Polyoxometalate (POM)-layered double hydroxides (LDH) composite materials: design and catalytic applications

Layered double hydroxides (LDHs) are an important large class of two-dimensional (2D) anionic lamellar materials that possess flexible modular structure, facile exchangeability of inter-lamellar guest anions and uniform distribution of metal cations in the layer. Owing to the modular accessible gallery and unique inter-lamellar chemical environment, polyoxometalates (POMs) intercalated with LDHs has shown a vast array of physical properties with applications in environment, energy, catalysis, etc. Here we describe how polyoxometalate clusters can be used as building components for the construction of systems with important catalytic properties. This review article mainly focuses on the discussion of new synthetic approaches developed recently that allow the incorporation of the element of design in the construction of a fundamentally new class of materials with pre-defined functionalities in catalytic applications. Introducing the element of design and taking control over the finally observed functionality we demonstrate the unique opportunity for engineering materials with modular properties for specific catalytic applications

Context-aware Authorization in Highly Dynamic Environments

Highly dynamic computing environments, like ubiquitous and pervasive computing environments, require frequent adaptation of applications. Context is a key to adapt suiting user needs. On the other hand, standard access control trusts users once they have authenticated, despite the fact that they may reach unauthorized contexts. We analyse how taking into account dynamic information like context in the authorization subsystem can improve security, and how this new access control applies to interaction patterns, like messaging or eventing. We experiment and validate our approach using context as an authorization factor for eventing in Web service for device (like UPnP or DPWS), in smart home security

Stable Wireless Network Control Under Service Constraints

We consider the design of wireless queueing network control policies with particular focus on combining stability with additional application-dependent requirements. Thereby, we consequently pursue a cost function based approach that provides the flexibility to incorporate constraints and requirements of particular services or applications. As typical examples of such requirements, we consider the reduction of buffer underflows in case of streaming traffic, and energy efficiency in networks of battery powered nodes. Compared to the classical throughput optimal control problem, such requirements significantly complicate the control problem. We provide easily verifyable theoretical conditions for stability, and, additionally, compare various candidate cost functions applied to wireless networks with streaming media traffic. Moreover, we demonstrate how the framework can be applied to the problem of energy efficient routing, and we demonstrate the aplication of our framework in cross-layer control problems for wireless multihop networks, using an advanced power control scheme for interference mitigation, based on successive convex approximation. In all scenarios, the performance of our control framework is evaluated using extensive numerical simulations.Comment: Accepted for publication in IEEE Transactions on Control of Network Systems. arXiv admin note: text overlap with arXiv:1208.297

A metal–organic framework/α-alumina composite with a novel geometry for enhanced adsorptive separation

The development of a metal–organic framework/α-alumina composite leads to a novel concept: efficient adsorption occurs within a plurality of radial micro-channels with no loss of the active adsorbents during the process. This composite can effectively remediate arsenic contaminated water producing potable water recovery, whereas the conventional fixed bed requires eight times the amount of active adsorbents to achieve a similar performance

Non destructive investigation of defects in composite structures by fullfield measurement methods

This paper presents different interests of non destructive full-field measurement. More precisely, it focuses on the characterization and the comparison of the X-ray tomography and two methods of infrared thermography in order to define the defect detection limits and to precise the specific application fields for each technique on multi-layered and sandwich composite structures. The obtained results are qualitatively and quantitatively analyzed

Advanced structural sizing methodology

Research in computerized structural sizing technology was reviewed. Areas covered include: overall design; structural subassembly design; thermal structures; and stiffened panels. In each case, sample results are presented