805 research outputs found

    Control and Power Supply for Resistance Spot Welding (RSW)

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    In the automobile industry, Resistance Spot Welding (RSW) is widely used for its low cost, high speed, simple mechanism and applicability for automation. RSW has become the predominant means of auto body assembly, resulting in two to six thousands spot welds performed on each manufactured car. In the North American automobile industry there are approximately 100 billion spot welds, which are done every year. RSW is the joining of two or more metal parts together in a localized area by resistive heating and pressure. Small Scale RSW (SSRSW) is commonly used for medical devices and electronic components, because the welded parts are thinner and smaller compared to common RSW applications, such as automotive applications. According to a study of Edison Welding Institute, 20% of the welding quality issues are the weld schedule or power supply related. Therefore, to contribute to weld quality improvement, the study of different weld schedules or power supplies and control schemes needs to be improved by doing further studies in this area. Thus a novel power supply, which can provide a testing bench for these studies, was designed and developed in 2005 by L. J. Brown and J. Lin. This research study will focus on studying and improving weld power supplies, weld schedules and control modes. One of the goals for this research is to improve the consistency of weld nugget size and strength by using different control parameters, which will be weighted geometric averages of voltage and current. These control parameters are fed back to a Proportional Integral Derivative (PID) controller that is designed to control the Direct Current (DC) power supply for the RSW to come up with the best control parameters that will improve the consistency of the RSW spot welds. Another goal for this research is it to further develop the existing DC power supply that was designed for SSRSW by L. J. Brown, to include tip voltage measurements, and Large Scale Resistance Spot Welding (LSRSW). This goal will lead to build additional weld modules to construct a 6000A welder in the future

    Battery Energy Storage Emulation for Power System Applications

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    The concept of energy storage for power systems has received increasingly more attention in recent decades, and the growing penetration of renewable energy sources has only escalated demand for it. Energy storage systems are excellent for balancing generation and load, for suppressing power fluctuations, and for providing other ancillary services to the grid. The Hardware Testbed (HTB) is a novel converter-based grid emulator created for studying the needs associated with high renewable penetration, but the system currently lacks a battery storage emulator. Thus, this work documents the development of a battery energy storage