3,226 research outputs found

    Chemical Self Assembly of Graphene Sheets

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    Chemically derived graphene sheets were found to self-assemble onto patterned gold structures via electrostatic interactions between noncovalent functional groups on GS and gold. This afforded regular arrays of single graphene sheets on large substrates, characterized by scanning electron and Auger microscopy imaging and Raman spectroscopy. Self assembly was used for the first time to produce on-substrate and fully-suspended graphene electrical devices. Molecular coatings on the GS were removed by high current electrical annealing, which recovered the high electrical conductance and Dirac point of the GS. Molecular sensors for highly sensitive gas detections are demonstrated with self-assembled GS devices.Comment: Nano Research, in press, http://www.thenanoresearch.co

    Charge-Reversal Instability in Mixed Bilayer Vesicles

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    Bilayer vesicles form readily from mixtures of charged and neutral surfactants. When such a mixed vesicle binds an oppositely-charged object, its membrane partially demixes: the adhesion zone recruits more charged surfactants from the rest of the membrane. Given an unlimited supply of adhering objects one might expect the vesicle to remain attractive until it was completely covered. Contrary to this expectation, we show that a vesicle can instead exhibit {\it adhesion saturation,} partitioning spontaneously into an attractive zone with definite area fraction, and a repulsive zone. The latter zone rejects additional incoming objects because counterions on the interior of the vesicle migrate there, effectively reversing the membrane's charge. The effect is strongest at high surface charge densities, low ionic strength, and with thin, impermeable membranes. Adhesion saturation in such a situation has recently been observed experimentally [H. Aranda-Espinoza {\it et al.}, {\sl Science} {\bf285} 394--397 (1999)]

    Flexural phonon scattering induced by electrostatic gating in graphene

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    Graphene has an extremely high carrier mobility partly due to its planar mirror symmetry inhibiting scattering by the highly occupied acoustic flexural phonons. Electrostatic gating of a graphene device can break the planar mirror symmetry yielding a coupling mechanism to the flexural phonons. We examine the effect of the gate-induced one-phonon scattering on the mobility for several gate geometries and dielectric environments using first-principles calculations based on density functional theory (DFT) and the Boltzmann equation. We demonstrate that this scattering mechanism can be a mobility-limiting factor, and show how the carrier density and temperature scaling of the mobility depends on the electrostatic environment. Our findings may explain the high deformation potential for in-plane acoustic phonons extracted from experiments and furthermore suggest a direct relation between device symmetry and resulting mobility.Comment: Accepted at Physical Review Letter

    Thermal noise limitations to force measurements with torsion pendulums: Applications to the measurement of the Casimir force and its thermal correction

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    A general analysis of thermal noise in torsion pendulums is presented. The specific case where the torsion angle is kept fixed by electronic feedback is analyzed. This analysis is applied to a recent experiment that employed a torsion pendulum to measure the Casimir force. The ultimate limit to the distance at which the Casimir force can be measured to high accuracy is discussed, and in particular the prospects for measuring the thermal correction are elaborated upon.Comment: one figure, five pages, to be submitted to Phys Rev

    Research and development of miniaturized electrets

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    A description is given of the realization of small electrets, using techniques generally applied in the fabrication of integrated circuits and microsensors. Attention is paid to the different electret decay mechanisms and their relative contributions to the overall stability of miniaturized electrets. A process is described by which polymer electrets such as Teflon-FEP and PTFE (polytetrafluoroethylene) can be deposited and shaped in a predefined pattern on a silicon wafer. Results on the application of new materials, especially silicon dioxide (SiO2), for use in electret applications, are presented. It appears that after an appropriate treatment of the oxide surface, its charge-stability is at least equal to that of polymer electrets such as Teflon-FEP and PTF

    Measuring the Dispersion Forces Near the van der Waals-Casimir Transition

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    Forces induced by quantum fluctuations of the electromagnetic field control adhesion phenomena between rough solids when the bodies are separated by distances of approximately 10 nm. However, this distance range remains largely unexplored experimentally in contrast with the shorter (van der Waals forces) or the longer (Casimir forces) separations. The reason for this is the pull-in instability of the systems with the elastic suspension that poses a formidable limitation. In this paper we propose a genuine experimental configuration that does not suffer from the short distance instability. The method is based on the adhered cantilever, whose shape is sensitive to the forces acting near the adhered end. The general principle of the method, its possible realization, and feasibility are extensively discussed. The dimensions of the cantilever are determined by the maximum sensitivity to the forces. If the adhesion is defined by strong capillary or chemical interactions, the method loses its sensitivity. Special discussion is presented for the determination of the minimum distance between the rough solids upon contact, and for the compensation of the residual electrostatic contribution. The proposed method can be applied to any kind of solids (metals, semiconductors, or dielectrics) and to any intervening medium (gas or liquid).</p
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