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Flexible high frequency electronics and plasmonics using two dimensional nanomaterials
In this work, we have demonstrated novel flexible electronics and plasmonic devices using 2-dimensional (2D) nanomaterials (graphene and MoS2). The first part of this work is about design of flexible high frequency electronics using 2D nanomaterials. We report sub-THz graphene transistors with fT ~ 100GHz. We also discuss how to integrate graphene based sub blocks (antenna, mixer and speaker) to fabricate all graphene based wireless receiver. We report for the first time flexible RF transistors with GHz frequency response using CVD grown monolayer MoS2. We also demonstrate flexible low power RF nanosystems (amplifiers, mixers, AM receiver) using CVD MoS2. We have developed MoS2 transistor models for integrated circuit design application. RF MoS2 transistors results are very promising for low power internet of things (IOT) applications. In second part, we have shown design of novel plasmonic devices using 2D nanomaterials. We have demonstrated large area tunable graphene metasurface using moiré nanosphere lithography (MNSL). We have shown novel method to fabricate large area graphene nanoribbons (GNRs) using block copolymer lithography (BCPL) and its potential application towards tunable mid-IR plasmonic sensing. We report for the first time nanopatterning of CVD MoS2 on plasmonic substrate using bubble pen lithography (BPL). We have also shown light enhancement of monolayer CVD MoS2 using plasmonic nanoantenna array (PNA). These results are very useful for design of highly efficient 2D nanomaterial based LEDs, photodetectors, lasers and sensors.Electrical and Computer Engineerin
Towards Single-Chip Nano-Systems
Important scientific discoveries are being propelled by the advent of nano-scale sensors that capture weak signals from their environment and pass them to complex instrumentation interface circuits for signal detection and processing. The highlight of this research is to investigate fabrication technologies to integrate such precision equipment with nano-sensors on a single complementary metal oxide semiconductor (CMOS) chip. In this context, several demonstration vehicles are proposed. First, an integration technology suitable for a fully integrated flexible microelectrode array has been proposed. A microelectrode array containing a single temperature sensor has been characterized and the versatility under dry/wet, and relaxed/strained conditions has been verified. On-chip instrumentation amplifier has been utilized to improve the temperature sensitivity of the device. While the flexibility of the array has been confirmed by laminating it on a fixed single cell, future experiments are necessary to confirm application of this device for live cell and tissue measurements. The proposed array can potentially attach itself to the pulsating surface of a single living cell or a network of cells to detect their vital signs
Photoelectrochemical imaging system for the mapping of cell surface charges
The surface charge of cells affects cell signaling, cell metabolic processes, adherence to surfaces, and cell proliferation. Our understanding of the role of membrane charges is limited due to the inability to observe changes without interfering, chemically or physically, with the cell or its membrane. Here, we report that a photoelectrochemical imaging system (PEIS) based on label-free ac-photocurrent measurements at indium tin oxide (ITO) coated glass substrates can be used to map the basal surface charge of single live cells under physiological conditions. Cells were cultured on the ITO substrate. Photocurrent images were generated by scanning a focused, modulated laser beam across the back of the ITO coated glass substrate under an applied bias voltage. The photocurrent was shown to be sensitive to the negative surface charge of the substrate facing, basal side of a single living cell—an area not accessible to other electrochemical or electrophysiological imaging techniques. The PEIS was used to monitor the lysis of mesenchymal stem cells
Photofunctional metal-organic framework thin films for sensing, catalysis and device fabrication
Metal Organic Frameworks (MOFs) constitute a developing class of materials constructed by metallic ions or inorganic clusters bridged by organic ligands, generating 2D or 3D extended porous crystalline structures. Their physical and chemical properties can be dramatically changed since the huge database of metal centers and type of ligands available for the design and construction MOFs. Besides, the implementation of anchored MOF onto different substrates opens up to an emerging field of device fabrication for specific applications. In this review we surveyed the recent progress and developments on MOF for sensing, catalylisis, photovoltaics, up conversion, and LED fabrication.Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - San Luis. Instituto de Investigaciones en TecnologĂa QuĂmica. Universidad Nacional de San Luis. Facultad de QuĂmica, BioquĂmica y Farmacia. Instituto de Investigaciones en TecnologĂa QuĂmica; ArgentinaFil: Roncaroli, Federico. ComisiĂłn Nacional de EnergĂa AtĂłmica. Centro AtĂłmico Constituyentes; Argentina. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas; Argentin
