Dynamic property characterization of ionic polymer metal composite (Ipmc)

In this thesis dynamic properties of Ionic Polymer Metal Composite (IPMC) is studied. The ionic polymer (IPMC) is made out of a high polymer gel film whose surface is plated with platinum. This ionic polymer finds its application in future as artificial muscle. Analytical modeling method for both single and segmented ionic polymer which can exhibit varying curvature along the polymer was introduced. This segmented ionic polymer can generate more flexible propulsion compared with a single strip ionic polymer where only forward propulsion can be generated by a simple oscillatory bending motion. It is well known in biomimetic system research that a simple bending motion has lower efficiency than a snake-like wavy motion in propulsion. In this segmented ionic polymer each segment can be bent individually. This segmented ionic polymer design consists of a number of independent electrode sections along the length of the ionic polymer to realize the undulatory motion by selectively activating each segment. The magnitude of curvature can be controlled by adjusting the voltage level applied across each segment. In this thesis we focus on the development of an analytical model to predict the deflection of this single and segmented ionic polymers and the model is validated with experimental results. Due to the complexity of the polymer, it is necessary to find the dynamic parameters from the experimental data. After proper tuning of dynamic model, this can be used for various control applications including the underwater robotic propulsor device design and others. The dynamic model developed in this work reasonable complies with experimental data and can be further developed for future control algorithm design

Integrated static and dynamic modeling of an ionic polymer–metal composite actuator

Ionic polymer–metal composites have been widely used as actuators for robotic systems. In this article, we investigate and verify the characteristics of ionic polymer–metal composite actuators experimentally and theoretically. Two analytical models are utilized to analyze the performance of ionic polymer–metal composites: a linear irreversible electrodynamical model and a dynamic model. We find that the first model accurately predicts the static characteristics of the ionic polymer–metal composite according to the Onsager equations, while the second model is able to reveal the back relaxation characteristics of the ionic polymer–metal composite. We combine the static and dynamic models of the ionic polymer–metal composite and derive the transfer function for the ionic polymer–metal composite’s mechanical response to an electrical signal. A driving signal with a smooth slope and a low frequency is beneficial for the power efficiency

Distributed force model for arbitrarily shaped IMPC actuators

A model that describes the relationship of an arbitrarily shaped artificial muscle to the force it produces does not currently exist for actuators made of ionic polymer-metal composites (IPMC), a type of electroactive smart material. The model in this thesis couples a finite element force simulation for IPMC with a novel method of performing force measurements for IPMC actuators. The model is capable of predicting the blocked force output for IPMC actuators of arbitrary dimension. The ultimate goal of this work is to create a method of analysis that allows for the design of custom IPMC fingers that have specific force production and actuation properties

3D Modeling and Design Optimization of Rod Shaped Ionic Polymer Metal Composite Actuator

Ionic polymer-metal composites (IPMCs) are some of the most well-known electro-active polymers. This is due to their large deformation provided a relatively low voltage source. IPMCs have been acknowledged as a potential candidate for biomedical applications such as cardiac catheters and surgical probes; however, there is still no existing mass manufacturing of IPMCs. This study intends to provide a theoretical framework which could be used to design practical purpose IPMCs depending on the end users interest. This study begins by investigating methodologies used to develop quantify the physical actuation of an IPMC in 3-dimensional space. This approach is taken in two separate means; however, both approaches utilize the finite element method. The first approach utilizes the finite element method in order to describe the dynamic response of a segmented IPMC actuator. The first approach manually constructs each element with a local coordinate system. Each system undergoes a rigid body motion along the element and deformation of the element is expressed in the local coordinate frame. The physical phenomenon in this system is simplified by utilizing a lumped RC model in order to simplify the electro-mechanical phenomena in the IPMC dynamics. The second study investigates 3D modeling of a rod shaped IPMC actuator by explicitly coupling electrostatics, transport phenomenon, and solid mechanics. This portion of the research will briefly discuss the mathematical background that more accurately quantifies the physical phenomena. Solving for the 3-dimensional actuation is explicitly carried out again by utilizing the finite element method. The numerical result is conducted in a software package known as COMSOL MULTIPHYSICS. This simulation allows for explicit geometric rendering as well as more explicit quantification of the physical quantities such as concentration, electric field, and deflection The final study will conduct design optimization on the COMSOL simulation in order to provide conceptual motivation for future designs. Utilizing a multi-physics analysis approach on a three dimensional cylinder and tube type IPMC provides physically accurate results for time dependent end effector displacement given a voltage source. Simulations are conducted with the finite element method and are also validated with empirical evidences. Having an in-depth understanding of the physical coupling provides optimal design parameters that cannot be altered from a standard electro-mechanical coupling. These parameters are altered in order to determine optimal designs for end-effector displacement, maximum force, and improved mobility with limited voltage magnitude. Design alterations are conducted on the electrode patterns in order to provide greater mobility, electrode size for efficient bending, and Nafion diameter for improved force. The results of this study will provide optimal design parameters of the IPMC for different applications