system (BESS) emulator for the HTB. The BESS emulator includes internal battery models for Lithium Ion, Lead Acid, and Vanadium redox flow battery technologies. The emulated BESS contains a two-stage power electronics interface using a DC-DC converter and a boost rectifier separated by a DC link. Controllers for active power output, reactive power output, and DC link voltage are designed for the power electronics interface, and application-specific control loops for primary frequency regulation, inertia emulation, and voltage support are also added. The models and control for this emulated BESS are implemented on a digital signal processor that controls one voltage source inverter on the HTB as if it were the BESSโ€™s boost rectifier. Consequently, the voltage source inverter mimics the behavior of a BESS at its point of common coupling with the HTBโ€™s power system. The BESS emulator is simulated and then tested experimentally on the HTB, and all of its control functions demonstrate correct operation. The BESS emulatorโ€™s primary frequency regulation and inertia emulation functions nearly eliminate the system frequency swing following a step change in load, and the voltage support keeps the BESS terminal voltage at a safer level following the disturbances. These three support functions are concluded to be capable of simultaneous operation, which allows the BESS emulator to support the HTBโ€™s power system in multiple ways at the same time. In the future, the BESS emulator can be used on the HTB to study how battery storage can be used to support renewables and other dynamic power system needs

    ์…€๋ฃฐ๋กœ์˜ค์Šค ๋‚˜๋…ธํ”ผ๋ธŒ๋ฆด ๊ธฐ๋ฐ˜ ๋ณตํ•ฉ์žฌ์˜ ์—ด์—๋„ˆ์ง€ ์ €์žฅ์šฉ ์ƒ๋ณ€ํ™” ๋ฌผ์งˆ์—์˜ ์ ์šฉ

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    ํ•™์œ„๋…ผ๋ฌธ(๋ฐ•์‚ฌ) -- ์„œ์šธ๋Œ€ํ•™๊ต๋Œ€ํ•™์› : ๋†์—…์ƒ๋ช…๊ณผํ•™๋Œ€ํ•™ ์‚ฐ๋ฆผ๊ณผํ•™๋ถ€(ํ™˜๊ฒฝ์žฌ๋ฃŒ๊ณผํ•™์ „๊ณต), 2021.8. Hak Lae Lee.Thermal energy storage (TES) has gathered intensive attention in recent decades due to its advantages of ease of use, cost-effectiveness and contribution to energy-saving. Phase change materials (PCMs) are the core part of a TES system, and the thermal energy can be stored and released through the phase transitions of PCMs. However, the drawbacks of PCMs have to be addressed to improve TES efficiency. Cellulose nanofibril (CNF), originated from natural cellulose, has numerous fascinating properties, such as abundant availability, biodegradability, renewability, recyclability and the easiness of various chemical modifications. Furthermore, CNF has light weight, high aspect ratio and high surface area, compared to larger-sized pulp fibers. In this study, CNF and CNF-based composites were prepared and used to overcome the drawbacks of PCMs, aiming at improving their thermal energy storage performance. The thickening effect of CNF, due to the entangled nanofibril networks, was used to solve the phase separation of sodium acetate trihydrate (SAT), a typical