595 research outputs found
Efficient ab initio auxiliary-field quantum Monte Carlo calculations in Gaussian bases via low-rank tensor decomposition
We describe an algorithm to reduce the cost of auxiliary-field quantum Monte
Carlo (AFQMC) calculations for the electronic structure problem. The technique
uses a nested low-rank factorization of the electron repulsion integral (ERI).
While the cost of conventional AFQMC calculations in Gaussian bases scales as
where is the size of the basis, we show that
ground-state energies can be computed through tensor decomposition with reduced
memory requirements and sub-quartic scaling. The algorithm is applied to
hydrogen chains and square grids, water clusters, and hexagonal BN. In all
cases we observe significant memory savings and, for larger systems, reduced,
sub-quartic simulation time.Comment: 14 pages, 13 figures, expanded dataset and tex
Tensor Numerical Methods in Quantum Chemistry: from Hartree-Fock Energy to Excited States
We resume the recent successes of the grid-based tensor numerical methods and
discuss their prospects in real-space electronic structure calculations. These
methods, based on the low-rank representation of the multidimensional functions
and integral operators, led to entirely grid-based tensor-structured 3D
Hartree-Fock eigenvalue solver. It benefits from tensor calculation of the core
Hamiltonian and two-electron integrals (TEI) in complexity using
the rank-structured approximation of basis functions, electron densities and
convolution integral operators all represented on 3D
Cartesian grids. The algorithm for calculating TEI tensor in a form of the
Cholesky decomposition is based on multiple factorizations using algebraic 1D
``density fitting`` scheme. The basis functions are not restricted to separable
Gaussians, since the analytical integration is substituted by high-precision
tensor-structured numerical quadratures. The tensor approaches to
post-Hartree-Fock calculations for the MP2 energy correction and for the
Bethe-Salpeter excited states, based on using low-rank factorizations and the
reduced basis method, were recently introduced. Another direction is related to
the recent attempts to develop a tensor-based Hartree-Fock numerical scheme for
finite lattice-structured systems, where one of the numerical challenges is the
summation of electrostatic potentials of a large number of nuclei. The 3D
grid-based tensor method for calculation of a potential sum on a lattice manifests the linear in computational work, ,
instead of the usual scaling by the Ewald-type approaches
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Preparing sparse solvers for exascale computing.
Sparse solvers provide essential functionality for a wide variety of scientific applications. Highly parallel sparse solvers are essential for continuing advances in high-fidelity, multi-physics and multi-scale simulations, especially as we target exascale platforms. This paper describes the challenges, strategies and progress of the US Department of Energy Exascale Computing project towards providing sparse solvers for exascale computing platforms. We address the demands of systems with thousands of high-performance node devices where exposing concurrency, hiding latency and creating alternative algorithms become essential. The efforts described here are works in progress, highlighting current success and upcoming challenges. This article is part of a discussion meeting issue 'Numerical algorithms for high-performance computational science'
Conic Optimization Theory: Convexification Techniques and Numerical Algorithms
Optimization is at the core of control theory and appears in several areas of
this field, such as optimal control, distributed control, system
identification, robust control, state estimation, model predictive control and
dynamic programming. The recent advances in various topics of modern
optimization have also been revamping the area of machine learning. Motivated
by the crucial role of optimization theory in the design, analysis, control and
operation of real-world systems, this tutorial paper offers a detailed overview
of some major advances in this area, namely conic optimization and its emerging
applications. First, we discuss the importance of conic optimization in
different areas. Then, we explain seminal results on the design of hierarchies
of convex relaxations for a wide range of nonconvex problems. Finally, we study
different numerical algorithms for large-scale conic optimization problems.Comment: 18 page
A bibliography on parallel and vector numerical algorithms
This is a bibliography of numerical methods. It also includes a number of other references on machine architecture, programming language, and other topics of interest to scientific computing. Certain conference proceedings and anthologies which have been published in book form are listed also
Fluctuating volume-current formulation of electromagnetic fluctuations in inhomogeneous media: incandecence and luminescence in arbitrary geometries
We describe a fluctuating volume--current formulation of electromagnetic
fluctuations that extends our recent work on heat exchange and Casimir
interactions between arbitrarily shaped homogeneous bodies [Phys. Rev. B. 88,
054305] to situations involving incandescence and luminescence problems,
including thermal radiation, heat transfer, Casimir forces, spontaneous
emission, fluorescence, and Raman scattering, in inhomogeneous media. Unlike
previous scattering formulations based on field and/or surface unknowns, our
work exploits powerful techniques from the volume--integral equation (VIE)
method, in which electromagnetic scattering is described in terms of
volumetric, current unknowns throughout the bodies. The resulting trace
formulas (boxed equations) involve products of well-studied VIE matrices and
describe power and momentum transfer between objects with spatially varying
material properties and fluctuation characteristics. We demonstrate that thanks
to the low-rank properties of the associatedmatrices, these formulas are
susceptible to fast-trace computations based on iterative methods, making
practical calculations tractable. We apply our techniques to study thermal
radiation, heat transfer, and fluorescence in complicated geometries, checking
our method against established techniques best suited for homogeneous bodies as
well as applying it to obtain predictions of radiation from complex bodies with
spatially varying permittivities and/or temperature profiles
EIT Reconstruction Algorithms: Pitfalls, Challenges and Recent Developments
We review developments, issues and challenges in Electrical Impedance
Tomography (EIT), for the 4th Workshop on Biomedical Applications of EIT,
Manchester 2003. We focus on the necessity for three dimensional data
collection and reconstruction, efficient solution of the forward problem and
present and future reconstruction algorithms. We also suggest common pitfalls
or ``inverse crimes'' to avoid.Comment: A review paper for the 4th Workshop on Biomedical Applications of
EIT, Manchester, UK, 200
Unconditionally stable integration of Maxwell's equations
Numerical integration of Maxwell’s equations is often based on explicit methods accepting a stability step size restriction. In literature evidence is given that there is also a need for unconditionally stable methods, as exemplified by the successful alternating direction
implicit – finite difference time domain scheme. In this paper, we discuss unconditionally stable integration for a general semidiscrete Maxwell system allowing non-Cartesian space grids as encountered in finite-element discretizations. Such grids exclude the alternating direction implicit approach. Particular attention
is given to the second-order trapezoidal rule implemented with preconditioned conjugate gradient iteration and to second-order exponential integration using Krylov subspace iteration for evaluating the arising ϕ-functions. A three-space dimensional test problem is used for numerical assessment and comparison with an economical second-order implicit–explicit integrator
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