Ioonsete elektromehaaniliselt aktiivsete polümeeride deformatsioonist sõltuv elektroodi impedants

Väitekirja elektrooniline versioon ei sisalda publikatsioone.Elektromehaaniliselt aktiivsed materjalid on polümeeridel põhinevad mitmekihilised komposiitmaterjalid, mis muudavad oma välist kuju, kui neid elektriliselt stimuleerida; tihti nimetatakse neid ka tehislihasteks. Taolistest materjalidest valmistatud täiturid pakkuvad huvi nii mikrolaborseadmetes kui ka loodust matkivas robootikas, sest võimaldavad luua keerukaid ülipisikesi ajameid. Võrreldes tavapäraste elektrimootoritega võimaldavad EAP-d (elektromehaaniliselt aktiivsed polümeerid) helitut liigutust ning neid saab lõigata konkreetse rakenduse jaoks sobivasse suurusesse. EAP-d jagunevad kahte põhiklassi: elektron- ja ioon-EAP. Doktoritöös käsitletakse kahte erinevat ioon-EAP materjali, kus mehaaniline koste on tingitud ioonide ümberpaigutumisest kolmekihilises komposiitmaterjalis. Kuna EAP-de elektromehaanilised omadused sõltuvad lisaks sisendpinge amplituudile ja sagedusele ka tugevasti ümbritseva keskkonna parameetritest (nt niiskus ja temperatuur), siis on nendest materjalidest loodud täiturite juhtimiseks tarvilik kasutada tagasisidet. Täiendav tagasisideallikas võib oma omaduste tõttu aga vähendada EAP-de rakendusvõimalusi ning seetõttu on eesmärgiks luua n-ö isetundlik EAP ajam, mis funktsioneerib samaaegselt nii täituri kui ka liigutusandurina. Doktoritööd esitatakse uuritud materjalide elektroodi impedantsi ja deformatsiooni vaheline seos ning kirjeldatakse vastav elektriline mudel. Eraldamaks andursignaali täituri sisendpingest pakutakse välja elektroodikihi piires täituri ja anduri elektriline eraldamine. Loobudes ainult elektroodimaterjalist säilitab polümeerkarkass täituri ja anduri mehaanilise ühendatuse – seega taolises süsteemis järgib sensor täituri kuju, kuigi need on elektriliselt lahti sidestatud. Elektroodimaterjali valikuliseks eemaldamiseks kasutatakse mitmeid erinevaid meetodeid (freesimine, laserablatsioon jne) ning ühtlasi uuritakse nende kasutusmugavust ja protsessi mõju kogu komposiitmaterjalile.Electromechanically active materials are polymer-based composites exhibiting mechanical deformation under electrical stimulus, i.e. they can be implemented as soft actuators in variety of devices. In comparison to conventional electromechanical actuators, their key characteristics include easy customisation, noiseless operation, straightforward mechanical design, sophisticated motion patterns, etc. Ionic EAPs (electromechanically active polymers) are one of two primary classes of electroactive materials, where actuation is caused mostly by the displacement of ions inside polymer matrix. Mechanical response of ionic EAPs is, in addition to voltage and frequency, dependent on environmental variables such as humidity and temperature. Therefore a major challenge lies in achieving controlled actuation of these materials. Due to their size and added complexity, external feedback devices inhibit the application of micro-scale actuators. Hence, self-sensing EAP actuators—capable for simultaneous actuation and sensing—are desired. In this thesis, sensing based on deformation-dependent electrochemical impedance is demonstrated and modelled for two types of trilayer ionic EAPs—ionic polymer-metal composite and carbon-polymer composite. Separating sensing signal from the input signal of the actuator is achieved by patterning the electrode layers of an IEAP material in a way that different but mechanically coupled sections for actuation and sensing are created. A variety of concepts for pattering the electrode layers (machining, laser ablation, masking, etc.) are implemented and their applicability is discussed

