Electrohydrodynamic and Aerosol Jet Printing for the Copatterning of Polydimethylsiloxane and Graphene Platelet Inks

The performance of soft sensing and actuation devices is dependent on their design, the electro‐mechanical response of materials, and the ability to copattern structural and functional features. For film based soft structures, such as wearable sensors and artificial muscles, manufacturing challenges exist that prevent the translation of technology from laboratory to practical application. In this work, a hybrid manufacturing technique is presented that integrates electro‐hydrodynamic and aerosol jet deposition to print multilayer, multimaterial structures. The combined approach overcomes the respective rheological constraints of the individual processes, while presenting a pathway to higher resolution computer‐controlled patterning. Electro‐hydrodynamic deposition of a polydimethylsiloxane elastomer is demonstrated and characterized, before being combined with aerosol jet deposition of a graphene platelet ink to produce functional devices. A proof‐of‐concept, multilayer capacitive sensor is presented as a first demonstration of the manufacturing technology

Additive Manufacturing of Conducting Polymers: Recent Advances, Challenges and Opportunities

Unformatted postprintConducting polymers (CPs) have been attracting great attention in the development of (bio)electronic devices. Most of current devices are rigid 2D systems and possess uncontrollable geometries and architectures that lead to poor mechanical properties presenting ion/electronic diffusion limitations. The goal of the article is to provide an overview about the additive manufacturing (AM) of conducting polymers, which is of paramount importance for the design of future wearable 3D (bio)electronic devices. Among different 3D printing AM techniques, inkjet, extrusion, electrohydrodynamic and light-based printing have been mainly used. This review article collects examples of 3D printing of conducting polymers such as poly(3,4-ethylene-dioxythiophene) (PEDOT), polypyrrole (PPy) and polyaniline (PANi). It also shows examples of AM of these polymers combined with other polymers and/or conducting fillers such as carbon nanotubes, graphene and silver nanowires. Afterwards, the foremost application of CPs processed by 3D printing techniques in the biomedical and energy fields, i.e., wearable electronics, sensors, soft robotics for human motion, or health monitoring devices, among others, will be discussed.This work was supported by Marie Sklodowska-Curie Research and Innovation Staff Exchanges (RISE) under the grant agreement No 823989 “IONBIKE”. N.A. has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement no. 753293, acronym NanoBEAT

Sustainable Robots 4D Printing

Nature frequently serves as an inspiration for modern robotics innovations that emphasize secure human–machine interaction. However, the advantages of increased automation and digital technology integration conflict with the global environmental objectives. Accordingly, biodegradable soft robots have been proposed for a range of intelligent applications. Biodegradability provides soft robotics with an extraordinary functional advantage for operations involving intelligent shape transformation in response to external stimuli such as heat, pH, and light. Soft robot fabrication using conventional manufacturing techniques is inflexible, time-consuming, and labor-intensive. Recent advances in 3D and 4D printing of soft materials and multi-materials have become the key to enabling the direct manufacture of soft robotics with complex designs and functions. This review comprises a detailed survey of 3D and 4D printing advances in biodegradable soft sensors and actuators (BSSA), which serve as the most prominent parts of each robotic system. In addition, a concise overview of biodegradable materials for the fabrication of 3D-printed flexible devices with medical along with industrial applications is provided. A complete summary of current additive manufacturing techniques for BSSA is discussed in depth. Moreover, the concept of biodegradable 4D-printed soft actuators and sensors and biohybrid soft robots is reviewed

Design, evaluation, and control of nexus: a multiscale additive manufacturing platform with integrated 3D printing and robotic assembly.

