Thermal and Mechanical Energy Harvesting Using Lead Sulfide Colloidal Quantum Dots

The human body is an abundant source of energy in the form of heat and mechanical movement. The ability to harvest this energy can be useful for supplying low-consumption wearable and implantable devices. Thermoelectric materials are usually used to harvest human body heat for wearable devices; however, thermoelectric generators require temperature gradient across the device to perform appropriately. Since they need to attach to the heat source to absorb the heat, temperature equalization decreases their efficiencies. Moreover, the electrostatic energy harvester, working based on the variable capacitor structure, is the most compatible candidate for harvesting low-frequency-movement of the human body. Although it can provide a high output voltage and high-power density at a small scale, they require an initial start-up voltage source to charge the capacitor for initiating the conversion process. The current methods for initially charging the variable capacitor suffer from the complexity of the design and fabrication process. In this research, a solution-processed photovoltaic structure was proposed to address the temperature equalization problem of the thermoelectric generators by harvesting infrared radiations emitted from the human body. However, normal photovoltaic devices have the bandgap limitation to absorb low energy photons radiated from the human body. In this structure, mid-gap states were intentionally introduced to the absorbing layer to activate the multi-step photon absorption process enabling electron promotion from the valence band to the conduction band. The fabricated device showed promising performance in harvesting low energy thermal radiations emitted from the human body. Finally, in order to increase the generated power, a hybrid structure was proposed to harvest both mechanical and heat energy sources available in the human body. The device is designed to harvest both the thermal radiation of the human body based on the proposed solution-processed photovoltaic structure and the mechanical movement of the human body based on an electrostatic generator. The photovoltaic structure was used to charge the capacitor at the initial step of each conversion cycle. The simple fabrication process of the photovoltaic device can potentially address the problem associated with the charging method of the electrostatic generators. The simulation results showed that the combination of two methods can significantly increase the harvested energy

Thermoelectric Textile Materials

Textile, as an intimate partner of human body, shows promising application in wearable thermoelectrics for body heat conversion. Compared with other widely studied flexible film thermoelectric materials, textiles having better air-permeability, wearability, and flexibility are more suitable for wearable electronics. In the past few years, many researches have focused on the design and fabrication of textile-based thermoelectric materials and generators. By integrating with high performance inorganic semiconductors and conductive polymers, fabrics or fibers will be given thermoelectric properties. Technologies of coating, printing, and even thermal drawing can be adopted in the fabrication of textile thermoelectric materials. With great design flexibility, various flexible textile generator structures can be obtained by using yarns or fabrics as thermoelectric legs, which will bring new inspirations for the future development of flexible thermoelectrics

Printing and Folding:A Solution for High-Throughput Processing of Organic Thin-Film Thermoelectric Devices

Wearable electronics are rapidly expanding, especially in applications like health monitoring through medical sensors and body area networks (BANs). Thermoelectric generators (TEGs) have been the main candidate among the different types of energy harvesting methods for body-mounted or even implantable sensors. Introducing new semiconductor materials like organic thermoelectric materials and advancing manufacturing techniques are paving the way to overcome the barriers associated with the bulky and inflexible nature of the common TEGs and are making it possible to fabricate flexible and biocompatible modules. Yet, the lower efficiency of these materials in comparison with bulk-inorganic counterparts as well as applying them mostly in the form of thin layers on flexible substrates limits their applications. This research aims to improve the functionality of thin and flexible organic thermoelectric generators (OTEs) by utilizing a novel design concept inspired by origami. The effects of critical geometric parameters are investigated using COMSOL Multiphysics to further prove the concept of printing and folding as an approach for the system level optimization of printed thin film TEGs

Review of Safety Evaluation of Thermal Wearable Power Harvesting Device

Thermal wearable power harvesting device is developing fast nowadays. The increasing demand on simple and easily handled devices forcing researches to find a better on improving the performance and safety of the devices. Thermal power harvesting is using the heat from the surrounding and human body to generate power. So, the safety precaution needs to be taken in order to keep it safe to use. This paper reviews the use of wearable technology, the basic concept, methods and future of power harvesting technology, ideas of thermoelectric power generators and its related work as well the safety evaluation for international standard of wearable devices

Human Heat Energy Harvesting Using Thermoelectric Cooler

An extensive research in renewable energy harvesting is increasing due to the limitation of energy resources. The known leading renewable energy harvesting sources is such as hydroelectricity, wind and solar. This research will focus on the human heat energy harvesting which will convert human waste heat to electricity. It focuses on converting the waste heat to electricity from five area of human body such as human palm, top palm, wrist, top wrist and leg. Thermoelectric cooler is used to convert the human body heat to electricity. In this research, a booster circuit is developed to boost the small voltage to higher voltage in order to power up an LED as output indicator. Based on experimental results, the maximum output voltage from Peltier module is obtained from human palm which is 0.1 V. The voltage is able to be boosted up to 2.9 V at the voltage booster output. The output voltage generated at load is 2.47 V and the power output is 24.7 mW. The prototype board built is able to generate human heat as electricity. Human palm is the most suitable location to power-up the LED

A polymer-based textile thermoelectric generator for wearable energy harvesting

Conducting polymers offer new opportunities to design soft, conformable and light-weight thermoelectric textile generators that can be unobtrusively integrated into garments or upholstery. Using the widely available conducting polymer:polyelectrolyte complex poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) as the p-type material, we have prepared an electrically conducting sewing thread, which we then embroidered into thick wool fabrics to form out-of-plane thermoelectric textile generators. The influence of device design is discussed in detail, and we show that the performance of e-textile devices can be accurately predicted and optimized using modeling developed for conventional thermoelectric systems, provided that the electrical and thermal contact resistances are included in the model. Finally, we demonstrate a thermoelectric textile device that can generate a, for polymer-based devices, unprecedented power of 1.2 μW at a temperature gradient ΔT of 65 K, and over 0.2 μW at a more modest ΔT of 30 K

Fabrication And Thermoelectric Characterization Of Stretchable Conductive Latex-Based Composites

Miniaturized stretchable electronic devices that can be bent and strained elastically without breaking, have drawn considerable research interest in recent years for wearable computers and integrated bio-sensor applications. Portable electrical power harvesting remains a critical challenge in flexible electronics materials. One proposed solution has been to convert waste heat from the human body into electricity using thermoelectric materials. Traditionally, however, these materials are brittle ceramic semiconductors with limited fracture resistance under deformation. The primary objective of this thesis is to address this challenge by fabricating and studying the mechanical, thermal and electrical performance of stretchable composites combining natural latex polymer with either metallic (Ni) or thermoelectric (InSb) powders. Ni-based and InSb-based latex specimens were synthesized with different powder concentrations up to 36 vol.%. The effects of the powder concentration on tensile elongation, electrical conductivity, and thermal conductivity of the composites were measured at ambient temperature. Strong dependences of mechanical and electrical properties on powder concentration were found. By contrast, thermal conductivity was observed to remain low at all concentrations, suggesting that the predominant heat transport process is through the low-conductivity latex matrix rather than the conductive particles. This thesis was conducted with the support of a Vermont Space Grant Consortium graduate research assistantship

FLEXIBLE TEG ON THE ANKLE FOR MEASURING THE POWER GENERATED WHILE PERFORMING ACTIVITIES OF DAILY LIVING

In this work, a commercial flexible thermoelectric generator (f-TEG) was used to harvest the body thermal energy during the execution of activities of daily living (ADL). The f-TEG was placed at the level of the ankle, and the performed activities were sitting at the desk and walking. In the first stage of measurements, tests were performed to choose the value of the resistor load that maximizes the power output. Then, while performing ADL, the values of generated power were in the range from 100 to 450 µW. Moreover, while users are walking, the pattern of the output signal of f-TEG is compatible to a sine function with frequency close to that one of human gait. This preliminary result may represent a new way to study the movement of human body to recognize AD