drawback of salt hydrate PCM. It was found that adding 0.8% of CNF to SAT increased viscosity, enhanced solid-like rheological behavior, and successfully eliminated phase separation. The use of 3% of sodium phosphate dibasic dodecahydrate (DSP) suppressed the supercooling degree of SAT to 2.1 ยฐC when CNF was used as the thickening agent for a stable phase. Meanwhile, the amphiphilicity of CNF facilitated the dispersion of graphene nanoplatelet (GNP), which was used as a thermal conductivity enhancer. When the prepared CNF/GNP composites were used to prepare SAT-based PCM composites, the supercooling degree was unaffected. Importantly, the prepared PCM composites showed enhanced thermal stability and thermal conductivity compared with that of pure SAT. Considering that CNF ensures the dispersion of nanoparticles, CNF/silver nanoparticles (AgNPs) composites were prepared to solve the supercooling problem of salt hydrate PCM. The synthesized AgNPs were uniformly dispersed by CNF and the prepared CNF/AgNPs were stable when added to SAT. The combined use of CNF/AgNPs composite and DSP further decreased the supercooling degree of SAT to only 1.2 ยฐC. SAT crystals grow on the surfaces of AgNPs, accelerating the crystallization process of SAT. Besides, the CNF/AgNPs composite provided phase stability to SAT, indicating that the presence of AgNPs did not negate the thickening effect of CNF. Owing to the excellent heat transfer performance of AgNPs, the thermal conductivity of the prepared PCM composites also improved, compared to that of the pure SAT. CNF-based foams were prepared to address the leakage problem of paraffin, a widely used organic PCM. The chemical modification of CNF improved the compatibility between the resulting foams and paraffin. These porous foam support greatly stabilized paraffin and prevented its leakage. Due to the light weight and high porosity of these foams, the prepared PCM composites had high fractions of paraffin. Carbon nanotube (CNT)-containing foams were used to enhance the thermal properties of PCM composites, and the uniform dispersion of CNT was achieved by the use of CNF. With the use of silylated CNF/CNF foams, the thermal properties of paraffin-based PCM composites were enhanced, while the high fractions of paraffin and negligible leakage of paraffin were maintained. CNF-based composites (i.e. CNF/GNP and CNF/AgNPs) provided phase stability to salt hydrate inorganic PCMs, CNF/AgNPs suppressed the supercooling, CNF/CNT foams improved the form-stability of paraffin organic PCMs, and these CNF-based composites improved the thermal conductivity of all PCMs. This work shows the potential of CNF-based composites in improving the thermal energy storage performance of PCMs.