Additive manufacturing (AM) technology is an emerging approach to creating three-dimensional (3D) objects and has seen numerous applications in medical implants, transportation, aerospace, energy, consumer products, etc. Compared with manufacturing by forming and machining, additive manufacturing techniques provide more rapid, economical, efficient, reliable, and complex manufacturing processes. However, additive manufacturing also has limitations on print strength and dimensional tolerance, while traditional additive manufacturing hardware platforms for 3D printing have limited flexibility. In particular, part geometry and materials are limited to most 3D printing hardware. In addition, for multiscale and complex products, samples must be printed, fabricated, and transferred among different additive manufacturing platforms in different locations, which leads to high cost, long process time, and low yield of products. This thesis investigates methods to design, evaluate, and control the NeXus, which is a novel custom robotic platform for multiscale additive manufacturing with integrated 3D printing and robotic assembly. NeXus can be used to prototype miniature devices and systems, such as wearable MEMS sensor fabrics, microrobots for wafer-scale microfactories, tactile robot skins, next generation energy storage (solar cells), nanostructure plasmonic devices, and biosensors. The NeXus has the flexibility to fixture, position, transport, and assemble components across a wide spectrum of length scales (Macro-Meso-Micro-Nano, 1m to 100nm) and provides unparalleled additive process capabilities such as 3D printing through both aerosol jetting and ultrasonic bonding and forming, thin-film photonic sintering, fiber loom weaving, and in-situ Micro-Electro-Mechanical System (MEMS) packaging and interconnect formation. The NeXus system has a footprint of around 4m x 3.5m x 2.4m (X-Y-Z) and includes two industrial robotic arms, precision positioners, multiple manipulation tools, and additive manufacturing processes and packaging capabilities. The design of the NeXus platform adopted the Lean Robotic Micromanufacturing (LRM) design principles and simulation tools to mitigate development risks. The NeXus has more than 50 degrees of freedom (DOF) from different instruments, precise evaluation of the custom robots and positioners is indispensable before employing them in complex and multiscale applications. The integration and control of multi-functional instruments is also a challenge in the NeXus system due to different communication protocols and compatibility. Thus, the NeXus system is controlled by National Instruments (NI) LabVIEW real-time operating system (RTOS) with NI PXI controller and a LabVIEW State Machine User Interface (SMUI) and was programmed considering the synchronization of various instruments and sequencing of additive manufacturing processes for different tasks. The operation sequences of each robot along with relevant tools must be organized in safe mode to avoid crashes and damage to tools during robots’ motions. This thesis also describes two demonstrators that are realized by the NeXus system in detail: skin tactile sensor arrays and electronic textiles. The fabrication process of the skin tactile sensor uses the automated manufacturing line in the NeXus with pattern design, precise calibration, synchronization of an Aerosol Jet printer, and a custom positioner. The fabrication process for electronic textiles is a combination of MEMS fabrication techniques in the cleanroom and the collaboration of multiple NeXus robots including two industrial robotic arms and a custom high-precision positioner for the deterministic alignment process