웨어러블 센서 및 에너지 소자의 공간 신호 및 열 전달 증진을 위한 나노복합체를 이용한 기계적 순응성 향상

학위논문 (박사) -- 서울대학교 대학원 : 공과대학 전기·정보공학부, 2020. 8. 홍용택.Electronic skin (e-skin) that mimics mechanical and functional properties of human skin has a strong impact on the field of wearable electronics. Beyond being just wearable, e-skin seamlessly interfaces human, machine, and environment by perfectly adhering to soft and time-dynamic three-dimensional (3D) geometries of human skin and organs. Real-time and intimate access to the sources of physical and biological signals can be achieved by adopting soft or flexible electronic sensors that can detect pressure, strain, temperature, and chemical substances. Such extensions in accessible signals drastically accelerate the growth of the Internet of Things (IoT) and expand its application to health monitoring, medical implants, and novel human-machine interfaces. In wearable sensors and energy devices, which are essential building blocks for skin-like functionalities and self-power generation in e-skin, spatial signals and heat are transferred from time-dynamic 3D environments through numerous geometries and electrical devices. Therefore, the transfer of high-fidelity signals or a large amount of heat is of great importance in these devices. The mechanical conformability potentially enhances the signal/heat transfer by providing conformal geometries with the 3D sources. However, while the relation between system conformability and electrical signals has been widely investigated, studies on its effect on the transfer of other mechanical signals and heat remain in their early stages. Furthermore, because active materials and their designs for sensors and energy devices have been optimized to maximize their performances, it is challenging to develop ultrathin or soft forms of active layers without compromising their performances. Therefore, many devices in these fields suffer from poor spatial signal/heat transfer due to limited conformability. In this dissertation, to ultimately augment the functionalities of wearable sensors and energy devices, comprehensive studies on conformability enhancement via composite materials and its effect on signal/heat transfer, especially in pressure sensors and thermoelectric generators (TEGs), are conducted. A solution for each device is carefully optimized to reinforce its conformability, taking account of the structure, characteristics, and potential advantages of the device. As a result, the mechanical conformability of each device is significantly enhanced, improving signal/heat transfer and consequently augmenting its functionalities, which have been considered as tough challenges in each area. The effect of the superior conformability on signal/heat transfer is systematically analyzed via a series of experiments and finite element analyses. Demonstrations of practical wearable electronics show the feasibility of the proposed strategies. For wearable pressure sensors, ultrathin piezoresistive layers are developed using cellulose/nanowire nanocomposites (CNNs). The unique nanostructured surface enables unprecedentedly high sensor performances such as ultrahigh sensitivity, wide working range, and fast response time without microstructures in sensing layers. Because the ultrathin pressure sensor perfectly conforms to 3D contact objects, it transfers pressure distribution into conductivity distribution with high spatial fidelity. When integrated with a quantum dot-based electroluminescent film, the transferred high-resolution pressure distribution is