์—ด์—๋„ˆ์ง€ ์ €์žฅ(TES) ๊ธฐ์ˆ ์€ ์‚ฌ์šฉ์ด ์šฉ์ดํ•  ๋ฟ ์•„๋‹ˆ๋ผ ๋น„์šฉ ์ ˆ๊ฐ, ์—๋„ˆ์ง€ ์ ˆ์•ฝ ์ธก๋ฉด์—์„œ ์žฅ์ ์„ ์ง€๋‹ˆ๊ธฐ์— ์ตœ๊ทผ ๋งŽ์€ ์ฃผ๋ชฉ์„ ๋ฐ›์•„์™”๋‹ค. ์ƒ๋ณ€ํ™”๋ฌผ์งˆ(PCMs)์€ TES ์‹œ์Šคํ…œ์˜ ํ•ต์‹ฌ ์š”์†Œ๋กœ์จ, ์ƒ๋ณ€ํ™”๋ฌผ์งˆ์˜ ์ƒ ๋ณ€์ด์— ๋”ฐ๋ผ ์—ด์—๋„ˆ์ง€๊ฐ€ ์ €์žฅ๋˜๊ณ  ๋ฐฉ์ถœ๋œ๋‹ค. ๊ทธ๋Ÿฌ๋‚˜, TES ์‹œ์Šคํ…œ์˜ ํšจ์œจ์„ ๋†’์ด๊ธฐ ์œ„ํ•ด์„œ๋Š” PCMs์˜ ๋‹จ์ ๋“ค์„ ๊ฐœ์„ ํ•ด์•ผํ•œ๋‹ค. ์…€๋ฃฐ๋กœ์˜ค์Šค ๋‚˜๋…ธํ”ผ๋ธŒ๋ฆด(CNF)์€ ์ฒœ์—ฐ ์…€๋ฃฐ๋กœ์˜ค์Šค๋กœ๋ถ€ํ„ฐ ์œ ๋ž˜๋œ ์ƒ๋ถ„ํ•ด๊ฐ€ ๊ฐ€๋Šฅํ•œ ๋ฌผ์งˆ๋กœ์„œ, ๊ณต๊ธ‰์›์ด ๋‹ค์–‘ํ•˜๋ฉฐ, ์žฌ์ƒ๊ณผ ์žฌ์‚ฌ์šฉ์ด ๊ฐ€๋Šฅํ•  ๋ฟ ์•„๋‹ˆ๋ผ ๋‹ค์–‘ํ•œ ํ™”ํ•™์  ๊ฐœ์งˆ์ด ๊ฐ€๋Šฅํ•˜๋‹ค๋Š” ๋“ฑ ์ˆ˜๋งŽ์€ ๋งค๋ ฅ์ ์ธ ํŠน์ง•์„ ์ง€๋‹ˆ๋Š” ๋ฌผ์งˆ์ด๋‹ค. ๊ฒŒ๋‹ค๊ฐ€, CNF๋Š” ํฐ ์‚ฌ์ด์ฆˆ์˜ ํŽ„ํ”„ ์„ฌ์œ ๋“ค์— ๋น„ํ•ด ๊ฐ€๋ณ๊ณ , ์ข…ํšก๋น„๊ฐ€ ํฌ๊ณ , ๋†’์€ ํ‘œ๋ฉด์ ์„ ์ง€๋‹ˆ๊ณ  ์žˆ๋‹ค. ๋ณธ ์—ฐ๊ตฌ๋Š” CNF์™€ CNF ๊ธฐ๋ฐ˜ ๋ณตํ•ฉ์žฌ๋ฅผ ์ค€๋น„, ํ™œ์šฉํ•˜์—ฌ PCMs์˜ ๋‹จ์ ์„ ๊ทน๋ณตํ•˜๊ณ ์ž ํ•˜์˜€์œผ๋ฉฐ, ์—ด์—๋„ˆ์ง€ ์ €์žฅ ์„ฑ๋Šฅ์„ ํ–ฅ์ƒ์‹œํ‚ค๋Š” ๊ฒƒ์„ ๋ชฉ์ ์œผ๋กœ ํ•˜์˜€๋‹ค. ๋‚˜๋…ธ์„ฌ์œ ์˜ ๊ณ ์œ ํ•œ ๋„คํŠธ์›Œํฌ ํ˜•์„ฑ๋Šฅ๋ ฅ์— ์˜ํ•ด ๋ฐœ์ƒํ•˜๋Š” CNF์˜ ์ฆ์ ํšจ๊ณผ๋ฅผ ์ด์šฉํ•˜์—ฌ ์—ผ์ˆ˜ํ™”๋ฌผ PCM์˜ ํ•˜๋‚˜์ธ ์•„์„ธํŠธ์‚ฐ๋‚˜ํŠธ๋ฅจ ์‚ผ์ˆ˜ํ™”๋ฌผ(SAT)์˜ ์ „ํ˜•์ ์ธ ์ƒ ๋ถ„๋ฆฌ ํ˜„์ƒ์˜ ๋‹จ์ ์„ ๊ฐœ์„ ํ•˜์˜€๋‹ค. SAT์— 0.8%์˜ CNF๋ฅผ ์ฒจ๊ฐ€ํ•˜๋Š” ๊ฒƒ์œผ๋กœ ์ ๋„์™€ ์ €์žฅํƒ„์„ฑ๊ณ„์ˆ˜๋ฅผ ํ–ฅ์ƒ์‹œํ‚ค๊ณ , ์ƒ๋ณ€ํ™”๋ฅผ ๋ฐฉ์ง€ํ•  ์ˆ˜ ์žˆ์—ˆ๋‹ค. CNF๊ฐ€ ์ฆ์ ์ œ๋กœ ์‚ฌ์šฉ๋˜์–ด ์•ˆ์ •๋œ ์ƒ์ด ์œ ์ง€๋  ๋•Œ, 3%์˜ ์ธ์‚ฐ๋‚˜ํŠธ๋ฅจ ์ด์—ผ๊ธฐ์„ฑ ์‹ญ์ด์ˆ˜ํ™”๋ฌผ(DSP)์˜ ์‚ฌ์šฉ์€ SAT์˜ ๊ณผ๋ƒ‰๊ฐ ์ •๋„๋ฅผ 2.1 ยฐC ์–ต์ œํ•˜์˜€๋‹ค. ํ•œํŽธ, CNF์˜ ์–‘์นœ์„ฑ์€ ์—ด์ „๋„์„ฑ ํ–ฅ์ƒ์ œ๋กœ ์‚ฌ์šฉ๋œ ๊ทธ๋ž˜ํ•€ ๋‚˜๋…ธํŒ (GNP)์˜ ๋ถ„์‚ฐ์„ ์šฉ์ดํ•˜๊ฒŒ ํ•˜์˜€๋‹ค. CNF/GNP ๋ณตํ•ฉ์žฌ๊ฐ€ SAT ๊ธฐ๋ฐ˜ PCM ๋ณตํ•ฉ์žฌ๋ฅผ ์ œ์ž‘ํ•˜๋Š” ๋ฐ ์‚ฌ์šฉ๋˜์—ˆ์„ ๋•Œ, ๊ณผ๋ƒ‰๊ฐ ์ •๋„๋Š” ์˜ํ–ฅ ๋ฐ›์ง€ ์•Š์•˜๋‹ค. ๋”์šฑ์ด, ์ œ์ž‘๋œ PCM ๋ณตํ•ฉ์žฌ๋Š” ์ˆœ์ˆ˜ํ•œ SAT์— ๋น„ํ•ด ํ–ฅ์ƒ๋œ ์—ด์•ˆ์ •์„ฑ๊ณผ ์—ด ์ „๋„์„ฑ์„ ๋ณด์˜€๋‹ค. CNF๊ฐ€ ๋‚˜๋…ธ ์ž…์ž๋“ค์˜ ๋ถ„์‚ฐ์„ ์ด‰์ง„ํ•œ๋‹ค๋Š” ์ ์„ ๊ณ ๋ คํ•˜์—ฌ, CNF/์€ ๋‚˜๋…ธ์ž…์ž (AgNPs) ๋ณตํ•ฉ์žฌ๊ฐ€ ์—ผ์ˆ˜ํ™”๋ฌผ PCM์˜ ๊ณผ๋ƒ‰๊ฐ ๋ฌธ์ œ๋ฅผ ํ•ด๊ฒฐํ•˜๊ธฐ ์œ„ํ•ด ํ™œ์šฉ๋˜์—ˆ๋‹ค. CNF๋Š” ํ•ฉ์„ฑ๋œ AgNPs์˜ ๋ถ„์‚ฐ๊ท ์ผ์„ฑ์„ ํ–ฅ์ƒ์‹œ์ผฐ์œผ๋ฉฐ, ์ œ์ž‘๋œ CNF/AgNPs ๋ณตํ•ฉ์žฌ๋ฅผ SAT์— ์ฒจ๊ฐ€ํ•˜์˜€์„ ๋•Œ ๋†’์€ ์•ˆ์ •์„ฑ์„ ๋ณด์˜€๋‹ค. CNF/AgNPs ๋ณตํ•ฉ์žฌ์™€ DSP๋ฅผ ํ•จ๊ป˜ ์‚ฌ์šฉํ•จ์œผ๋กœ์จ SAT์˜ ๊ณผ๋ƒ‰๊ฐ ์ •๋„๋ฅผ ๋‹จ 1.2 ยฐC๋กœ ๋” ๊ฐ์†Œ์‹œํ‚ฌ ์ˆ˜ ์žˆ์—ˆ๋‹ค. AgNPs์˜ ํ‘œ๋ฉด์— SAT ๊ฒฐ์ •์ด ์ž๋ผ๋‚จ์— ๋”ฐ๋ผ, SAT์˜ ๊ฒฐ์ •ํ™” ๊ณผ์ •์ด ์ด‰์ง„๋˜์—ˆ๋‹ค. ๊ฒŒ๋‹ค๊ฐ€, CNF/AgNPs ๋ณตํ•ฉ์žฌ๋Š” SAT์— ์ƒ ์•ˆ์ •์„ฑ์„ ๋ถ€์—ฌํ•˜์˜€๊ณ , ์ด๋Š” AgNPs์˜ ์กด์žฌ๊ฐ€ CNF์˜ ์ฆ์  ํšจ๊ณผ๋ฅผ ๋ฐฉํ•ดํ•˜์ง€ ์•Š๋Š”๋‹ค๋Š” ๊ฒƒ์„ ์˜๋ฏธํ•œ๋‹ค. AgNPs์˜ ์šฐ์ˆ˜ํ•œ ์—ด ์ „๋„ ์„ฑ๋Šฅ์€ ์ˆœ์ˆ˜ํ•œ SAT์— ๋น„ํ•ด ์ œ์ž‘๋œ PCM ๋ณตํ•ฉ์žฌ์˜ ์—ด์ „๋„์„ฑ์„ ํ–ฅ์ƒ์‹œ์ผฐ๋‹ค. ๋„๋ฆฌ ์“ฐ์ด๋Š” ์œ ๊ธฐ๋ฌผ์งˆ ๊ธฐ๋ฐ˜์˜ PCM์ธ ํŒŒ๋ผํ•€์˜ ๋ˆ„์ถœ ๋ฌธ์ œ๋ฅผ ํ•ด๊ฒฐํ•˜๊ธฐ ์œ„ํ•ด CNF ๊ธฐ๋ฐ˜์˜ ํผ์„ ํ™œ์šฉํ•˜์˜€๋‹ค. CNF์˜ ํ™”ํ•™์  ๊ฐœ์งˆ์€ ์ œ์ž‘๋˜๋Š” ํผ๊ณผ ํŒŒ๋ผํ•€ ๊ฐ„ ํ™”ํ•ฉ์„ ์ฆ์ง„์‹œ์ผฐ๋‹ค. ์ด ๋‹ค๊ณต์„ฑ ํผ ์ง€์ง€๋Œ€๋Š” ํŒŒ๋ผํ•€์„ ๋งค์šฐ ์•ˆ์ •ํ™”์‹œํ‚ด์œผ๋กœ์จ ์ด์˜ ๋ˆ„์ถœ์„ ๋ฐฉ์ง€ํ•˜์˜€๋‹ค. ์ด ํผ๋“ค์€ ๊ฐ€๋ณ๊ณ  ๋†’์€ ๊ณต๊ทน๋ฅ ์„ ๋‚˜ํƒ€๋‚ด๊ธฐ์—, ์ œ์ž‘๋œ PCM ๋ณตํ•ฉ์žฌ๋Š” ๋†’์€ ๋น„์œจ๋กœ ํŒŒ๋ผํ•€์„ ํƒ‘์žฌํ•  ์ˆ˜ ์žˆ์—ˆ๋‹ค. PCM ๋ณตํ•ฉ์žฌ์˜ ์—ด ํŠน์„ฑ์„ ํ–ฅ์ƒ์‹œํ‚ค๊ธฐ ์œ„ํ•ด ํƒ„์†Œ ๋‚˜๋…ธํŠœ๋ธŒ (CNT)๋ฅผ ํ•จ์œ ํ•˜๋Š” ํผ์„ ํ™œ์šฉํ•˜์˜€๊ณ , CNF๋ฅผ ํ™œ์šฉํ•˜์—ฌ CNT๋ฅผ ๊ท ์ผํ•˜๊ฒŒ ๋ถ„์‚ฐ์‹œํ‚ฌ ์ˆ˜ ์žˆ์—ˆ๋‹ค. ์‹ค๋ž€ํ™” CNF/CNF ํผ์„ ์ด์šฉํ•˜์—ฌ, ํŒŒ๋ผํ•€ ๊ธฐ๋ฐ˜์˜ PCM ๋ณตํ•ฉ์žฌ์˜ ์—ด ํŠน์„ฑ์„ ํ–ฅ์ƒ์‹œํ‚ค๊ณ , ๋†’์€ ํŒŒ๋ผํ•€ ํ•จ๋Ÿ‰์„ ์œ ์ง€์‹œํ‚ค๋ฉด์„œ๋„ ๋ˆ„์ถœ์„ ๋ฐฉ์ง€ํ•  ์ˆ˜ ์žˆ์—ˆ๋‹ค. CNF ๊ธฐ๋ฐ˜์˜ ๋ณตํ•ฉ์žฌ (์ฆ‰, CNF/GNP์™€ CNF/AgNPs)๋Š” ๋ฌด๊ธฐ๋ฌผ์งˆ ๊ธฐ๋ฐ˜์˜ ์—ผ์ˆ˜ํ™”๋ฌผ PCM์— ์ƒ ์•ˆ์ •์„ฑ์„ ๋ถ€์—ฌํ•˜๊ณ , CNF/AgNPs๋Š” ๊ณผ๋ƒ‰๊ฐ์„ ์–ต์ œํ•˜๋ฉฐ, CNF/CNT ํผ์€ ํŒŒ๋ผํ•€ ์œ ๊ธฐ ๋ฌผ์งˆ ๊ธฐ๋ฐ˜์˜ PCM์˜ ํผ ์•ˆ์ •์„ฑ์„ ํ–ฅ์ƒ์‹œํ‚ค๊ณ , CNF ๊ธฐ๋ฐ˜์˜ ๋ณตํ•ฉ์žฌ๋“ค์€ ๋ชจ๋“  PCM๋“ค์˜ ์—ด์ „๋„์„ฑ์„ ํ–ฅ์ƒ์‹œ์ผฐ๋‹ค. ๋ณธ ์—ฐ๊ตฌ๋Š” CNF๊ธฐ๋ฐ˜์˜ ๋ณตํ•ฉ์žฌ๊ฐ€ ์ƒ๋ณ€ํ™”๋ฌผ์งˆ์˜ ์—ด์—๋„ˆ์ง€ ์ €์žฅ ์„ฑ๋Šฅ์„ ํ–ฅ์ƒ์‹œํ‚ฌ ์ˆ˜ ์žˆ๋Š” ์ž ์žฌ๋ ฅ์ด ์žˆ์Œ์„ ๋ณด์—ฌ์ฃผ์—ˆ๋‹ค.Chapter 1 Introduction 1 1. Introduction 2 1.1 Energy crisis and energy storage 2 1.2 Thermal energy storage 4 1.2.1 Sensible heat storage 4 1.2.2 Latent heat storage 6 1.3 Introduction of PCMs 9 1.3.1 Organic PCMs 12 1.3.2 Eutectic PCMs 14 1.3.3 Inorganic PCMs 15 1.4 Barriers of PCMs for efficient TES 19 1.4.1 Phase separation of salt hydrates 20 1.4.2 Supercooling of salt hydrates 21 1.4.3 Thermal conductivity insufficiency of PCMs 24 1.4.4 Poor form-stability of paraffin 26 1.5 The potential of CNF to improve the performance of PCMs 28 2. Objectives 34 3. Literature review 36 3.1 Sodium acetate trihydrate for TES 36 3.2 Solutions to eliminating the phase separation 39 3.3 Nucleating agents for supercooling suppression 43 3.4 Ways to enhance the thermal conductivity 47 3.5 Methods to improve the form-stability of paraffin 52 Chapter 2 Preparation and application of CNF/GNP composites in salt hydrate PCM 56 1. Introduction 57 2. Experimental 61 2.1 Materials 61 2.2 Methods 61 2.2.1 Preparation of CNF 61 2.2.2 Preparation of CNF/GNP composites 62 2.2.3 Preparation of PCM composites 62 2.2.4 Phase stability and fluidity tests 63 2.2.5 Rheology tests 63 2.2.6 Determination of supercooling degrees 64 2.2.7 Transmission electron microscopy 65 2.2.8 Field-emission scanning electron microscopy 65 2.2.9 Fourier transform-infrared spectroscopy 66 2.2.10 X-ray diffraction 66 2.2.11 Differential scanning calorimetry 66 2.2.12 Thermogravimetric analysis 67 2.2.13 Measurement of thermal conductivity 67 2.2.14 Thermal reliability tests 68 3. Results and discussion 69 3.1 Effectiveness of CNF in eliminating phase separation 69 3.2 Screening of suitable nucleating agents 73 3.3 Incorporation of CNF/GNP to fabricate PCM composites 76 3.4 Morphology and structures of PCM composites 82 3.5 Thermal properties of PCM composites 86 4. Summary 94 Chapter 3 Preparation and application of CNF/AgNPs composites in salt hydrate PCM 95 1. Introduction 96 2. Experimental 100 2.1 Materials 100 2.2 Methods 100 2.2.1 Preparation of CNF 100 2.2.2 Synthesis of CNF/AgNPs composites 100 2.2.3 Preparation of PCM composites 101 2.2.4 Transmission electron microscopy 102 2.2.5 Measurement of particle size and its distribution 102 2.2.6 UV-visible spectroscopy 102 2.2.7 Determination of silver content 