Inversion of inherent optical properties in optically complex waters using sentinel-3A/OLCI images: A case study using China\u27s three largest freshwater lakes

Inherent optical properties (IOPs) play an important role in underwater light field, and are difficult to estimate accurately using satellite data in optically complex waters. To study water quality in appropriate temporal and spatial scales, it is necessary to develop methods to obtain IOPs form space-based observation with quantified uncertainties. Field-measured IOP data (N = 405) were collected from 17 surveys between 2011 and 2017 in the three major largest freshwater lakes of China (Lake Chaohu, Lake Taihu, and Lake Hongze) in the lower reaches of the Yangtze River and Huai River (LYHR). Here we provide a case-study on how to use in-situ observation of IOPs to devise an improved algorithm for retrieval of IOPs. We then apply this algorithm to observation with Sentinel-3A OLCI (Ocean and Land Colour Instrument, corrected with our improved AC scheme), and use in-situ data to show that the algorithm performs better than the standard OLCI IOP product. We use the satellite derived products to study the spatial and seasonal distributions of IOPs and concentrations of optically active constituents in these three lakes, including chlorophyll-a (Chla) and suspended particulate matter (SPM), using all cloud-free OLCI images (115 scenes) over the lakes in the LYHR basin in 2017. Our study provides a strategy for using local and remote observations to obtain important water quality parameters necessary to manage resources such as reservoirs, lakes and coastal waters

Modeling Atmosphere-Ocean Radiative Transfer: A PACE Mission Perspective

The research frontiers of radiative transfer (RT) in coupled atmosphere-ocean systems are explored to enable new science and specifically to support the upcoming Plankton, Aerosol, Cloud ocean Ecosystem (PACE) satellite mission. Given (i) the multitude of atmospheric and oceanic constituents at any given moment that each exhibits a large variety of physical and chemical properties and (ii) the diversity of light-matter interactions (scattering, absorption, and emission), tackling all outstanding RT aspects related to interpreting and/or simulating light reflected by atmosphere-ocean systems becomes impossible. Instead, we focus on both theoretical and experimental studies of RT topics important to the science threshold and goal questions of the PACE mission and the measurement capabilities of its instruments. We differentiate between (a) forward (FWD) RT studies that focus mainly on sensitivity to influencing variables and/or simulating data sets, and (b) inverse (INV) RT studies that also involve the retrieval of atmosphere and ocean parameters. Our topics cover (1) the ocean (i.e., water body): absorption and elastic/inelastic scattering by pure water (FWD RT) and models for scattering and absorption by particulates (FWD RT and INV RT); (2) the air-water interface: variations in ocean surface refractive index (INV RT) and in whitecap reflectance (INV RT); (3) the atmosphere: polarimetric and/or hyperspectral remote sensing of aerosols (INV RT) and of gases (FWD RT); and (4) atmosphere-ocean systems: benchmark comparisons, impact of the Earth's sphericity and adjacency effects on space-borne observations, and scattering in the ultraviolet regime (FWD RT). We provide for each topic a summary of past relevant (heritage) work, followed by a discussion (for unresolved questions) and RT updates

Modeling Atmosphere-Ocean Radiative Transfer: A PACE Mission Perspective

The research frontiers of radiative transfer (RT) in coupled atmosphere-ocean systems are explored to enable new science and specifically to support the upcoming Plankton, Aerosol, Cloud ocean Ecosystem (PACE) satellite mission. Given (i) the multitude of atmospheric and oceanic constituents at any given moment that each exhibits a large variety of physical and chemical properties and (ii) the diversity of light-matter interactions (scattering, absorption, and emission), tackling all outstanding RT aspects related to interpreting and/or simulating light reflected by atmosphere-ocean systems becomes impossible. Instead, we focus on both theoretical and experimental studies of RT topics important to the science threshold and goal questions of the PACE mission and the measurement capabilities of its instruments. We differentiate between (a) forward (FWD) RT studies that focus mainly on sensitivity to influencing variables and/or simulating data sets, and (b) inverse (INV) RT studies that also involve the retrieval of atmosphere and ocean parameters. Our topics cover (1) the ocean (i.e., water body): absorption and elastic/inelastic scattering by pure water (FWD RT) and models for scattering and absorption by particulates (FWD RT and INV RT); (2) the air-water interface: variations in ocean surface refractive index (INV RT) and in whitecap reflectance (INV RT); (3) the atmosphere: polarimetric and/or hyperspectral remote sensing of aerosols (INV RT) and of gases (FWD RT); and (4) atmosphere-ocean systems: benchmark comparisons, impact of the Earth’s sphericity and adjacency effects on space-borne observations, and scattering in the ultraviolet regime (FWD RT). We provide for each topic a summary of past relevant (heritage) work, followed by a discussion (for unresolved questions) and RT updates