directly visualized without the need for pixel structures. The electroluminescent skin enables real-time smart touch interfaces that can identify the user as well as touch force and location. For high-performance wearable TEGs, an intrinsically soft heat transfer and electrical interconnection platform (SHEP) is developed. The SHEP comprises AgNW random networks for intrinsically stretchable electrodes and magnetically self-assembled metal particles for soft thermal conductors (STCs). The stretchable electrodes lower the flexural rigidity, and the STCs enhance the heat exchange capability of the soft platform, maintaining its softness. As a result, a compliant TEG with SHEPs forms unprecedentedly conformal contact with 3D heat sources, thereby enhancing the heat transfer to the TE legs. This results in significant improvement in thermal energy harvesting on 3D surfaces. Self-powered wearable warning systems indicating an abrupt temperature increase with light-emitting alarms are demonstrated to show the feasibility of this strategy. This study provides a systematic and comprehensive framework for enhancing mechanical conformability of e-skin and consequently improving the transfer of spatial signals and energy from time-dynamic and complex 3D surfaces. The framework can be universally applied to other fields in wearable electronics that require improvement in signal/energy transfer through conformal contact with 3D surfaces. The materials, manufacturing methods, and devices introduced in this dissertation will be actively exploited in practical and futuristic applications of wearable electronics such as skin-attachable advanced user interfaces, implantable bio-imaging systems, nervous systems in soft robotics, and self-powered artificial tactile systems.인간 피부의 기계적 특성 및 기능을 모방하는 전자피부(electronic skin, e-skin)는 웨어러블 전자기기 분야의 트렌드를 바꾸고 있다. 기존의 웨어러블 전자기기가 단지 착용하는데 그쳤다면, 전자피부는 인간의 피부와 장기 표면에 완벽하게 붙어 동작함으로써 기존에는 접근 불가능 했던 다양한 생체 신호를 높은 신뢰도로 감지하고 처리할 수 있다. 실시간으로 감지 가능한 생체 신호의 확장은 사물인터넷(Internet of Things, IoT)의 성장을 획기적으로 가속화하고 헬스케어, 의료용 임플란트, 소프트 로봇 및 새로운 휴먼 머신 인터페이스로의 응용을 가능하게 한다. 전자피부의 필수요소인 센서와 에너지 소자에서는 삼차원 표면의 공간신호와 열에너지를 손실 없이 전달하는 것이 매우 중요하다. 이러한 공간 신호와 열에너지는 다양한 기하 구조와 전자소자를 거쳐 처리 가능한 신호로 전달된다. 이 과정에서 3차원 표면에 빈틈없이 붙는 기계적 순응성(mechanical conformability)은 공간신호와 열에너지를 왜곡 없이 전달하는 것을 가능하게 한다. 전자피부의 기계적 순응성을 증가시키는 방법은 크게 다음과 같이 두 가지로 나눌 수 있다. (1) 전자피부를 두께를 낮추는 전략과 (2) 전자피부의 영률(Youngs modulus)을 낮추어 고무와 같이 부드럽게 만드는 전략이다. 하지만, 기존 센서 및 에너지 소자를 위한 재료와 디자인이 각 장치의 성능을 향상시키는 것에 초점이 맞추어져 있기 때문에, 고성능을 유지하면서 매우 얇거나 연질 형태의 소자를 개발하는 것은 매우 도전적이었다. 따라서 고유연성을 확보하지 못한 기존 센서와 에너지 소자는 공간 신호 및 열 전달이 심각하게 저해되고, 이로 인해 공간 압력의 왜곡, 열전 효율의 저하와 같은 한계를 보여준다. 이 논문에서는 웨어러블 센서와 에너지 소자의 비약적인 기능 향상을 궁극적인 목표로, 각 소자에 최적화된 재료와 제작방식, 구조를 이용해 이들의 기계적 순응성을 획기적으로 높이고, 이를 통한 공간 신호 및 열 전달의 향상을 심도 있게 분석한다. 특히, 두께를 낮추거나 영률을 낮추는 두 가지 전략 중 각 소자에 가장 적합한 전략을 선택하고, 체계적인 방법론을 적용하여 이들의 기계적 순응성과 공간 신호 및 열 전달을 증진시킨다. 이 과정에서 나노융복합재료가 각 전략을 구현하는 핵심 요소로 작용한다. 각 소자에 따른 구체적인 연구 내용은 다음과 같다. 첫째, 압력 센서의 경우 초박막 셀룰로오스/나노와이어 복합체를 이용하여 고성능의 저항방식 압력 센서를 개발한다. 이러한 복합체는 표면에 형성된 고유한 나노구조 덕분에 마이크로구조체를 이용한 기존 압력 센서보다 월등한 성능을 보여준다. 특히, 1 마이크로 미터 수준의 매우 얇은 두께로 인해 접촉 물체의 복잡한 형상에 완벽하게 순응할 수 있고, 이로 인해 고해상도 압력 분포를 왜곡 없이 저항 분포로 전달할 수 있다. 이러한 압력 센서를 양자 점 발광소자와 결합하여 고해상도의 압력분포를 높은 정밀도로 이미징 가능한 발광 소자를 보고한다. 둘째, 열전 소자의 경우 기존의 금속 전극으로 인한 낮은 유연성과 탄성중합체의 낮은 열 전도도를 극복하기 위해 열 전달 능력이 획기적으로 향상된 낮은 영률의 소프트 전극 플랫폼을 개발한다. 소프트 플랫폼은 내부에 은 나노와이어 기반의 신축성 전극을 갖고 있으며, 자기장을 통해 자가 정렬된 금속 입자들이 효과적으로 외부 열을 열전 재료에 전달한다. 이를 기반으로 제작된 고유연성 열전 소자는 삼차원 열원에 빈틈없이 붙어 열 손실을 최소화 하며, 이로 인해 높은 열전 효율을 달성한다. 