Theoretical and Experimental Investigation on the Multiple Shape Memory Ionic Polymer-Metal Composite Actuator

Development of biomimetic actuators has been an essential motivation in the study of smart materials. However, few materials are capable of controlling complex twisting and bending deformations simultaneously or separately using a dynamic control system. The ionic polymer-metal composite (IPMC) is an emerging smart material in actuation and sensing applications, such as biomimetic robotics, advanced medical devices and human affinity applications. Here, we report a Multiple Shape Memory Ionic Polymer-Metal Composite (MSM-IPMC) actuator having multiple-shape memory effect, and is able to perform complex motion by two external inputs, electrical and thermal. Prior to the development of this type of actuator, this capability only could be realized with existing actuator technologies by using multiple actuators or another robotic system. Theoretical and experimental investigation on the MSM-IPMC actuator were performed. To date, the effect of the surface electrode properties change on the actuating of IPMC have not been well studied. To address this problem, we theoretically predict and experimentally investigate the dynamic electro-mechanical response of the IPMC thin-strip actuator. A model of the IPMC actuator is proposed based on the Poisson-Nernst-Planck equations for ion transport and charge dynamics in the polymer membrane, while a physical model for the change of surface resistance of the electrodes of the IPMC due to deformation is also incorporated. By incorporating these two models, a complete, dynamic, physics-based model for IPMC actuators is presented. To verify the model, IPMC samples were prepared and experiments were conducted. The results show that the theoretical model can accurately predict the actuating performance of IPMC actuators over a range of dynamic conditions. Additionally, the charge dynamics inside the polymer during the oscillation of the IPMC are presented. It is also shown that the charge at the boundary mainly affects the induced stress of the IPMC. This study is beneficial for the comprehensive understanding of the surface electrode effect on the performance of IPMC actuators. In our study, we introduce a soft MSM-IPMC actuator having multiple degrees-of-freedom that demonstrates high maneuverability when controlled by two external inputs, electrical and thermal. These multiple inputs allow for complex motions that are routine in nature, but that would be otherwise difficult to obtain with a single actuator. To the best of our knowledge, this MSM-IPMC actuator is the first solitary actuator capable of multiple-input control and the resulting deformability and maneuverability. The shape memory properties of MSM-IPMC were theoretically and experimentally studied. We presented the multiple shape memory properties of Nafion cylinder. A physics based model of the IPMC was proposed. The free energy density theory was utilized to analyze the shape properties of the IPMC. To verify the model, IPMC samples with the Nafion as the base membrane was prepared and experiments were conducted. Simulation of the model was performed and the results were compared with the experimental data. It was successfully demonstrated that the theoretical model can well explain the shape memory properties of the IPMC. The results showed that the reheat glass transition temperature of the IPMC is lower than the programming temperature. It was also found that the back-relaxation of the IPMC decreases as the programming temperature increases. This study may be useful for the better understanding of the shape memory effect of IPMC. Furthermore, we theoretically modeled and experimentally investigated the multiple shape memory effect of MSM-IPMC. We proposed a new physical principle to explain the shape memory behavior. A theoretical model of the multiple shape memory effect of MSM-IPMC was developed. Based on our previous study on the electro-mechanical actuation effect of IPMC, we proposed a comprehensive physics-based model of MSM-IPMC which couples the actuation effect and the multiple shape memory effect. It is the first model that includes these two actuation effects and multiple shape memory effect. Simulation of the model was performed using finite element method. To verify the model, an MSM-IPMC sample was prepared. Experimental tests of MSM-IPMC were conducted. By comparing the simulation results and the experimental results, both results have a good agreement. The multiple shape memory effect and reversibility of three different polymers, namely the Nafion, Aquivion and GEFC with three different ions, which are the hydrogen, lithium and sodium, were also quantitatively tested respectively. Based on the results, it is shown that all the polymers have good multiple shape memory effect and reversibility. The ions have an influence on the broad glass transition range of the polymers. The current study is beneficial for the better understanding of the underlying physics of MSM-IPMC. A biomimetic underwater robot, that was actuated by the MSM-IPMC, was developed. The design of the robot was inspired by the pectoral fish swimming modes, such as stingrays, knifefish and cuttefish. The robot was actuated by two soft fins which were consisted of multiple IPMC samples. Through actuating the IPMCs separately, traveling wave was generated on the soft fin. Experiments were performed for the test of the robot. The deformation and the blocking force of the IPMCs on the fin were measured. A force measurement system in a flow channel was implemented. The thrust force of the robot under different frequencies and traveling wave numbers were recorded. Multiple shape memory effect was performed on the robot. The robot was capable of changing its swimming modes from Gymnotiform to Mobuliform, which has high deformability, maneuverability and agility

