous materials, biochar, the solid residue of biomass waste pyrolysis, was recently investigated to improve the mechanical properties, internal curing, and CO2 capture of concrete and for the preparation of self-sensing ECC

Epoxy-Based Composites

Epoxy-based composites are used in automotive and aerospace applications because of their high strength-to-weight ratio, high stiffness-to-weight ratio, and good resistance to wear and corrosion. This book presents research on epoxy-based composites and their applications. It explains methods of preparing and testing these composites, including the hand lay-up technique, compression molding, and others. This book is useful for industrialists, undergraduate and postgraduate students, research scholars, and scientists

Advances in the Processing and Application of Polymer and Its Composites

This book mainly focuses on the processing and applications of polymer and its composites. With the fast development of the petroleum industry, polymer materials have been widely utilized in our daily lives. The various processing methods of polymers determine the final properties and performance of products. In addition, the introduction of different fillers, including inorganic fillers, metal oxide, natural fibers, and so on, can increase the physical and chemical properties of polymer composites, which will further broaden their practical applications. Special attention will be paid to the type of processing methods and the functional fillers on the performance of polymer composites

Reinforced Polymer Composites

This book, consisting of 21 articles, including three review papers, written by research groups of experts in the field, considers recent research on reinforced polymer composites. Most of them relate to the fiber-reinforced polymer composites, which are a real hot topic in the field. Depending on the reinforcing fiber nature, such composites are divided into synthetic and natural fiber-reinforced ones. Synthetic fibers, such as carbon, glass, or basalt, provide more stiffness, while natural fibers, such as jute, flax, bamboo, kenaf, and others, are inexpensive and biodegradable, making them environmentally friendly. To acquire the benefits of design flexibility and recycling possibilities, natural reinforcers can be hybridized with small amounts of synthetic fibers to make them more desirable for technical applications. Elaborated composites have great potential as structural materials in automotive, marine and aerospace application, as fire resistant concrete, in bridge systems, as mechanical gear pair, as biomedical materials for dentistry and orthopedic application and tissue engineering, as well as functional materials such as proton-exchange membranes, biodegradable superabsorbent resins and polymer electrolytes

Recent advances and trends of nano-filled/nano-structured epoxies

none2noThis paper aims at reviewing the papers published in the last five years (2016-2020) on polymer nanocomposites based on epoxy resins. The different nano-fillers successfully added to epoxies to enhance some of their characteristics, in relation to the nature and the feature of each nano-filler, are illustrated. The organic-inorganic hybrid nano-structured epoxies are also introduced and their strong potential in many applications have been highlighted. The different methods and routes employed for the production of nano-filled/nano-structured epoxies are described. A discussion of the main properties and final performance, comprised durability, of epoxy nanocomposites, depending on chemical nature, shape and size of nano-particles and on their distribution, is presented. It is also shown why an efficient uniform dispersion of the nano-fillers in the epoxy matrix, along with strong interfacial interactions with the polymeric network, will guarantee the success of the application for which the nanocomposite is proposed. The mechanisms yielding to the improved properties in comparison to the neat polymer are illustrated. The most important applications in which these new materials can better exploit their uniqueness are finally presented, also evidencing the aspects that limit a wider diffusion.openM. Frigione, M. LettieriFrigione, M.; Lettieri, M

High Performance Self-Compacting Cementitious Materials Using Nano/Micro Carbonaceous Inerts