이 논문은 다양한 전자소자의 유연성을 증진시키고 이를 통한 공간 신호 및 열 전달의 향상을 도모하고 분석하는 체계적이고 종합적인 방법론을 제시했다는 데 큰 의의가 있다. 제안된 방법론은 분야에 국한되지 않고 다양한 소자의 개발에 적용할 수 있어 웨어러블 기기와 전자피부 분야의 기계적, 기능적 발전에 크게 기여할 것으로 기대된다. 뿐만 아니라 이 연구에서 최초로 개발한 소재 및 소자들은 다양한 웨어러블 어플리케이션과 산업에 곧바로 융합되고 응용될 수 있다. 이를 통해 신체 부착 및 삽입 가능한 생체 이미징 시스템, 소프트 로봇을 위한 신경 체계, 자가 발전이 가능한 인공 감각 기관, 가상 및 증강 현실을 위한 새로운 유저 인터페이스와 같은 미래 지향적 융합 어플리케이션의 실현을 앞당길 것으로 기대된다.Chapter 1. Introduction 1 1.1 Wearable Electronics and Electronic Skin 1 1.2 Mechanical Conformability of Electronic Skin 6 1.2.1 Definition and Advantages 6 1.2.2 Thickness-Based Conformability 11 1.2.3 Softness-Based Conformability 15 1.3 Conformability for Enhanced Signal/Heat Transfer in Wearable Sensors and Energy Devices 19 1.3.1 Conformability for Spatial Signal Transfer in Pressure Sensors 20 1.3.2 Conformability for Heat Transfer in Thermoelectric Generators 22 1.4 Motivation and Organization of This Dissertation 24 Chapter 2. Ultrathin Cellulose Nanocomposites for High-Performance Piezoresistive Pressure Sensors 28 2.1 Introduction 28 2.2 Experimental Section 31 2.2.1 Fabrication of the CNNs and Pressure Sensors 31 2.2.2 Measurements 34 2.3 Results and Discussion 38 2.3.1 Morphology of CNNs 38 2.3.2 Piezoresistive Characteristics of CNNs 41 2.3.3 Mechanism of High Sensitivity and Great Linearity 45 2.3.4 Fast Response Time of CNN-Based Pressure Sensors 49 2.3.5 Cyclic Reliability of CNN-Based Pressure Sensors 53 2.3.6 Mechanical Reliability and Conformability 57 2.3.7 Temperature and Humidity Tolerance 63 2.4 Conclusion 66 Chapter 3. Ultraflexible Electroluminescent Skin for High-Resolution Imaging of Pressure Distribution 67 3.1 Introduction 67 3.2 Main Concept 70 3.3 Experimental Section 72 3.3.1 Fabrication of Pressure-Sensitive Photonic Skin 72 3.3.2 Characterization of Photonic Skin 74 3.4 Results and Discussion 76 3.4.1 Structure and Morphology of Photonic Skin 76 3.4.2 Pressure Response of Photonic Skin 79 3.4.3 Effect of Conformability on Spatial Resolution 85 3.4.4 Demonstration of High-Resolution Pressure Imaging 99 3.4.5 Pressure Data Acquisition 104 3.4.6 Application to Smart Touch Interfaces 106 3.5 Conclusion 109 Chapter 4. Intrinsically Soft Heat Transfer and Electrical Interconnection Platforms Using Magnetic Nanocomposites 110 4.1 Introduction 110 4.2 Experimental Section 115 4.2.1 Fabrication of SHEPs 115 4.2.2 Measurements 117 4.3 Results and Discussion 119 4.3.1 Fabrication Scheme and Morphology of SHEPs 119 4.3.2 Calculation of Particle Concentration in STCs 124 4.3.3 Enhancement of Heat Transfer Ability via Magnetic Self-Assembly 127 4.3.4 Softness of STCs 131 4.3.5 Mechanical Reliability of Stretchable Electrodes 133 4.3.6 Optimization of Magnetic Self-Assembly Process 135 4.4 Conclusion 139 Chapter 5. Highly Conformable Thermoelectric Generators with Enhanced Heat Transfer Ability 140 5.1 Introduction 140 5.2 Experimental Section 142 5.2.1 Fabrication of Compliant TEGs 142 5.2.2 Measurements 144 5.2.3 Finite Element Analysis 147 5.3 Results and Discussion 149 5.3.1 Enhancement of TE Performance via STCs 149 5.3.2 Mechanical Reliability of Compliant TEGs 157 5.3.3 Enhanced TE Performance on 3D Surfaces via Conformability 162 5.3.4 Self-Powered Wearable Applications 167 5.4 Conclusion 171 Chapter 6. Summary, Limitations, and Recommendations for Future Researches 172 6.1 Summary and Conclusion 172 6.2 Limitations and Recommendations 176 6.2.1 Pressure Sensors and Photonic Skin 176 6.2.2 Compliant TEGs 177 Bibliography 178 Publication List 186 Abstract in Korean 192Docto