103 2.2.8 Measurement of supercooling degrees 103 2.2.9 Phase stability and fluidity tests 104 2.2.10 Field-emission scanning electron microscopy 104 2.2.11 Fourier transform-infrared spectroscopy 104 2.2.12 X-ray diffraction 105 2.2.13 Differential scanning calorimetry 105 2.2.14 Thermogravimetric analysis 105 2.2.15 Measurement of thermal conductivity 106 2.2.16 Thermal reliability tests 106 3. Results and discussion 107 3.1 Characterizations of CNF/AgNPs composites 107 3.2 Effect of CNF/AgNPs composites on supercooling suppression 112 3.3 Phase stability and physical structures of PCM composites 117 3.4 Chemical structures of PCM composites 122 3.5 Thermal properties of PCM composites 125 4. Summary 133 Chapter 4 Preparation and application of CNF/CNT composite foams in organic PCM 134 1. Introduction 135 2. Experimental 138 2.1 Materials 138 2.2 Methods 138 2.2.1 Preparation of CNF 138 2.2.2 Preparation of CNF/CNT composites 139 2.2.3 Preparation of foams 139 2.2.4 Measurement of density and porosity of foams 140 2.2.5 Measurement of water contact angles 141 2.2.6 Preparation of foam-stabilized PCM composites 141 2.2.7 Transmission electron microscopy 142 2.2.8 Field-emission scanning electron microscopy 142 2.2.9 Leakage tests 142 2.2.10 Fourier transform-infrared spectroscopy 143 2.2.11 X-ray diffraction 143 2.2.12 Differential scanning calorimetry 144 2.2.13 Thermogravimetric analysis 144 2.2.14 Measurement of thermal conductivity 144 2.2.15 Heat transfer analysis 145 2.2.16 Thermal reliability tests 145 2.2.17 Test of PCM composite in solar-thermal-electricity system 146 3. Results and discussion 147 3.1 Characterizations of SCNF foams and their paraffin-stabilization effect 149 3.2 Characterizations of SCNF/CNT foams and their paraffin-stabilization effect 157 3.3 Physical and chemical structures of PCM composites 165 3.4 Phase change and thermal properties of PCM composites 169 3.5 Thermal reliability and practical application 175 4. Summary 183 Chapter 5 Overall conclusions and future work 184 1. Performance improvement of inorganic salt hydrate PCM 186 2. Performance improvement of organic PCM 188 3. Future work 190 References 192 ์ดˆ ๋ก 231๋ฐ•

    Novel Metamaterials and Their Applications in Subwavelength Waveguides, Imaging and Modulation

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    The development of metamaterials has opened the door for engineering electromagnetic properties by subwavelength artificial atoms , and hence accessing new properties and functionalities which cannot be found among naturally occurring materials. In particular, metamaterials enable the flexibility of independently controlling the permittivity and permeability to be almost any arbitrary value, which promises to achieve deep subwavelength confinement and focusing of electromagnetic waves in different spectrum regimes. The next stage of this technological revolution will be focused on the development of active and controllable