Modeling and Control of a Flexible Ionic Polymer Metal Composite(IPMC) Actuator for Underwater Propulsion

The goal of this research is to model and control the underwater vehicle propelled by IPMC actuator. IPMC consists of an ionic membrane sandwiched between two metallic electrodes. When an external voltage is applied, IPMC undergoes large deformation due to transport of ions. Due to its ability to work in aqueous environments, it can be used for developing small scale underwater vehicles. First, Finite element approach is used to describe the dynamics of the both single and segmented IPMC actuator. In the approach presented, each element is attached with a local coordinate system that undergoes rigid body motion along with the element and the deformation of the element is expressed in local coordinate frame. This large deflection model is combines with Clumped RC model to model the dynamics of the IPMC. Next, hydrodynamic model for the IPMC driven vehicle is developed. Frictional resistive forces are considered for modeling the interaction with water. The hydrodynamic coefficients are identified using FLUENT CFD analysis. The developed hydrodynamic model is validated using the experimental data. An autonomous IPMC propelled vehicle is developed to overcome the limited applications tethered vehicle developed earlier. In this research, two kinds of control algorithms based on system identification are developed. A PI controller is designed using simulation data and implemented for controlling speed and orientation of the vehicle. Using the identified linear model, a decoupling control algorithm is developed to eliminate the interactions in tracking speed and orientation (heading angle) of the vehicle. The developed algorithm implemented on original non-linear plant. A path planning algorithm is presented to control the trajectory of the vehicle in the presence of obstacles. Obstacles are approximated by polygonal shapes that approximate their actual dimensions and the vehicle is approximated by a rectangle that encloses the largest deformation of the oscillating IPMC actuator. To simplify the problem of collision detection, vehicle is shrunk to a line while obstacles are expanded by a half width of the rectangle representing the vehicle. The path generated by the algorithm is discretized with respect to time and controlled simultaneously for the orientation angle and speed of the vehicle. A model reference adaptive controller (MRAC) is designed for underwater vehicle propelled by the Ionic polymer metal composite (IPMC) actuator. Trajectories of the vehicle are controlled by simultaneously controlling the bias and amplitude of the sinusoidal voltage applied to the IPMC actuator attached at the rear end of the vehicle. Using Lyapunov stability theory and factorization of the high frequency gain matrix, an adaptive output feedback control is designed for trajectory control of a heading angle and a speed of the vehicle. In the proposed approach, SDU (Square Diagonal and Upper triangular matrix) decomposition of the high frequency gain (HFG) matrix is used. Only signs of the leading principle minors of the HFG matrix are assumed to be known. Simulations results are presented to show that precise trajectory control of the heading and speed is achieved in spite of the coupling between controlled variables

