A numerical study on the design trade-offs of a thin-film thermoelectric generator for large-area applications

Thin-film thermoelectric generators with a novel folding scheme are proposed for large-area, low energy-density applications. Both the electrical current and heat transfer are in the plane of the thermoelectric thin-film, yet the heat transfer is across the plane of the module - similar to conventional bulk thermoelectric modules. With such designs, the heat leakage through the module itself can be minimized and the available temperature gradient maximized. Different from the previously reported corrugated thermoelectric generators, the proposed folding scheme enables high packing densities without compromising the thermal contact area to the heat source and sink. The significance of various thermal transport, or leakage, mechanisms in relation to power production is demonstrated for different packing densities and thicknesses of the module under heat sink-limited conditions. It is shown that the power factor is more important than ZT for predicting the power output of such thin-film devices. As very thin thermoelectric films are employed with modest temperature gradients, high aspect-ratio elements are needed to meet the - usually ignored - requirements of practical applications for the current. With the design trade-offs considered, the proposed devices may enable the exploitation of thermoelectric energy harvesting in new - large-area - applications at reasonable cost.Comment: 26 pages,5 figures, post-peer-review, pre-copyedit version of an article published in Renewable Energ

Low-profile and wearable energy harvester based on plucked piezoelectric cantilevers

The Pizzicato Energy Harvester (EH) introduced the technique of frequency up-conversion to piezoelectric EHs wearable on the lateral side of the knee-joint. The operation principle is to pluck the piezoelectric bimorphs with plectra so that they produce electrical energy during the ensuing mechanical vibrations. The device presented in this work is, in some ways, an evolution of the earlier Pizzicato: it is a significantly more compact and lighter device; the central hub holds 16 piezoelectric bimorphs shaped as trapezoids, which permits a sleek design and potentially increased energy output for the same bimorph area. Plectra were formed by Photochemical Machining of a 100-μm-thick steel sheet. To avoid the risk of short-circuiting, the plectra were electrically passivated by sputtering a 100 nm layer of ZrO2. Bench tests with the steel plectra showed a very large energy generation. Polyimide plectra were also manufactured with a cutting plotter from a 125μm-thick film. Besides bench tests, a volunteer wore the device while walking on flat ground or climbing stairs, with a measured energy output of approximately 0.8 mJ per step. Whereas most of the tests were performed by the traditional method of discharging the rectified output from the EH onto a resistive load, tests were performed also with a circuit offering a stabilised 3.3 V supply. The circuit produced a stable 0.1 mA supply during running gait with kapton plectra

Printable magnesium ion quasi-solid-state asymmetric supercapacitors for flexible solar-charging integrated units.

Wearable and portable self-powered units have stimulated considerable attention in both the scientific and technological realms. However, their innovative development is still limited by inefficient bulky connections between functional modules, incompatible energy storage systems with poor cycling stability, and real safety concerns. Herein, we demonstrate a flexible solar-charging integrated unit based on the design of printed magnesium ion aqueous asymmetric supercapacitors. This power unit exhibits excellent mechanical robustness, high photo-charging cycling stability (98.7% capacitance retention after 100 cycles), excellent overall energy conversion and storage efficiency (ηoverall = 17.57%), and outstanding input current tolerance. In addition, the Mg ion quasi-solid-state asymmetric supercapacitors show high energy density up to 13.1 mWh cm-3 via pseudocapacitive ion storage as investigated by an operando X-ray diffraction technique. The findings pave a practical route toward the design of future self-powered systems affording favorable safety, long life, and high energy

Design and Fabrication of 3D Electrostatic Energy Harvester

This paper discusses the design of an electrostatic generator, power supply component of the self-powered microsystem, which is able to provide enough energy to power smart sensor chains or if necessary also other electronic monitoring devices. One of the requirements for this analyzer is the mobility, so designing the power supply expects use of an alternative way of getting electricity to power the device, rather than rely on periodic supply of external energy in the form of charging batteries, etc. In this case the most suitable method to use is so-called energy harvesting – a way how to gather energy. This uses the principle of non-electric conversion of energy into electrical energy in the form of converters. The present study describes the topology design of such structures of electrostatic generator. Structure is designed and modeled as a three-dimensional silicon based MEMS. Innovative approach involving the achievement of very low resonant frequency of the structure, while the minimum area of the chip, the ability to work in all 3 axes of coordinate system and ability to be tuned to reach desired parameters proves promising directions of possible further development of this issue. The work includes simulation of electro-mechanical and electrical properties of the structure, description of its behavior in different operating modes and phases of activity. Simulation results were compared with measured values of the produced prototype chip. These results can suggest possible modifications to the proposed structure for further optimization and application environment adaptation