Modeling atmosphere-ocean radiative transfer: A PACE mission perspective

The research frontiers of radiative transfer (RT) in coupled atmosphere-ocean systems are explored to enable new science and specifically to support the upcoming Plankton, Aerosol, Cloud ocean Ecosystem (PACE) satellite mission. Given (i) the multitude of atmospheric and oceanic constituents at any given moment that each exhibits a large variety of physical and chemical properties and (ii) the diversity of light-matter interactions (scattering, absorption, and emission), tackling all outstanding RT aspects related to interpreting and/or simulating light reflected by atmosphere-ocean systems becomes impossible. Instead, we focus on both theoretical and experimental studies of RT topics important to the science threshold and goal questions of the PACE mission and the measurement capabilities of its instruments. We differentiate between (a) forward (FWD) RT studies that focus mainly on sensitivity to influencing variables and/or simulating data sets, and (b) inverse (INV) RT studies that also involve the retrieval of atmosphere and ocean parameters. Our topics cover (1) the ocean (i.e., water body): absorption and elastic/inelastic scattering by pure water (FWD RT) and models for scattering and absorption by particulates (FWD RT and INV RT); (2) the air-water interface: variations in ocean surface refractive index (INV RT) and in whitecap reflectance (INV RT); (3) the atmosphere: polarimetric and/or hyperspectral remote sensing of aerosols (INV RT) and of gases (FWD RT); and (4) atmosphere-ocean systems: benchmark comparisons, impact of the Earth’s sphericity and adjacency effects on space-borne observations, and scattering in the ultraviolet regime (FWD RT). We provide for each topic a summary of past relevant (heritage) work, followed by a discussion (for unresolved questions) and RT updates

Monte Carlo simulation of light propagation in stratified water

Master'sMASTER OF SCIENC

Bayesian Methodology for Ocean Color Remote Sensing

66 pagesThe inverse ocean color problem, i.e., the retrieval of marine reflectance from top-of-atmosphere (TOA) reflectance, is examined in a Bayesian context. The solution is expressed as a probability distribution that measures the likelihood of encountering specific values of the marine reflectance given the observed TOA reflectance. This conditional distribution, the posterior distribution, allows the construction of reliable multi-dimensional confidence domains of the retrieved marine reflectance. The expectation and covariance of the posterior distribution are computed, which gives for each pixel an estimate of the marine reflectance and a measure of its uncertainty. Situations for which forward model and observation are incompatible are also identified. Prior distributions of the forward model parameters that are suitable for use at the global scale, as well as a noise model, are determined. Partition-based models are defined and implemented for SeaWiFS, to approximate numerically the expectation and covariance. The ill-posed nature of the inverse problem is illustrated, indicating that a large set of ocean and atmospheric states, or pre-images, may correspond to very close values of the satellite signal. Theoretical performance is good globally, i.e., on average over all the geometric and geophysical situations considered, with negligible biases and standard deviation decreasing from 0.004 at 412 nm to 0.001 at 670 nm. Errors are smaller for geometries that avoid Sun glint and minimize air mass and aerosol influence, and for small aerosol optical thickness and maritime aerosols. The estimated uncertainty is consistent with the inversion error. The theoretical concepts and inverse models are applied to actual SeaWiFS imagery, and comparisons are made with estimates from the SeaDAS standard atmospheric correction algorithm and in situ measurements. The Bayesian and SeaDAS marine reflectance fields exhibit resemblance in patterns of variability, but the Bayesian imagery is less noisy and characterized by different spatial de-correlation scales, with more realistic values in the presence of absorbing aerosols. Experimental errors obtained from match-up data are similar to the theoretical errors determined from simulated data. Regionalization of the inverse models is a natural development to improve retrieval accuracy, for example by including explicit knowledge of the space and time variability of atmospheric variables

CHARACTERIZING CDOM SPECTRAL VARIABILITY FROM SEAS TO SPACE

Colored dissolved organic matter (CDOM) absorption varies significantly across the global oceans, presumably due to differences in source and degradation pathways. Tracking this variability on a global, or even regional, scale requires broad temporal and spatial sampling at high frequency. Satellite remote sensing provides this platform; however, current and near future sensors are/will be limited to measurements within the UV and visible wavelengths (\u3e 350 nm) while most optical proxies estimating CDOM composition, and relevant for understanding largescale biogeochemical processes, use wavelengths less than 350 nm. This dissertation examines global variability in CDOM spectral variability utilizing a variety of optical metrics. After assessing global variability in these optical metrics, we considered the ability to observe changes in remotely-sensed reflectance (Rrs(l)) strictly due to Sg variability. Using the radiative transfer software, HydroLight, and data from Lake Superior, modeled Rrs(l) showed that Sg variability significantly alters Rrs(l) in waters where ag(l) contributes \u3e20% to total non-water absorption (at-w(l)) at 440 nm. Based on the proposed signal-to-noise ratio of NASA’s proposed Plankton, Aerosol, Cloud and ocean Ecosystem (PACE) hyperspectral sensor, Sg variability on the order of 0.001 nm-1 is an observable feature in these waters. We then developed an capable of estimating Sdg free of bias on hyperspectral absorption data. The algorithm shows that the increased spectral resolution of hyperspectral sensors should allow for remote estimation of Sdg and potentially Sg, providing a broad view of biogeochemical variability reflected by Sg

