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Parametric amplification of optical phonons
Amplification of light through stimulated emission or nonlinear optical
interactions has had a transformative impact on modern science and technology.
The amplification of other bosonic excitations, like phonons in solids, is
likely to open up new remarkable physical phenomena. Here, we report on an
experimental demonstration of optical phonon amplification. A coherent
mid-infrared optical field is used to drive large amplitude oscillations of the
Si-C stretching mode in silicon carbide. Upon nonlinear phonon excitation, a
second probe pulse experiences parametric optical gain at all wavelengths
throughout the reststrahlen band, which reflects the amplification of
optical-phonon fluctuations. Starting from first principle calculations, we
show that the high-frequency dielectric permittivity and the phonon oscillator
strength depend quadratically on the lattice coordinate. In the experimental
conditions explored here, these oscillate then at twice the frequency of the
optical field and provide a parametric drive for lattice fluctuations.
Parametric gain in phononic four wave mixing is a generic mechanism that can be
extended to all polar modes of solids, as a new means to control the kinetics
of phase transitions, to amplify many body interactions or to control
phonon-polariton waves
Large Electronic Anisotropy and Enhanced Chemical Activity of Highly Rippled Phosphorene
We investigate the electronic structure and chemical activity of rippled
phosphorene induced by large compressive strains via first-principles
calculation. It is found that phosphorene is extraordinarily bendable, enabling
the accommodation of ripples with large curvatures. Such highly rippled
phosphorene shows a strong anisotropy in electronic properties. For ripples
along the armchair direction, the band gap changes from 0.84 to 0.51 eV for the
compressive strain up to -20% and further compression shows no significant
effect, for ripples along the zigzag direction, semiconductor to metal
transition occurs. Within the rippled phosphorene, the local electronic
properties, such as the modulated band gap and the alignments of frontier
orbitals, are found to be highly spatially dependent, which may be used for
modulating the injection and confinement of carriers for optical and
photovoltaic applications. The examination of the interaction of a physisorbed
NO molecule with the rippled phosphorene under different compressive strains
shows that the chemical activities of the phosphorene are significantly
enhanced at the top and bottom peaks of the ripples, indicated by the enhanced
adsorption and charge transfer between them. All these features can be ascribed
to the effect of curvatures, which modifies the orbital coupling between atoms
at the ripple peaks
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