metamaterials, where the properties of the metamaterials are expected to be tuned by external stimuli. In this sense, some natural materials are also promising to provide the tunable capability, particularly in the near infrared and terahertz domains either by applying a voltage or shining light on the materials. The objective of this dissertation is to investigate novel metamaterials and explore three important applications of them: subwavelength waveguiding, imaging and modulation. The first part of this dissertation covers the theory, design and fabrication of several different types of metamaterials, which includes artificially designed metamaterials and some naturally existing materials. The second part demonstrates metal gratings functioning as designer surface plasmonic waveguides support deep subwavelength surface propagation modes at microwave frequency. The third part proposes multilayered metal-insulator stack as indefinite metamaterial that converts evanescent waves to propagating waves, hence deep subwavelength image can be observed. The fourth part explores the tunability of several natural materials - gallium (Ga), indium tin oxide (ITO) and graphene, and demonstrates electro-optical (EO) modulators based on these materials can be achieved on nano-scale. The final part summarizes the work presented in this dissertation and also discusses some future work for photodetection, photovoltaics, and modulation

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    Ultrasonic systems are widely used in many fields of non-destructive testing. The increasing requirement for high quality steel product stirs the improvement of both ultrasonic instruments and testing methods. The thesis indicates the basics of ultrasonic testing and Digital Signal Processing (DSP) technology for the development of an ultrasonic system. The aim of this project was to apply a new ultrasonic testing method - the Normal Probe Diffraction method to course grained steel in real-time and investigate whether the potential of probability of detection (POD) has been improved. The theories and corresponding experiment set-up of pulse-echo method, TOFD and NPD method are explained and demonstrated separately. A comparison of these methods shows different contributions made by these methods using different types of algorithms and signals. Non-real-time experiments were carried out on a VI calibration block using an USPC 3100 ultrasonic testing card to implement pulse-echo and NPD method respectively. The experiments and algorithm were simulated and demonstrated in Matlab. A low frequency Single-transmitter-multi-receiver ultrasonic system was designed and built with a digital development board and an analogue daughter card to transmit or receive signals asynchronously. A high frequency high voltage amplifier was designed to drive the ultrasonic probes. A Matlab simulation system built with Simulink indicates that the Signal to Noise Ratio (SNR) can be improved with an increment