Light trapping structures for photovoltaics using silicon nanowires and silicon micro-pyramids

The current photovoltaic industry is dominated by crystalline or poly-crystalline Si in a planar pn-junction configuration. The use of silicon nanowire arrays (SiNWA) within this industry has shown great promise due to its application as an anti-reflective layer, as well as benefits in charge carrier extraction. In this work, we use a metal assisted chemical etch process to fabricate SiNWAs onto a dense periodic array of pyramids that are formed using an alkaline etch masked with an oxide layer. The hybrid micro-nano structure acts as an anti-reflective coating with experimental reflectivity below 1% over the visible and near-infrared spectral regions. This represents an improvement of up to 11 and 14 times compared to the pyramid array and SiNWAs on bulk, respectively. In addition to the experimental work, we optically simulate the hybrid structure using the commercial Lumerical FDTD package. The results of the optical simulations support our experimental work, illustrating a reduced reflectivity in the hybrid structure. The nanowire array increases the absorbed carrier density within the pyramid by providing a guided transition of the refractive index along the light path from air into the silicon. Furthermore, electrical simulations which take into account surface and Auger recombination show an effi ciency increase for the hybrid structure of 56% over bulk, 11% over pyramid array and 8.5% over SiNWAs. Opto-electronic modelling was performed by establishing a tool flow to integrate the eff ective optical simulator Lumerical FDTD with the excellent fabrication and electrical simulation capability of Sentaurus TCAD. Interfacing between the two packages is achieved through tool command language and Matlab, off ering fast and accurate electro-optical characteristics of nano-structured PV devices.Open Acces

Efficient Many-Light Rendering of Scenes with Participating Media

We present several approaches based on virtual lights that aim at capturing the light transport without compromising quality, and while preserving the elegance and efficiency of many-light rendering. By reformulating the integration scheme, we obtain two numerically efficient techniques; one tailored specifically for interactive, high-quality lighting on surfaces, and one for handling scenes with participating media

Optical Cerebral Blood Flow Monitoring of Mice to Men

This thesis describes cerebral hemodynamic monitoring with the optical techniques of diffuse optical spectroscopy (DOS) and diffuse correlation spectroscopy (DCS). DOS and DCS both employ near-infrared light to investigate tissue physiology millimeters to centimeters below the tissue surface. DOS is a static technique that analyzes multispectral tissue-scattered light intensity signals with a photon diffusion approach (Chapter 2) or a Modified Beer-Lambert law approach (Chapter 3) to derive tissue oxy- and deoxy-hemoglobin concentrations, which are in turn used to compute tissue oxygen saturation and blood volume (Section 2.13). DCS is a qualitatively different dynamic technique that analyzes rapid temporal fluctuations in tissue-scattered light with a correlation diffusion approach to derive tissue blood flow (Chapter 4). Further, in combination these measurements of blood flow and blood oxygenation provide access to tissue oxygen metabolism (Section 7.6). The new contributions of my thesis to the diffuse optics field are a novel analysis technique for the DCS signal (Chapter 5), and a novel approach for separating cerebral hemodynamic signals from extra-cerebral artifacts (Chapter 6). The DCS analysis technique extends the Modified Beer-Lambert approach for DOS to the DCS measurement. This new technique has some useful advantages compared to the correlation diffusion approach. It facilitates real-time flow monitoring in complex tissue geometries, provides a novel route for increasing DCS measurement speed, and can be used to probe tissues wherein light transport is non-diffusive (Chapter 5). It also can be used to filter signals from superficial tissues. For separation of cerebral hemodynamic signals from extra-cerebral artifacts, the Modified Beer-Lambert approach is employed in a pressure modulation scheme, which determines subject-specific contributions of extra-cerebral and cerebral tissues to the DCS/DOS signals by utilizing probe pressure modulation to induce variations in extra-cerebral hemodynamics while cerebral hemodynamics remain constant (Chapter 6). In another novel contribution, I used optical techniques to characterize neurovascular coupling at several levels of cerebral ischemia in a rat model (Chapter 7). Neurovascular coupling refers to the relationship between increased blood flow and oxygen metabolism and increased neuronal activity in the brain. In the rat, localized neuronal activity was increased from functional forepaw stimulation. Under normal flow levels, I (and others) observed that the increase in cerebral blood flow (surrogate for oxygen delivery) from forepaw stimulation exceeded the increase in cerebral oxygen metabolism by about a factor of 2. My measurements indicate that this mismatch between oxygen delivery and consumption are more balanced during ischemia (Chapter 7). In Chapters 2 and 3, I review the underlying theory for the photon diffusion model and the Modified Beer-Lambert law for DOS analysis. I also review the correlation diffusion approach for analyzing DCS signals in Chapter 4. My hope is that readers new to the field will find these background chapters helpful

