Coupling bioturbation activity to metal (Fe and Mn) profiles in situ

This work was supported by a University of Aberdeen 6th century scholarship (awarded to L. T.), CEFAS Lowestoft (DP204), NERC NFSD support (08/02) and a SAMS research bursary (awarded to L. T)Peer reviewedPublisher PD

A Concept for Attribute-Based Authorization on D-Grid Resources

In Germany's D-Grid project numerous Grid communities are working together to provide a common overarching Grid infrastructure. The major aims of D-Grid are the integration of existing Grid deployments and their interoperability. The challenge lies in the heterogeneity of the current implementations: three Grid middleware stacks and different Virtual Organization management approaches have to be embraced to achieve the intended goals. In this article we focus oil the implementation of an attribute-based authorization infrastructure that not only leverages the well-known VO attributes but also campus attributes managed by a Shibboleth federation

No Dream in Georgia? Domestic quarrels and local elections show: "winner takes all" likely to continue

Even though the country is a regional frontrunner, Georgian democracy is not yet consolidated. Parliamentary elections in 2016 saw the governing Georgian Dream returned with a constitutional majority. The October 2017 local elections brought the ruling party another sweeping victory. Despite Georgian Dream’s overwhelming electoral successes, the country faces voter apathy. Alongside lack of parliamentary controls and a fragmentation of the party-political spectrum this does not bode well for consolidating democracy in the near future. (Autorenreferat

The Lumberjack, March 12, 1975

The student newspaper of Humboldt State University.https://digitalcommons.humboldt.edu/studentnewspaper/1856/thumbnail.jp

A theoretical study of the mechanism of the desymmetrization of cyclic meso-anhydrides by chiral amino alcohols

The alcoholysis of cyclic meso-anhydrides catalyzed by β-amino alcohols has been investigated with DFT quantum mechanics to determine the mechanism of this reaction. Both nucleophilic catalysis and general base catalysis pathways are explored for methanol-induced ring opening of an anhydride catalyzed by a chiral amino alcohol. The nucleophilic pathway involves a late transition state with a high energy barrier. In this mechanism, methanolysis is expected to take place following the amine-induced ring opening of the anhydride. In the base-catalyzed mechanism, methanol attack on one carbonyl group of the meso-anhydride is assisted by the β-amino alcohol; the amine functionality abstracts the methanol proton. The chiral amino alcohol also catalyzes the reaction by stabilizing the oxyanion that forms upon ring opening of the anhydride by hydrogen bonding with its alcoholic moiety. Both stepwise and concerted pathways have been studied for the general base catalysis route. Transition structures for both are found to be lower in energy than in the nucleophilic mechanism. Overall this study has shed light on the mechanism of the β-amino alcohol-catalyzed alcoholysis of cyclic meso-anhydrides, showing that the nucleophilic pathway is approximately 100 kJ mol−1 higher in energy than the general base pathwa

Do Community-Level Models Account for the Effects of Biotic Interactions? A Comparison of Community-Level and Species Distribution Modeling of Rocky Mountain Conifers

Community-level models (CLMs) aim to improve species distribution modeling (SDM) methods by attempting to explicitly incorporate the influences of interacting species. However, the ability of CLMs to appropriately account for biotic interactions is unclear. We applied CLM and SDM methods to predict the distributions of three dominant conifer tree species in the U.S. Rocky Mountains and compared CLM and SDM predictive accuracy as well as the ability of each approach to accurately reproduce species co-occurrence patterns. We specifically evaluated the performance of two statistical algorithms, MARS and CForest, within both CLM and SDM frameworks. Across all species, differences in SDM and CLM predictive accuracy were slight and can be attributed to differences in model structure rather than accounting for the effects of biotic interactions. In addition, CLMs generally over-predicted species cooccurrence, while SDMs under-predicted cooccurrence. Our results demonstrate no real improvement in the ability of CLMs to account for biotic interactions relative to SDMs. We conclude that alternative modeling approaches are needed in order to accurately account for the effects of biotic interactions on species distributions

A Not So-Random Walk with Wind: Evaluating Wind Velocity Update Methods in Ground Based Spray Deposition Models

The notion that wind speed and direction can be approximated by adding a random fluctuation to the previous value was investigated. The data were recorded at one meter above a field to simulate conditions that are present at a ground sprayer‘s boom. Variance ratio tests were carried out to test the null hypothesis that wind possesses similar properties to a random walk versus the alternative that wind does not. More specifically, are the random fluctuations auto correlated with one another in time? This process was done to a 10Hz sample and averages of the measured wind data at 0.5, 1, 5, 10, 30, 60, 300, and 600 seconds. It was found that for all tests, except for the 300 and 600 second data samples, the null hypothesis was rejected at greater than 99.9% certainty. This indicates that there is evidence of autocorrelation (rather than randomness) in the measurements of wind speed and direction, associated with each other in time

Chronic hand eczema in Europe:Patient experiences and perspectives (CHEPEP) in qualitative interviews

Background: Chronic hand eczema (CHE) is a very common skin disease among the European population. It causes itch and pain and, in more severe cases, seriously impairs hand functioning at work and in private life. Objectives: To explore perspectives of people with lived experience on CHE-related problems, wishes and goals. Methods: Following a qualitative approach, we conducted topic-guided interviews in five European countries and applied template analysis to identify recurrent themes among patients with CHE. Results: We interviewed 60 patients in seven outpatient dermatological and occupational medicine clinics in Croatia, Denmark, Germany, the Netherlands and Spain. Five main themes were identified: (1) knowledge about the disease and its course, (2) preventive behaviour, (3) hand eczema therapy, (4) impact on everyday life and (5) attitudes towards CHE and healthcare. Participants did not feel well informed about CHE, especially about causes, triggers and treatment options. Preventive measures were experienced as more or less effective but also cumbersome. Experiences with therapy were diverse. Treatment satisfaction depended on the results and on the perceived support from the treatment teams. Participants found it important to be taken seriously, to receive practical advice, to try out additional treatments or examinations, find new hope and have occupational perspectives. They wished that others could better understand the physical and emotional burden of CHE. Patient support groups were not mentioned. Participants found it important to learn to take care of themselves and accept life with CHE. Conclusions: Due to its annoying symptoms, high visibility and impaired functioning at work and in private life, CHE has a high emotional and social impact. Some people may require support to learn coping with CHE and its prevention. Patients wish for information about causes and triggers. They value physicians who listen to them and keep looking for solutions.</p

The Lumberjack, October 09, 1974

The student newspaper of Humboldt State University.https://digitalcommons.humboldt.edu/studentnewspaper/2946/thumbnail.jp