IPMC materjali hp-FEM mudel

Väitekirja elektrooniline versioon ei sisalda publikatsioone.Ioonjuhtivaid polümeer-metall komposiitmaterjale (edaspidi lühendatud IPMC ehk ionic polymer-metal composite) on uuritud juba vähemalt kaks aastakümmet nende huvipakkuvate omaduste tõttu. Võimalikeks kasutusaladeks on vaiksed aktuaatorid või sensorid. IPMC eelised teiste elektroaktiivsete polümeeride ees on töötamine madalal pingel (1...5V), suur paindeulatus, ja toimimine veekeskkonnas. Kuigi põhiliselt on uuritud materjalide omadusi aktuaatoritena, on hiljuti materjalide sensor-omadused rohkem tähelepanu saanud. Et materjali toimimisest aru saada ning seda kirjeldada erinevate rakenduste tarbeks, on vajalik füüsikal baseeruvat mudelit. Sellest lähtuvalt on välja töötatud Poisson-Nernst-Planck-Navier võrranditel baseeruva IPMC mudel. See baseerub füüsikalistel printsiipidest, ehk et saab kasutada võimalikult palju mõõdetavaid suurusi ääretingimustena (nagu materjali paindumine, rakendatud pinge jne). Lisaks on oluline, et meetod millel mudel baseerub, oleks efektiivne ning võimaldaks arvutusi väikese või vähemalt teadaoleva maksimaalse arvutusveaga. Käesoleva töö keskendub peamiselt just arvutusmeetodil ja annab ülevaate uudsest hp-FEM (finite element method) ehk hp lõplike elementide meetodist ja sellel baseeruvast IPMC mudelist. Kõigepealt on täielikult tuletatud võrrandid ja nende integraalne esitus Newtoni meetodi jaoks. Seejärel antakse lühike ülevaade hp-FEM meetodist adaptiivse väljapõhise võrguga ning kogu süsteemi Jakobiaani tuletus hp-FEM tarkvara Hermes jaoks. On näidatud kuidas automaatne adaptiivne hp-FEM võimaldab probleemi suuruse hoida väiksena (süsteemi vabadusastmeid ja kasutatud mälu silmas pidades). Kõige pealt on lahendatud Poisson-Nernst-Plancki võrrandisüsteem ja on käsitletud erinevaid adaptiivusalgoritme. Üks huvitav tulemus on, et adaptiivsed algoritmid võimaldavad lahendada probleemi tingimustel, kus Debye pikkus jääb nanomeetri suurusjärku – seda süsteemis mille mõõtmed on millimeetri skaalas. Nendest tulemustest lähtuvalt esitatakse lahendus terve Poisson-Nernst-Planck-Navier võrrandite süsteemile IPMC paindumise arvutustes. Taaskord on lõplikud võrrandid koos tuletuskäiguga esitatud. Lisaks on analüüsitud suur hulk simulatsiooni tulemusi arvutusprobleemi suurust ja kulutatud arvutusaega silmas pidades ja sellest lähtuvalt leitud parim adaptiivuse algoritm seda liiki probleemide jaoks. On ka näidatud kuidas meetod võimaldab arvutusdomeeni geomeetriat arvesse võtta – domeeni pikkuse ja laiuse suhtest tulenevad ääreefektid on automaatselt arvutustes käsitletud. Kokkuvõtteks, käesolevas töös on detailselt kirjeldatud kuidas kasutades uudne hp-FEM meetod koos adaptiivsete algoritmide ja väljapõhise võrguga võimaldab Nernst-Planck-Poisson-Navier probleemi lahendada efektiivselt, samal ajal hoides lahenduse arvutusvea etteseatud piirides.Ionic polymer-metal composites (IPMC) have been studied during the past two decades for their potential to serve as noiseless mechanoelectrical and electromechanical transducers. The advantages of IPMC over other electroactive polymer actuators are low voltage bending, high strains (>1%), and an ability to work in wet environments. The main focus has been on the electromechanical transduction property – the material’s ability to exhibit large bending deformation in response to a low (typically 1...5 V) applied voltage. However, lately research on the mechanoelectrical transduction properties of the material has gained more attention. In order to describe both deformation in response to applied voltage (electromechanical transduction) and induced voltage in response to applied deformation (mechanoelectrical transduction) properties of IPMC, an advanced physics based model of the material is necessary. Ongoing research has been focused on creating such model where real measurable quantities can be imposed as boundary conditions in order to reduce the number of unknown parameters required for calculations. In this dissertation, a physics based model that is based on novel hp-FEM (finite element method) is proposed. From the fundamental aspect, previously proposed and validated physics based model consisting of a system of Poisson-Nernst-Planck-Navier’s equations is described in detail and used in IPMC deformation calculations. From the mathematical aspect, a novel hp-FEM method was researched to model the equations efficiently. The main focus of this disseration is on the mathematical aspect. Full derivation of the equations with an in-depth study of the benefits of using higher order FEM with automatic adaptivity is presented. The explicit weak form of the Poisson-Nernst-Planck system for Newton’s method is presented. Thereafter, a brief overview of the adaptive multi-mesh hp-FEM is introduced and the residual vector and Jacobian matrix of the system is derived and implemented using hp-FEM library Hermes. It is shown how such problem benefits from using individual meshes with mutually independent adaptivity mechanisms. To begin with, a model consisting of only the Poisson-Nernst-Planck system is solved using different adaptivity algorithms. For instance, it is demonstrated that the problem with set of constants that results Debye’s length in the nanometer scale can be successfully solved. What makes it even more remarkable is the fact that the calculation domain size is in the millimeter scale. Based on those results, the complete Poisson-Nernst-Planck-Navier’s system of equations is studied for IPMC electromechanical transduction calculations. Again, the entire mathematical derivation including weak forms, the residual vector and Jacobian matrix are presented. Thereafter, a number of simulations are analyzed in terms of problem size and consumed CPU time. The best automatic adaptivity mode for such problem is determined. It is also shown how hp-FEM helps to keep the problem geometrically scalable. Additionally, it is demonstrated how employing a PID controller based time step adaptivity helps to reduce the total calculation time. Overall, by using hp-FEM with adaptive multi-mesh configuration the Nernst-Planck-Poisson-Navier’s problem size in IPMC deformation calculations is reduced significantly while a prescribed precision of the solution is maintained

