2 research outputs found

    Electrochemical Determination of Glycoalkaloids Using a Carbon Nanotubes-Phenylboronic Acid Modified Glassy Carbon Electrode

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    A versatile strategy for electrochemical determination of glycoalkaloids (GAs) was developed by using a carbon nanotubes-phenylboronic acid (CNTs-PBA) modified glassy carbon electrode. PBA reacts with α-solanine and α-chaconine to form a cyclic ester, which could be utilized to detect GAs. This method allowed GA detection from 1 μM to 28 μM and the detection limit was 0.3 μM. Affinity interaction of GAs and immobilized PBA caused an essential change of the peak current. The CNT-PBA modified electrodes were sensitive for detection of GAs, and the peak current values were in quite good agreement with those measured by the sensors

    DEFINITION OF AN ADVANCED PROCESS FOR THE PRODUCTION OF LOW ENVIRONMENTAL IMPACT CONTAINERS AS POTENTIAL ALTERNATIVE TO PLASTICS

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    For decades, petroleum-based synthetic polymers, commonly known as plastics, have become one of the most appealing materials used for a wide variety of applications. Nevertheless, currently, conventional petroleum-based plastics represent a serious problem for global pollution because remain for hundreds of years in the environment when discarded. In order to reduce dependence on fossil resources, bioplastic materials are being proposed as safer and more sustainable alternatives. Bioplastics are bio-based and/or biodegradable materials, typically derived from renewable sources. Among different resources, food waste is attracting more and more attention in the research field of bioplastics’ production. The sources of food waste include household, commercial, industrial and agricultural residues. In fact, every year, around one-third of all food resources produced for human consumption are lost or wasted. Although European Union guidelines stated that food waste should preferentially be used as animal feed, in some cases, it became illegal because of disease control concerns and other times its nutritional value is very poor. On the other hand, the production of bioplastics from food waste is a renewable, sustainable process, in which materials are fabricated from carbon neutral resources, thus aligning itself with the principles of the circular bioeconomy. However, the conversion of fruit and vegetable by-products into eco-friendly materials with mechanical and hydrodynamic performances comparable to those of fuel-based plastics still remains a challenge. In this thesis, different approaches have been investigated for the valorization of fruit and vegetable wastes to produce low environmental impact materials, as a potential alternative to plastics with application in the field of food packaging. In the first section, apple waste and tomato peel by-products have been used as fillers to fabricate starch-based biocomposites. The mechanical characterization of the samples showed their suitability for covering purposes, since a ductile and soft behaviour was exhibited. In the second section, an avocado by-product extract has been incorporated to an ethyl cellulose matrix for the production of impregnated paper with enhanced durability. Since fruit wastes can contain potential pathogens and physical and chemical contaminants which can be released when used as additive for active packaging, a preliminary untargeted metabolomic characterization of the extract was conducted by LC-ESI(-)-Q Exactive-Orbitrap- MS/MS. The lipid components detected in the extract proved to be useful additives to improve paper hydrophobicity, preventing food browning and moisture loss. In general, the addition of all tested wastes (apple waste, tomato peel and avocado by-products) has proved to be useful to increase the biodegradability of the fabricated biomaterials. Hence, the environmental benefits associated with their recovery are proposed as a driving force to expand their further use for these purposes. The upcycling of food waste through the production of value-added products is an ideal and practical end use, allowing to save huge economic and energy losses
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