Summaries of the Sixth Annual JPL Airborne Earth Science Workshop

This publication contains the summaries for the Sixth Annual JPL Airborne Earth Science Workshop, held in Pasadena, California, on March 4-8, 1996. The main workshop is divided into two smaller workshops as follows: (1) The Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) workshop, on March 4-6. The summaries for this workshop appear in Volume 1; (2) The Airborne Synthetic Aperture Radar (AIRSAR) workshop, on March 6-8. The summaries for this workshop appear in Volume 2

Remote sensing of chlorophyll-a in small inland waters

Small inland waters (SIWs) – waterbodies smaller than 100 km2 – are the predominant form of lakes globally, yet they are highly subject to water quality degradation, especially due to harmful algae blooms (HABs). Space-borne remote sensing has proven its capability to detect and map HABs in coastal waters as well as large waterbodies mostly through estimating chlorophyll-a (Chla). However, remote retrieval of near-surface Chla concentration in SIWs is challenging due to adjacency effects in remotely sensed signals and substantial in situ optical interferences of various water constituents. Although various algorithms have been developed or adapted to estimate Chla from moderate-resolution terrestrial missions (~ 10 – 60 m), there remains a need for robust algorithms to retrieve Chla in SIWs. Here, we introduce and evaluate new approaches to retrieve Chla in small lakes in a large lake catchment using Sentinel-2 and Landsat-8 imagery. In situ Chla data used in this study originate from various sources with contrasting measurement methods, ranging from field fluorometry to high-performance liquid chromatography (HPLC). Our analysis revealed that in vivo Chla measurements are not consistent with in vitro measurements, especially in high Chla amounts, and should be calibrated before being fed into retrieval models. Calibrated models based on phycocyanin (PC) fluorescence and environmental factors, such as turbidity, significantly decreased Chla retrieval error and increased the range of reconstructed Chla values. The proposed calibration models were then employed to build a consistent dataset of in situ Chla for Buffalo Pound Lake (BPL) – 30 km length and 1 km width – in the Qu’Appelle River drainage basin, Saskatchewan, Canada. Using this dataset for training and test, support vector regression (SVR) models were developed and reliably retrieved Chla in BPL. SVR models outperformed well-known commonly used retrieval models, namely ocean color (OC3), 2band, 3band, normalized difference chlorophyll index (NDCI), and mixture density networks (MDN) when applied on ~200 matchups extracted from atmospherically-corrected Sentinel-2 data. SVR models also performed well when applied to Landsat-8 data and data processed through various atmospheric correction (AC) processors. The proposed models also suggested good transferability over two optical water types (OWTs) found in BPL. Based on prior evaluations of the models’ transferability over OWTs in BPL, locally trained machine-learning (ML) models were extrapolated for regional retrieval of Chla in the Qu’Appelle River drainage basin. The regional approach was trained on in situ Chla data from BPL and retrieved Chla in other six lakes in the drainage basin. The proposed regional approach outperformed a recently developed global approach (MDN) in terms of accuracy, and showed more applicability than local models given the scarcity of in situ data in most lakes. In addition, ML models, e.g., SVR, performed consistently better than other models when employed in the regional approach. A rare phenomenon of marked blue discoloration of ice and water in winter 2021 in Pasqua Lake, a small lake in Qu’Appelle Watershed, provided an opportunity to assess the regional approaches in estimating chlorophyll-a for waterbodies where enough training data is not available. Therefore, using a developed model based on data from BPL, we produced Chla maps and could successfully relate the discoloration event to a late fall bloom in Pasqua Lake. We included the details of that study in Appendix A. Altogether, the models and approaches introduced in this thesis can serve as first steps toward developing a remote-sensing-based early warning system for monitoring HABs in small inland waters. Results showed that the development of an early warning system for SIWs based on Chla monitoring is currently possible, thanks to advancements in medium-resolution satellite sensors, in situ data collection methods, and machine learning algorithms. However, further steps need to be taken to improve the accuracy and reliability of systems: (a) in situ data need to be consistent for being fed into remote sensing models, (b) retrieval models and AC processors should be improved to provide better estimations of Chla, and (c) regional approaches might be developed as alternatives for local and global approaches in the absence of accurate AC processors and scarcity of in situ Chla data