3D-Printing and Machine Learning Control of Soft Ionic Polymer-Metal Composite Actuators

This paper presents a new manufacturing and control paradigm for developing soft ionic polymer-metal composite (IPMC) actuators for soft robotics applications. First, an additive manufacturing method that exploits the fused-filament (3D printing) process is described to overcome challenges with existing methods of creating custom-shaped IPMC actuators. By working with ionomeric precursor material, the 3D-printing process enables the creation of 3D monolithic IPMC devices where ultimately integrated sensors and actuators can be achieved. Second, Bayesian optimization is used as a learning-based control approach to help mitigate complex time-varying dynamic effects in 3D-printed actuators. This approach overcomes the challenges with existing methods where complex models or continuous sensor feedback are needed. The manufacturing and control paradigm is applied to create and control the behavior of example actuators, and subsequently the actuator components are combined to create an example modular reconfigurable IPMC soft crawling robot to demonstrate feasibility. Two hypotheses related to the effectiveness of the machine-learning process are tested. Results show enhancement of actuator performance through machine learning, and the proof-of-concepts can be leveraged for continued advancement of more complex IPMC devices. Emerging challenges are also highlighted

Characterization of a Low-Cost Millinewton Force Sensor for Ionic Polymer Metal Composite Actuators

Ionic polymer-metal composites (IPMCs) have become an area of interest in the past decade for their unique properties as actuators. Conventional IPMCs require the use of rare earth metals for electrodes making the fabrication of these materials expensive, time consuming to produce, and not suitable for large scale manufacturing. Due to the low actuational forces, in the millinewton scale, characterization of IPMCs is costly and often requires expensive force sensors and data acquisition (DAQ) systems. This thesis explores the capabilities of a low cost, two dimensional millinewton force sensor fabricated out of nitinol #1 wire and orthogonally mounted strain gauge pairs in half bridge configurations. An Arduino microcontroller based DAQ system and a modular test stand were developed to facilitate calibration of the force sensor and testing of IPMCs. The overall system cost, approximately $200 USD, was able to achieve a force resolution of 0.49 mN. Calibration of the force sensor was accomplished gravimetrically and the data was processed in an Arduino-LabVIEW™ interface. An ionic polymer-carbon composite (IPCC) fabrication concept was also developed that utilizes buckypaper (BP) electrodes, electrospun nanofibrous Nafion mats, and EMI-Tf ionic liquid for hydration. The IPCC concept has the potential to achieve faster actuation rates, larger deflections, and longer operations in air compared to IPMCs. The IPCC fabrication process developed takes a fraction of the time compared to conventional IPMC fabrication and can be applied to IPMC fabrication for production on an industrial scale