21,280 research outputs found
Tiramisu: A Polyhedral Compiler for Expressing Fast and Portable Code
This paper introduces Tiramisu, a polyhedral framework designed to generate
high performance code for multiple platforms including multicores, GPUs, and
distributed machines. Tiramisu introduces a scheduling language with novel
extensions to explicitly manage the complexities that arise when targeting
these systems. The framework is designed for the areas of image processing,
stencils, linear algebra and deep learning. Tiramisu has two main features: it
relies on a flexible representation based on the polyhedral model and it has a
rich scheduling language allowing fine-grained control of optimizations.
Tiramisu uses a four-level intermediate representation that allows full
separation between the algorithms, loop transformations, data layouts, and
communication. This separation simplifies targeting multiple hardware
architectures with the same algorithm. We evaluate Tiramisu by writing a set of
image processing, deep learning, and linear algebra benchmarks and compare them
with state-of-the-art compilers and hand-tuned libraries. We show that Tiramisu
matches or outperforms existing compilers and libraries on different hardware
architectures, including multicore CPUs, GPUs, and distributed machines.Comment: arXiv admin note: substantial text overlap with arXiv:1803.0041
Effect of disorder on transport properties in a tight-binding model for lead halide perovskites
The hybrid organic-inorganic lead halide perovskite materials have emerged as
remarkable materials for photovoltaic applications. Their strengths include
good electric transport properties in spite of the disorder inherent in them.
Motivated by this observation, we analyze the effects of disorder on the energy
eigenstates of a tight-binding model of these materials. In particular, we
analyze the spatial extension of the energy eigenstates, which is quantified by
the inverse participation ratio. This parameter exhibits a tendency, and
possibly a phase transition, to localization as the on-site energy disorder
strength is increased. However, we argue that the disorder in the lead halide
perovskites corresponds to a point in the regime of highly delocalized states.
Our results also suggest that the electronic states of mixed-halide materials
tend to be more localized than those of pure materials, which suggests a weaker
tendency to form extended bonding states in the mixed-halide materials and is
therefore not favourable for halide mixing.Comment: 24 pages (preprint), 11 figure
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Highly Stable Luminous "snakes" from CsPbX3 Perovskite Nanocrystals Anchored on Amine-Coated Silica Nanowires
CsPbX3 (X = Cl, Br, and I) perovskite nanocrystals (NCs) are known for their exceptional optoelectronic properties, yet the material's instability toward polar solvents, heat, or UV irradiation greatly limits its further applications. Herein, an efficient in situ growing strategy has been developed to give highly stable perovskite NC composites (abbreviated CsPbX3@CA-SiO2) by anchoring CsPbX3 NCs onto silica nanowires (NWs), which effectively depresses the optical degradation of their photoluminescence (PL) and enhances stability. The preparation of surface-functionalized serpentine silica NWs is realized by a sol-gel process involving hydrolysis of a mixture of tetraethyl orthosilicate (TEOS), 3-aminopropyltriethoxysilane (APTES), and trimethoxy(octadecyl)silane (TMODS) in a water/oil emulsion. The serpentine NWs are formed via an anisotropic growth with lengths up to 8 μm. The free amino groups are employed as surface ligands for growing perovskite NCs, yielding distributed monodisperse NCs (∼8 nm) around the NW matrix. The emission wavelength is tunable by simple variation of the halide compositions (CsPbX3, X = Cl, Br, or I), and the composites demonstrate a high photoluminescence quantum yield (PLQY 32-69%). Additionally, we have demonstrated the composites CsPbX3@CA-SiO2 can be self-woven to form a porous 3D hierarchical NWs membrane, giving rise to a superhydrophobic surface with hierarchical micro/nano structural features. The resulting composites exhibit high stability toward water, heat, and UV irradiation. This work elucidates an effective strategy to incorporate perovskite nanocrystals onto functional matrices as multifunctional stable light sources
Structural and spectral dynamics of single-crystalline Ruddlesden-Popper phase halide perovskite blue light-emitting diodes.
Achieving perovskite-based high-color purity blue-emitting light-emitting diodes (LEDs) is still challenging. Here, we report successful synthesis of a series of blue-emissive two-dimensional Ruddlesden-Popper phase single crystals and their high-color purity blue-emitting LED demonstrations. Although this approach successfully achieves a series of bandgap emissions based on the different layer thicknesses, it still suffers from a conventional temperature-induced device degradation mechanism during high-voltage operations. To understand the underlying mechanism, we further elucidate temperature-induced device degradation by investigating the crystal structural and spectral evolution dynamics via in situ temperature-dependent single-crystal x-ray diffraction, photoluminescence (PL) characterization, and density functional theory calculation. The PL peak becomes asymmetrically broadened with a marked intensity decay, as temperature increases owing to [PbBr6]4- octahedra tilting and the organic chain disordering, which results in bandgap decrease. This study indicates that careful heat management under LED operation is a key factor to maintain the sharp and intense emission
Halide-Perovskite Resonant Nanophotonics
Halide perovskites have emerged recently as promising materials for many
applications in photovoltaics and optoelectronics. Recent studies of their
optical properties suggest many novel opportunities for a design of advanced
nanophotonic devices due to low-cost fabrication, high values of the refractive
index, existence of excitons at room temperatures, broadband bandgap
tunability, high optical gain and nonlinear response, as well as simplicity of
their integration with other types of structures. This paper provides an
overview of the recent progress in the study of optical effects originating
from nanostructured perovskites, including their potential applications.Comment: revie
High power metallic halide laser
A laser amplification system is disclosed whereby a metallic halide vapor such as copper chloride is caused to flow through a laser amplifier and a heat exchanger in a closed loop system so that the flow rate is altered to control the temperature rise across the length of the laser amplifier. The copper atoms within the laser amplifier should not exceed a temperature of 3000 K, so that the number of copper atoms in the metastable state will not be high enough to prevent amplification in the amplifier. A molecular dissociation apparatus is provided at the input to the laser amplifier for dissociating the copper chloride into copper atoms and ions and chlorine atoms and ions. The dissociation apparatus includes a hollow cathode tube and an annular ring spaced apart from the tube end. A voltage differential is applied between the annular ring and the hollow cathode tube so that as the copper chloride flows through, it is dissociated into copper and chlorine ions and atoms
Atomistic Mechanism of the Nucleation of Methylammonium Lead Iodide Perovskite from Solution
In the ongoing intense quest to increase the photoconversion efficiencies of
lead halide perovskites, it has become evident that optimizing the morphology
of the material is essential to achieve high peformance. Despite the fact that
nucleation plays a key role in controlling the crystal morphology, very little
is known about the nucleation and crystal growth processes. Here, we perform
metadynamics simulations of nucleation of methylammonium lead triiodide (MAPI)
in order to unravel the atomistic details of perovskite crystallization from a
-butyrolactone solution. The metadynamics trajectories show that the
nucleation process takes place in several stages. Initially, dense amorphous
clusters mainly consisting of lead and iodide appear from the homogeneous
solution. These clusters evolve into lead iodide (PbI) like structures.
Subsequently, methylammonium (MA) ions diffuse into this PbI-like
aggregates triggering the transformation into a perovskite crystal through a
solid-solid transformation. Demonstrating the crucial role of the monovalent
cations in crystallization, our simulations provide key insights into the
evolution of the perovskite microstructure which is essential to make
high-quality perovskite based solar cells and optoelectronics
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