Engineering aperiodic spiral order for photonic-plasmonic device applications

Thesis (Ph.D.)--Boston UniversityDeterministic arrays of metal (i.e., Au) nanoparticles and dielectric nanopillars (i.e., Si and SiN) arranged in aperiodic spiral geometries (Vogel's spirals) are proposed as a novel platform for engineering enhanced photonic-plasmonic coupling and increased light-matter interaction over broad frequency and angular spectra for planar optical devices. Vogel's spirals lack both translational and orientational symmetry in real space, while displaying continuous circular symmetry (i.e., rotational symmetry of infinite order) in reciprocal Fourier space. The novel regime of "circular multiple light scattering" in finite-size deterministic structures will be investigated. The distinctive geometrical structure of Vogel spirals will be studied by a multifractal analysis, Fourier-Bessel decomposition, and Delaunay tessellation methods, leading to spiral structure optimization for novel localized optical states with broadband fluctuations in their photonic mode density. Experimentally, a number of designed passive and active spiral structures will be fabricated and characterized using dark-field optical spectroscopy, ellipsometry, and Fourier space imaging. Polarization-insensitive planar omnidirectional diffraction will be demonstrated and engineered over a large and controllable range of frequencies. Device applications to enhanced LEDs, novel lasers, and thin-film solar cells with enhanced absorption will be specifically targeted. Additionally, using Vogel spirals we investigate the direct (i.e. free space) generation of optical vortices, with well-defined and controllable values of orbital angular momentum, paving the way to the engineering and control of novel types of phase discontinuities (i.e., phase dislocation loops) in compact, chip-scale optical devices. Finally, we report on the design, modeling, and experimental demonstration of array-enhanced nanoantennas for polarization-controlled multispectral nanofocusing, nanoantennas for resonant near-field optical concentration of radiation to individual nanowires, and aperiodic double resonance surface enhanced Raman scattering substrates

NEAR-FIELD RADIATIVE TRANSFER: THERMAL RADIATION, THERMOPHOTOVOLTAIC POWER GENERATION AND OPTICAL CHARACTERIZATION

This dissertation focuses on near-field radiative transfer, which can be defined as the discipline concerned with energy transfer via electromagnetic waves at sub-wavelength distances. Three specific subjects related to this discipline are investigated, namely nearfield thermal radiation, nanoscale-gap thermophotovoltaic (nano-TPV) power generation and optical characterization. An algorithm for the solution of near-field thermal radiation problems in one-dimensional layered media is developed, and several tests are performed showing the accuracy, consistency and versatility of the procedure. The possibility of tuning near-field radiative heat transfer via thin films supporting surface phononpolaritons (SPhPs) in the infrared is afterwards investigated via the computation of the local density of electromagnetic states and the radiative heat flux between two films. Results reveal that due to SPhP coupling, fine tuning of near-field radiative heat transfer is possible by solely varying the structure of the system, the structure being the film thicknesses and their distance of separation. The coexistence of two regimes of near-field thermal radiation between two thin films of silicon carbide is demonstrated via numerical simulations and an asymptotic analysis of the radiative heat transfer coefficient. The impacts of thermal effects on the performances of nano-TPV power generators are investigated via the solution of the coupled near-field thermal radiation, charge and heat transport problem. The viability of nano-TPV devices proposed so far in the literature, based on a tungsten radiator at 2000 K and indium gallium antimonide cell, is questioned due to excessive heating of the junction converting thermal radiation into electricity. Using a convective thermal management system, a heat transfer coefficient as high as 105 Wm-2K-1 is required to maintain the junction at room temperature. The possibility of characterizing non-intrusively, and potentially in real-time, nanoparticles from 5 nm to 100 nm in size via scattered surface wave is explored. The feasibility of the characterization framework is theoretically demonstrated via a sensitivity analysis of the scattering matrix elements. Measurements of the scattering matrix elements for 200 nm and 50 nm gold spherical particles show the great sensitivity of the characterization tool, although an ultimate calibration is difficult with the current version of the experimental set-up