Cementitious materials are commonly and extensively used worldwide by construction industry for various types of infrastructures. Despite of their exceptional strength in compression they still possess limited tensile strength and tensile strain capacity. Different types of fibers have been investigated since last fifty decades to reinforce the cementitious matrix against tensile failures and to impart ductility. The size of the reinforcing fillers has diminished from macro to micro and now even to the nano scale with the recent advancements in nanotechnology. Due to exceptional intrinsic properties and large aspect ratio, carbon nanotubes have been successfully investigated as a reinforcing filler to modify the mechanical strength, fracture toughness, electrical and electromagnetic wave absorbing properties of cementitious composites. However the problems associated with its effective dispersion and bonding with the host material limit its widespread applications on large scale. To overcome the aforementioned issues concerning the dispersion and bonding of nano reinforcing materials with the host matrix, graphene nano sheets were explored for the first time as a reinforcing agent for high performance cementitious matrices. Graphene sheets are free form entanglement problems and therefore need comparatively lesser energy for proper dispersion. Due to very high specific surface area and large aspect ratio in comparison with carbon nanotubes they are much capable to develop strong interfacial bond with the host medium. In the commercialization of these nano carbon particles filled cementitious composites, another major concern would be the related expenses. Therefore in parallel, research work was also done to explore the cost effective alternatives for the production of carbon nano particles to be used for modification or improvement in the properties of cement matrices. In recent wok by Prof. Ferro’s research team it has been explored that carbon nano particles produced from coconut shells can be effectively used to improve the mechanical strength and fracture toughness of cementitious composites with limited dispersion issues (G. Ferro et al. 2014, 2015). To continue with the productive research pertaining the cost effective production of carbon nano particles for high performance cementitious composites, bio-waste in the form of bagasse fibers, hazelnut shell and peanut shell was investigated. These particular types of agricultural wastes were selected keeping in view their economic availability as well as the excellent conversion efficiency via pyrolysis. The present work encompasses complete characterization of the investigated materials, detailed study on their dispersion ability in water and the cement matrix, entire mechanical characterization of reinforced cementitious composites at varying proportions as well as their electromagnetic wave absorption properties in 2-10 GHz frequency range. It was determined that graphene nano-platelets can be uniformly dispersed in water as well as in the cementitious matrix without any addition of separate dispersant or surfactant or stabilizing agent. It was found that even at a very low content of addition remarkable improvements in the mechanical strength and fracture toughness were attained. The optimum content of addition for the grade 4 graphene nano-platelets was found as 0.08 wt% providing with a significant increase of 89% and 29% in compressive and flexure strength along with 115% improved fracture toughness. Similarly the carbonized particles produced for bio-waste were found quite effective in modifying the mechanical performance of cementitious composites. Maximum enhancement by 139% and 88% in flexural and compressive strength were achieved on 0.2 wt % addition of nano/micro carbonized particles produced from peanut shell with an increase of 69% in the fracture toughness as well. Microstructural investigations evidenced the proper homogeneous dispersion of GNPs and NMCPs throughout cementitious matrix along with their efficient filling action to refine the pore-structure of the cementitious composite. The phenomena of crack bridging, crack deflections, crack contouring and crack branching were observed via scanning electron microscopy revealing the mechanism behind the remarkable improvements of mechanical properties achieved in the present research. A novel cost effective material in the form of cement composites containing carbonized agricultural residue (comprising CPS and CHS) was proposed for shielding against electromagnetic waves. The investigated material was found much efficient for electromagnetic interference shielding applications, providing the advantage of better dispersion, simple manufacture at a much lower cost (cost saving ˃ 85%) compared to the corresponding carbon nanotubes based cement composite material

Abstract book for the proceedings of the 2nd International conference on structural nano composites (NANOSTRUC 2014), 20-21 May 2014, Madrid, Spain.

The purpose of the 2nd International Conference on Structural Nano Composites (NANOSTRUC 2014) is to promote activities in various areas of materials and structures by providing a forum for exchange of ideas, presentation of technical achievements and discussion of future directions. NANOSTRUC brings together an international community of experts to discuss the state-of-the-art, new research results, perspectives of future developments, and innovative applications relevant to structural materials, engineering structures, nanocomposites, modelling and simulations, and their related application areas. We would like to acknowledge the hard work, professional skills and efficiency of the team which ensured the general organisation. The nanoparticles and nanocomposites have a wide range of applications in various fields such as medicine, textiles, cosmetics, agriculture, optics, food packaging, optoelectronic devices, semiconductor devices, aerospace, automotive, construction and catalysis. Advancements in the nanotechnology industry promise to offer improvements in capabilities across a spectrum of applications. This is of immense strategic importance to the high performance sector which has historically leveraged technological advances in materials

Advanced Mechanical Modeling of Nanomaterials and Nanostructures

This reprint presents a collection of contributions on the application of high-performing computational strategies and enhanced theoretical formulations to solve a wide variety of linear or nonlinear problems in a multiphysical sense, together with different experimental studies

Polymeric Foams

Postprint (published version