Single- and Multi-Transducer Arrays Employing Nanoparticle Interface Layers as Vapor Detectors for a Microfabricated Gas Chromatograph.

This body of research focuses on improving microsensor arrays used as detectors in Si-microfabricated gas chromatographs (µGC) for the determination of volatile organic compounds (VOCs). By means of such improvements, µGC technology should find wider application in homeland security, disease diagnosis, and environmental monitoring. The microsensors considered here all employ thiolate-monolayer-protected gold nanoparticles (MPN) as vapor sorptive interface layers. The central hypothesis is that by altering the MPN ligand, core size, and/or the underlying transducer, the diversity of responses to VOCs provided by microsensor arrays with MPN interfaces can be improved. The first study evaluated a single transducer (ST) array of MPN-coated chemiresistors (CR) as a µGC detector for three semi-volatile markers of the explosive 2,4,6-trinitrotoluene in the presence of alkane interferences of similar volatility. The effects of flow rate and temperature on chromatographic resolution, sensitivity, and limits of detection (LOD) were assessed. Under optimized conditions, a complete analysis required 95%). These types of sensor arrays can enhance the vapor discrimination of sorption-based detectors utilized in µGC technology, making the analysis of complex VOC mixtures possible.PHDChemistryUniversity of Michigan, Horace H. Rackham School of Graduate Studieshttp://deepblue.lib.umich.edu/bitstream/2027.42/111430/1/lkamos_1.pd

Photonic low-cost sensors for in-line fluid monitoring. Design methodology

779 p.The paradigm of process monitoring has evolved in the last years, driven by a clear need for improving efficiency, quality and safety of processes and products. Sectors as manufacturing, energy, food and beverages, etc. are fostering the adoption of innovative methods for controlling their processes and products, in a non-destructive, in-place, reliable, fast, accurate and cost-efficient manner. Furthermore, the parameters requested by the industry for the quality assessment are evolving from basic magnitudes as pressures, temperatures, humidity, etc. to complete chemical and physical fingerprints of these products and processes. In this situation, techniques based on the UV/VIS/NIR light-matter interaction appear to be optimum candidates to face the request of the industry. Moreover, at this moment, when we are witnessing a technological revolution in the field of optoelectronic components, which are required for setting up these light-based analyzers.However, being able to integrate these optoelectronic components with the rest of subsystems (electronics, optics, mechanics, hydraulics, data processing, etc.) is not straightforward. The development of these multi-domain and heterogeneous sensor products meeting not just technological but also market objectives poses a considerable technical and organizational challenge for any company.In this context, a methodological hybrid and agile integration of photonic components within the rest of subsystems towards a sensor product development is presented as the main outcome of the thesis. The methodology has been validated in several industrial scenarios, being three of them included in this thesis, which covers from hydraulic fluid quality control to real-time monitoring of alcoholic beverage fermentation process

Photonic Technology for Precision Metrology

Photonics has had a decisive influence on recent scientific and technological achievements. It includes aspects of photon generation and photon–matter interaction. Although it finds many applications in the whole optical range of the wavelengths, most solutions operate in the visible and infrared range. Since the invention of the laser, a source of highly coherent optical radiation, optical measurements have become the perfect tool for highly precise and accurate measurements. Such measurements have the additional advantages of requiring no contact and a fast rate suitable for in-process metrology. However, their extreme precision is ultimately limited by, e.g., the noise of both lasers and photodetectors. The Special Issue of the Applied Science is devoted to the cutting-edge uses of optical sources, detectors, and optoelectronics systems in numerous fields of science and technology (e.g., industry, environment, healthcare, telecommunication, security, and space). The aim is to provide detail on state-of-the-art photonic technology for precision metrology and identify future developmental directions. This issue focuses on metrology principles and measurement instrumentation in optical technology to solve challenging engineering problems

VLSI Design

This book provides some recent advances in design nanometer VLSI chips. The selected topics try to present some open problems and challenges with important topics ranging from design tools, new post-silicon devices, GPU-based parallel computing, emerging 3D integration, and antenna design. The book consists of two parts, with chapters such as: VLSI design for multi-sensor smart systems on a chip, Three-dimensional integrated circuits design for thousand-core processors, Parallel symbolic analysis of large analog circuits on GPU platforms, Algorithms for CAD tools VLSI design, A multilevel memetic algorithm for large SAT-encoded problems, etc