NASA SBIR abstracts of 1990 phase 1 projects
The research objectives of the 280 projects placed under contract in the National Aeronautics and Space Administration (NASA) 1990 Small Business Innovation Research (SBIR) Phase 1 program are described. The basic document consists of edited, non-proprietary abstracts of the winning proposals submitted by small businesses in response to NASA's 1990 SBIR Phase 1 Program Solicitation. The abstracts are presented under the 15 technical topics within which Phase 1 proposals were solicited. Each project was assigned a sequential identifying number from 001 to 280, in order of its appearance in the body of the report. The document also includes Appendixes to provide additional information about the SBIR program and permit cross-reference in the 1990 Phase 1 projects by company name, location by state, principal investigator, NASA field center responsible for management of each project, and NASA contract number
Tunable intervalence charge transfer in ruthenium Prussian blue analogue enables stable and efficient biocompatible artificial synapses
Emerging concepts for neuromorphic computing, bioelectronics, and
brain-computer interfacing inspire new research avenues aimed at understanding
the relationship between oxidation state and conductivity in unexplored
materials. Here, we present ruthenium Prussian blue analogue (RuPBA), a mixed
valence coordination compound with an open framework structure and ability to
conduct both ionic and electronic charge, for flexible artificial synapses that
reversibly switch conductance by more than four orders of magnitude based on
electrochemically tunable oxidation state. Retention of programmed states is
improved by nearly two orders of magnitude compared to the extensively studied
organic polymers, thus reducing the frequency, complexity and energy costs
associated with error correction schemes. We demonstrate dopamine detection
using RuPBA synapses and biocompatibility with neuronal cells, evoking
prospective application for brain-computer interfacing. By application of
electron transfer theory to in-situ spectroscopic probing of intervalence
charge transfer, we elucidate a switching mechanism whereby the degree of mixed
valency between N-coordinated Ru sites controls the carrier concentration and
mobility, as supported by DFT
Portable Bio-Devices: Design of Electrochemical Instruments from Miniaturized to Implantable Devices
The integration of biosensors and electronic technologies allows the development of
biomedical systems able to diagnose and monitoring pathologies by detecting specific
biomarkers.
The chapter presents the main modules involved in the development of such devices,
generically represented in Fig. 1, and focuses its attention on the essential components of
these systems to address questions such as: how is the device powered? How does it
communicate the measured data? What kind of sensors could be used?, and What kinds of
electronics are used
NASA SBIR abstracts of 1991 phase 1 projects
The objectives of 301 projects placed under contract by the Small Business Innovation Research (SBIR) program of the National Aeronautics and Space Administration (NASA) are described. These projects were selected competitively from among proposals submitted to NASA in response to the 1991 SBIR Program Solicitation. The basic document consists of edited, non-proprietary abstracts of the winning proposals submitted by small businesses. The abstracts are presented under the 15 technical topics within which Phase 1 proposals were solicited. Each project was assigned a sequential identifying number from 001 to 301, in order of its appearance in the body of the report. Appendixes to provide additional information about the SBIR program and permit cross-reference of the 1991 Phase 1 projects by company name, location by state, principal investigator, NASA Field Center responsible for management of each project, and NASA contract number are included
Ono: an open platform for social robotics
In recent times, the focal point of research in robotics has shifted from industrial ro- bots toward robots that interact with humans in an intuitive and safe manner. This evolution has resulted in the subfield of social robotics, which pertains to robots that function in a human environment and that can communicate with humans in an int- uitive way, e.g. with facial expressions. Social robots have the potential to impact many different aspects of our lives, but one particularly promising application is the use of robots in therapy, such as the treatment of children with autism. Unfortunately, many of the existing social robots are neither suited for practical use in therapy nor for large scale studies, mainly because they are expensive, one-of-a-kind robots that are hard to modify to suit a specific need. We created Ono, a social robotics platform, to tackle these issues. Ono is composed entirely from off-the-shelf components and cheap materials, and can be built at a local FabLab at the fraction of the cost of other robots. Ono is also entirely open source and the modular design further encourages modification and reuse of parts of the platform
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