A Flexible PMN-PT Ribbon-Based Piezoelectric-Pyroelectric Hybrid Generator for Human-Activity Energy Harvesting and Monitoring

The rapid advancements of wearable electronics require continued innovation in sustainable power sources and human interactive sensors. An abundance of energy in various forms, such as mechanical, thermal, optical, and sound, are ubiquitous in the environment and human activities. Hybrid generators using piezoelectric polymers with relatively low piezoelectric and pyroelectric constants have been fabricated to simultaneously scavenge mechanical and thermal energies. In this work, micropatterned single-crystal (1-x)Pb(Mg,Nb)O3-xPbTiO3 (PMN-PT) ribbons, which possess excellent piezoelectric and pyroelectric properties, are utilized to build human activities energy harvesting and monitoring systems. The flexible PMN-PT ribbon-based sensor conformally attached on the surface of human skin enables high sensitivity for human body motions and can detect acoustic sounds precisely. The sensor has been used for monitoring temperature-related activities, caused for instance by warm water flow and even light illumination. The multifunctional performance of the PMN-PT ribbon-based hybrid generator shows great potential for self-powered wearable and human activities monitoring devices. This is the peer reviewed version of the following article: Chen, Y. et al.: A Flexible PMN-PT Ribbon-Based Piezoelectric-Pyroelectric Hybrid Generator for Human-Activity Energy Harvesting and Monitoring. In: Advanced Electronic Materials (2017), which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/aelm.201600540/abstract. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.DFG/DI 2013/2-1BMBF/Q.Com-H/16KIS010

Printing and Folding:A Solution for High-Throughput Processing of Organic Thin-Film Thermoelectric Devices

Wearable electronics are rapidly expanding, especially in applications like health monitoring through medical sensors and body area networks (BANs). Thermoelectric generators (TEGs) have been the main candidate among the different types of energy harvesting methods for body-mounted or even implantable sensors. Introducing new semiconductor materials like organic thermoelectric materials and advancing manufacturing techniques are paving the way to overcome the barriers associated with the bulky and inflexible nature of the common TEGs and are making it possible to fabricate flexible and biocompatible modules. Yet, the lower efficiency of these materials in comparison with bulk-inorganic counterparts as well as applying them mostly in the form of thin layers on flexible substrates limits their applications. This research aims to improve the functionality of thin and flexible organic thermoelectric generators (OTEs) by utilizing a novel design concept inspired by origami. The effects of critical geometric parameters are investigated using COMSOL Multiphysics to further prove the concept of printing and folding as an approach for the system level optimization of printed thin film TEGs

Kirigami-Inspired Organic and Inorganic Film-Based Flexible Thermoelectric Devices with Built-In Heat Sink

Thermoelectric (TE) devices can convert heat to electricity directly, which offers a unique opportunity to realize waste heat recovery. However, conventional TE devices inevitably use heat sinks, which are bulky, rigid and heavy, limiting practical applications. Herein, we propose a fully integrated film-based TE device with intrinsically built-in fins as heat sink in a hexagonal honeycomb device structure, that simultaneously achieves high TE performance and conformability, as confirmed by experiments and modelling. A flexible Kapton substrate with copper electrodes, integrating either carbon nanotube (CNT) veils or bismuth telluride (Bi2Te3) TE ‘legs’, both of n- and p-type, achieved a remarkable specific power of 185.4 nW K−2 for a Bi2Te3-based device and 53.1 nW K−2 for a CNT-based device, thanks to the heat dissipation effect granted by the built-in fins. Besides, the addition of oriented polymer films interconnects, contracting when above their glass transition temperature, allowed a single substrate two-dimensional (2D) TE device to self-fold into a three-dimensional (3D) hexagonal honeycomb structure, with built-in fins, contactlessly and autonomously. The demonstrated shape-programmed kirigami-inspired scalable TE device paves the way for realising self-powered applications comprising hundreds of TE legs with both inorganic (e.g., Bi2Te3) and organic (e.g. CNT veils) TE materials and integrated heat sinks

Construction of membrane-bound artificial cells using microfluidics: a new frontier in bottom-up synthetic biology

The quest to construct artificial cells from the bottom-up using simple building blocks has received much attention over recent decades and is one of the grand challenges in synthetic biology. Cell mimics that are encapsulated by lipid membranes are a particularly powerful class of artificial cells due to their biocompatibility and the ability to reconstitute biological machinery within them. One of the key obstacles in the field centres on the following: how can membrane-based artificial cells be generated in a controlled way and in high-throughput? In particular, how can they be constructed to have precisely defined parameters including size, biomolecular composition and spatial organization? Microfluidic generation strategies have proved instrumental in addressing these questions. This article will outline some of the major principles underpinning membrane-based artificial cells and their construction using microfluidics, and will detail some recent landmarks that have been achieved