Collapse Dynamics of a Homopolymer: Theory and Simulation

We present a scaling theory describing the collapse of a homopolymer chain in poor solvent. At time t after the beginning of the collapse, the original Gaussian chain of length N is streamlined to form N/g segments of length R(t), each containing g ~ t monomers. These segments are statistical quantities representing cylinders of length R ~ t^{1/2} and diameter d ~ t^{1/4}, but structured out of stretched arrays of spherical globules. This prescription incorporates the capillary instability. We compare the time-dependent structure factor derived for our theory with that obtained from ultra-large-scale molecular dynamics simulation with explicit solvent. This is the first time such a detailed comparison of theoretical and simulation predictions of collapsing chain structure has been attempted. The favorable agreement between the theoretical and computed structure factors supports the picture of the coarse-graining process during polymer collapse.Comment: 4 pages, 3 figure

Micelle formation, gelation and phase separation of amphiphilic multiblock copolymers

The phase behaviour of amphiphilic multiblock copolymers with a large number of blocks in semidilute solutions is studied by lattice Monte Carlo simulations. The influence on the resulting structures of the concentration, the solvent quality and the ratio of hydrophobic to hydrophilic monomers in the chains has been assessed explicitely. Several distinct regimes are put in evidence. For poorly substituted (mainly hydrophilic) copolymers formation of micelles is observed, either isolated or connected by the hydrophilic moieties, depending on concentration and chain length. For more highly substituted chains larger tubular hydrophobic structures appear which, at higher concentration, join to form extended hydrophobic cores. For both substitution ratios gelation is observed, but with a very different gel network structure. For the poorly substituted chains the gel consists of micelles cross-linked by hydrophilic blocks whereas for the highly substituted copolymers the extended hydrophobic cores form the gelling network. The interplay between gelation and phase separation clearly appears in the phase diagram. In particular, for poorly substituted copolymers and in a narrow concentration range, we observe a sol-gel transition followed by an inverse gel-sol transition when increasing the interaction energy. The simulation results are discussed in the context of the experimentally observed phase properties of methylcellulose, a hydrophobically substituted polysaccharide.Comment: 14 pages, 14 figures; Soft Matter (2011

Fast Universal Quantum Computation with Railroad-switch Local Hamiltonians

We present two universal models of quantum computation with a time-independent, frustration-free Hamiltonian. The first construction uses 3-local (qubit) projectors, and the second one requires only 2-local qubit-qutrit projectors. We build on Feynman's Hamiltonian computer idea and use a railroad-switch type clock register. The resources required to simulate a quantum circuit with L gates in this model are O(L) small-dimensional quantum systems (qubits or qutrits), a time-independent Hamiltonian composed of O(L) local, constant norm, projector terms, the possibility to prepare computational basis product states, a running time O(L log^2 L), and the possibility to measure a few qubits in the computational basis. Our models also give a simplified proof of the universality of 3-local Adiabatic Quantum Computation.Comment: Added references to work by de Falco et al., and realized that Feynman's '85 paper already contained the idea of a switch in i

The Beltline Emerald Necklace: Atlanta's New Public Realm

Proposes a corridor of transit, parks, and trails that will add more than 1,400 acres of green space to the city of Atlanta; connect 46 historic neighborhoods; provide a trail for running and bicycling; and include links to the existing transit network

Quantum oscillations and decoherence due to electron-electron interaction in metallic networks and hollow cylinders

We have studied the quantum oscillations of the conductance for arrays of connected mesoscopic metallic rings, in the presence of an external magnetic field. Several geometries have been considered: a linear array of rings connected with short or long wires compared to the phase coherence length, square networks and hollow cylinders. Compared to the well-known case of the isolated ring, we show that for connected rings, the winding of the Brownian trajectories around the rings is modified, leading to a different harmonics content of the quantum oscillations. We relate this harmonics content to the distribution of winding numbers. We consider the limits where coherence length $L_\varphi$ is small or large compared to the perimeter $L$ of each ring constituting the network. In the latter case, the coherent diffusive trajectories explore a region larger than $L$, whence a network dependent harmonics content. Our analysis is based on the calculation of the spectral determinant of the diffusion equation for which we have a simple expression on any network. It is also based on the hypothesis that the time dependence of the dephasing between diffusive trajectories can be described by an exponential decay with a single characteristic time $\tau_\varphi$ (model A) . At low temperature, decoherence is limited by electron-electron interaction, and can be modelled in a one-electron picture by the fluctuating electric field created by other electrons (model B). It is described by a functional of the trajectories and thus the dependence on geometry is crucial. Expressions for the magnetoconductance oscillations are derived within this model and compared to the results of model A. It is shown that they involve several temperature-dependent length scales.Comment: 35 pages, revtex4, 25 figures (34 pdf files

Public Spaces/Private Money: The Triumphs and Pitfalls of Urban Park Conservancies

This study explores city park conservancies -- private organizations that utilize donations to rebuild, refurbish, and even maintain some of their most iconic parks. The study uses examples and experiences from 41 organizations across the country that have a collective experience record of nearly 750 years