Charakterisierung funktionaler Nanomaterialien für biomagnetische Sensoren und Atemanalyse

The presented thesis is covering materials aspects for the development of magnetoelectric sensors for biomagnetic sensing and solid state sensors for breath monitoring. The electrophysiological signals of the human body and especially their irregularities provide extremely valuable information about the heart, brain or nerve malfunction in medical diagnostics. Similar and even more detailed information is contained in the generated biomagnetic fields which measurement offers improved diagnostics and treatment of the patients. A new type of room temperature operable magnetoelectric composite sensors is developed in the framework of the CRC1261 Magnetoelectric Sensors: From Composite Materials to Biomagnetic Diagnostics. This thesis focuses on the individual materials structure-property relations and their combination in magnetoelectric composite sensors studied by electron beam based techniques, at lengths scales ranging from micrometers to atomic resolution. The first part of this thesis highlights selected studies on the structural and analytic aspects of single phase materials and their composites using TEM as the primary method of investigation. With respect to the piezoelectric phase, alternatives to AlN have been thoroughly investigated to seek for improvement of specific sensor approaches. In this context, the alloying of Sc into the AlN matrix has been demonstrated to yield high quality films with improved piezoelectric and unprecedented ferroelectric properties grown under the control of deposition parameters. Lead-free titanate films with large piezo-coefficients at the verge of the morphotropic phase boundary as alternative to PZT films have been investigated in terms of crystal symmetry, defect structure and domains of cation ordering. New morphologies of ZnO and GaN semiconductors envisioned for a piezotronic-based sensor approach were subject of in-depth defect and analytical studies describing intrinsic defects and lattice strains upon deposition as well as hollow composite structures. When the dimensions of a materials are reduced, novel exciting properties such as in-plane piezoelectricity can arise in planar transition-metal dichalcogenides. Here, the turbostratic disorder in a few-layered MoSe2 film has been investigated by nanobeam electron diffraction and Fast Fourier Transformations. From the perspective of magnetic materials, the atomic structure of magnetostrictive multilayers of FeCo/TiN showing stability up to elevated temperatures has been analyzed in detail regarding the crystallographic relationship of heteroepitaxy in multilayer composites exhibiting individual layer thicknesses below 1 nm. Further, magnetic hard layers have been investigated in the context of exchange spring concepts and ME composites based on shape memory alloy substrates have been studied regarding structural changes implied by different annealing processes. The second part of this thesis introduces materials aspects and sensor studies on gas detection in the clinical context of breath analysis. The detection of specific vapors in the human breath is of medical relevance, since certain species can be enriched depending on the conditions and processes within the human body. Hence, they can be regarded as biomarkers for the patients condition of health. The selection of suitable materials and the gas measurement working principle are considered and selected studies on solid state sensors with different surface functionalization or targeted application on basis of ZnO or CuO-oxide and Fe-oxide species are presented

Optoelectronics – Devices and Applications

Optoelectronics - Devices and Applications is the second part of an edited anthology on the multifaced areas of optoelectronics by a selected group of authors including promising novices to experts in the field. Photonics and optoelectronics are making an impact multiple times as the semiconductor revolution made on the quality of our life. In telecommunication, entertainment devices, computational techniques, clean energy harvesting, medical instrumentation, materials and device characterization and scores of other areas of R&D the science of optics and electronics get coupled by fine technology advances to make incredibly large strides. The technology of light has advanced to a stage where disciplines sans boundaries are finding it indispensable. New design concepts are fast emerging and being tested and applications developed in an unimaginable pace and speed. The wide spectrum of topics related to optoelectronics and photonics presented here is sure to make this collection of essays extremely useful to students and other stake holders in the field such as researchers and device designers

Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems

We present the science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems, targeting an evolution in technology, that might lead to impacts and benefits reaching into most areas of society. This roadmap was developed within the framework of the European Graphene Flagship and outlines the main targets and research areas as best understood at the start of this ambitious project. We provide an overview of the key aspects of graphene and related materials (GRMs), ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries. We also define an extensive list of acronyms in an effort to standardize the nomenclature in this emerging field.Peer ReviewedPostprint (published version

Innovative ozone sensors for environmental monitoring working at low temperature

L'abstract è presente nell'allegato / the abstract is in the attachmen