Stability of Colloidal Quasicrystals

Freezing of charge-stabilized colloidal suspensions and relative stabilities of crystals and quasicrystals are studied using thermodynamic perturbation theory. Macroion interactions are modelled by effective pair potentials combining electrostatic repulsion with polymer-depletion or van der Waals attraction. Comparing free energies -- counterion terms included -- for elementary crystals and rational approximants to icosahedral quasicrystals, parameters are identified for which one-component quasicrystals are stabilized by a compromise between packing entropy and cohesive energy.Comment: 6 pages, 4 figure

Thermodynamically Stable One-Component Metallic Quasicrystals

Classical density-functional theory is employed to study finite-temperature trends in the relative stabilities of one-component quasicrystals interacting via effective metallic pair potentials derived from pseudopotential theory. Comparing the free energies of several periodic crystals and rational approximant models of quasicrystals over a range of pseudopotential parameters, thermodynamically stable quasicrystals are predicted for parameters approaching the limits of mechanical stability of the crystalline structures. The results support and significantly extend conclusions of previous ground-state lattice-sum studies.Comment: REVTeX, 13 pages + 2 figures, to appear, Europhys. Let

Time Quasilattices in Dissipative Dynamical Systems

We establish the existence of `time quasilattices' as stable trajectories in dissipative dynamical systems. These tilings of the time axis, with two unit cells of different durations, can be generated as cuts through a periodic lattice spanned by two orthogonal directions of time. We show that there are precisely two admissible time quasilattices, which we term the infinite Pell and Clapeyron words, reached by a generalization of the period-doubling cascade. Finite Pell and Clapeyron words of increasing length provide systematic periodic approximations to time quasilattices which can be verified experimentally. The results apply to all systems featuring the universal sequence of periodic windows. We provide examples of discrete-time maps, and periodically-driven continuous-time dynamical systems. We identify quantum many-body systems in which time quasilattices develop rigidity via the interaction of many degrees of freedom, thus constituting dissipative discrete `time quasicrystals'.Comment: 38 pages, 14 figures. This version incorporates "Pell and Clapeyron Words as Stable Trajectories in Dynamical Systems", arXiv:1707.09333. Submission to SciPos

Proliferation of anomalous symmetries in colloidal monolayers subjected to quasiperiodic light fields

Quasicrystals provide a fascinating class of materials with intriguing properties. Despite a strong potential for numerous technical applications, the conditions under which quasicrystals form are still poorly understood. Currently, it is not clear why most quasicrystals hold 5- or 10-fold symmetry but no single example with 7 or 9-fold symmetry has ever been observed. Here we report on geometrical constraints which impede the formation of quasicrystals with certain symmetries in a colloidal model system. Experimentally, colloidal quasicrystals are created by subjecting micron-sized particles to two-dimensional quasiperiodic potential landscapes created by n=5 or seven laser beams. Our results clearly demonstrate that quasicrystalline order is much easier established for n = 5 compared to n = 7. With increasing laser intensity we observe that the colloids first adopt quasiperiodic order at local areas which then laterally grow until an extended quasicrystalline layer forms. As nucleation sites where quasiperiodicity originates, we identify highly symmetric motifs in the laser pattern. We find that their density strongly varies with n and surprisingly is smallest exactly for those quasicrystalline symmetries which have never been observed in atomic systems. Since such high symmetry motifs also exist in atomic quasicrystals where they act as preferential adsorption sites, this suggests that it is indeed the deficiency of such motifs which accounts for the absence of materials with e.g. 7-fold symmetry

Symmetry Breaking and Order in the Age of Quasicrystals

The discovery of quasicrystals has changed our view of some of the most basic notions related to the condensed state of matter. Before the age of quasicrystals, it was believed that crystals break the continuous translation and rotation symmetries of the liquid-phase into a discrete lattice of translations, and a finite group of rotations. Quasicrystals, on the other hand, possess no such symmetries-there are no translations, nor, in general, are there any rotations, leaving them invariant. Does this imply that no symmetry is left, or that the meaning of symmetry should be revised? We review this and other questions related to the liquid-to-crystal symmetry-breaking transition using the notion of indistinguishability. We characterize the order-parameter space, describe the different elementary excitations, phonons and phasons, and discuss the nature of dislocations-keeping in mind that we are now living in the age of quasicrystals.Comment: To appear in a special issue on quasicrystals of The Israel Journal of Chemistry, in celebration of the 2011 Nobel Prize in Chemistr