of up to 3dB theoretically based on the simulation results using DSP techniques. The DSP system hardware and software was investigated and a real-time DSP hardware system was supposed to be built to implement the high frequency system using a rapid code generated system based on Matlab Simulink model and the method was presented. However, extra effort needs to be taken to program the hardware using a low-level computer language to make the system work stably and efficiently

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    This thesis examines the capabilities of different Rapid Prototyping (RP) manufacturing processes for producing sound metallic parts incorporating features in the micrometre range using the Investment Casting (IC) process. RP has been growing in the past twenty years and is nowadays widely employed in the area of precision investment casting since the technology offers the possibility of manufacturing wax patterns which can be directly implemented into investment casting. Owing to the steady improvements of the technology, some of the recently developed RP building machines offer the possibility of manufacturing small parts incorporating micro-features. In this work, a detailed description of the accuracy and capabilities of the IC process regarding its potential for producing sound meso/micro components is given using two types of conventional RP machines. The results of this analysis are then compared through a benchmarking study with a recently developed RP process suitable for the direct manufacture of ceramic moulds. The different technological chains are compared regarding their overall accuracy, surface finish, the amount of structural defects present in the castings and their relative production costs and lead-time. Finally, the potential of the investment casting process for manufacturing sound micro-castings with high aspect ratio is approached from a structural point of view. Through a metallographic analysis study, the research investigates the size-scale effect of cast micro-components upon their microstructure and the subsequent changes in their mechanical properties

    NASA's Microgravity Technology Report, 1996: Summary of Activities

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    This report covers technology development and technology transfer activities within the Microgravity Science Research Programs during FY 1996. It also describes the recent major tasks under the Advanced Technology Development (ATD) Program and identifies current technology requirements. This document is consistent with NASA,s Enteprise for the Human Exploration and development of Space (HEDS) Strategic Plan. This annual update reflects changes in the Microgravity Science Research Program's new technology activities and requirements. Appendix A. FY 1996 Advanced Technology Development. Program and Project Descriptions. Appendix B. Technology Development
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