A Digital Manufacturing Process For Three-Dimensional Electronics

Additive manufacturing (AM) offers the ability to produce devices with a degree of three-dimensional complexity and mass customisation previously unachievable with subtractive and formative approaches. These benefits have not transitioned into the production of commercial electronics that still rely on planar, template-driven manufacturing, which prevents them from being tailored to the end user or exploiting conformal circuitry for miniaturisation. Research into the AM fabrication of 3D electronics has been demonstrated; however, because of material restrictions, the durability and electrical conductivity of such devices was often limited. This thesis presents a novel manufacturing approach that hybridises the AM of polyetherimide (PEI) with chemical modification and selective light-based synthesis of silver nanoparticles to produce 3D electronic systems. The resulting nanoparticles act as a seed site for the electroless deposition of copper. The use of high-performance materials for both the conductive and dielectric elements created devices with the performance required for real-world applications. For printing PEI, a low-cost fused filament fabrication (FFF); also known as fused deposition modelling (FDM), printer with a unique inverted design was developed. The orientation of the printer traps hot air within a heated build environment that is open on its underside allowing the print head to deposit the polymer while keeping the sensitive components outside. The maximum achievable temperature was 120 °C and was found to reduce the degree of warping and the ultimate tensile strength of printed parts. The dimensional accuracy was, on average, within 0.05 mm of a benchmark printer and fine control over the layer thickness led to the discovery of flexible substrates that can be directly integrated into rigid parts. Chemical modification of the printed PEI was used to embed ionic silver into the polymer chain, sensitising it to patterning with a 405 nm laser. The rig used for patterning was a re-purposed vat-photopolymerisation printer that uses a galvanometer to guide the beam that is focused to a spot size of 155 µm at the focal plane. The positioning of the laser spot was controlled with an open-sourced version of the printers slicing software. The optimal laser patterning parameters were experimentally validated and a link between area-related energy density and the quality of the copper deposition was found. In tests where samples were exposed to more than 2.55 J/cm^2, degradation of the polymer was experienced which produced blistering and delamination of the copper. Less than 2.34 J/cm^2 also had negative effect and resulted in incomplete coverage of the patterned area. The minimum feature resolution produced by the patterning setup was 301 µm; however, tests with a photomask demonstrated features an order of magnitude smaller. The non-contact approach was also used to produce conformal patterns over sloped and curved surfaces. Characterisation of the copper deposits found an average thickness of 559 nm and a conductivity of 3.81 × 107 S/m. Tape peel and bend fatigue testing showed that the copper was ductile and adhered well to the PEI, with flexible electronic samples demonstrating over 50,000 cycles at a minimum bend radius of 6.59 mm without failure. Additionally, the PEI and copper combination was shown to survive a solder reflow with peak temperatures of 249°C. Using a robotic pick and place system a test board was automatically populated with surface mount components as small as 0201 resistors which were affixed using high-temperature, Type-V Tin-Silver-Copper solder paste. Finally, to prove the process a range of functional demonstrators were built and evaluated. These included a functional timer circuit, inductive wireless power coils compatible with two existing standards, a cylindrical RF antenna capable of operating at several frequencies below 10 GHz, flexible positional sensors, and multi-mode shape memory alloy actuators

Micro-scale aerosol jet printing of superparamagnetic Fe₃O₄ nanoparticle patterns

The opportunity to create different patterns of magnetic nanoparticles on surfaces is highly desirable across many technological and biomedical applications. In this paper, this ability is demonstrated for the first time using a computer-controlled aerosol jet printing (AJP) technology. AJP is an emerging digitally driven, non-contact and mask-less printing process which has distinguishing advantages over other patterning technologies as it offers high-resolution and versatile direct-write deposition of a wide range of materials onto a variety of substrates. This research demonstrates the ability of AJP to reliably print large-area, fine-feature patterns of superparamagnetic iron oxide nanoparticles (SPIONs) onto both rigid material (glass) and soft and flexible materials (polydimethylsiloxane (PDMS) films and poly-L-lactic acid (PLLA) nanofilms). Investigation identified and controlled influential process variables which permitted feature sizes in the region of 20 μm to be realised. This method could be employed for a wide range of applications that require a flexible and responsive process that permits high yield and rapid patterning of magnetic material over large areas. As a first proof of concept, we present patterned magnetic nanofilms with enhanced manipulability under external magnetic field gradient control and which are capable of performing complex movements such as rotation and bending, with applicability to soft robotics and biomedical engineering applications

Additive Manufactured Antennas and Novel Frequency Selective Sensors

The research work carried out and reported in this thesis focuses on the application of additive manufacturing (AM) for the development antennas and novel frequency selective surfaces structures. Various AM techniques such as direct writing (DW), material extrusion, nanoparticle conductive inks are investigated for the fabrication of antennas and FSS based sensors. This research has two parts. The first involves the development of antennas at the microwave and millimetre wave bands using AM techniques. Inkjet printing of nanoparticle silver inks on paper substrate is employed in the fabrication of antennas for an origami robotic bird. This provides an exploration on the practicability of developing foldable antennas which can be integrated on expendable robots using low-cost household inkjet printers. This is followed using Aerosol jet printing in the fabrication of fingernail wearable antennas. The antennas are developed to operate at microwave and millimetre wave bands for potential use in 5G Internet of Things (IoT) or body-centric networks. The second part of the research work involves the development of frequency selective sensors. Trenches have been incorporated on an FSS structure to produce a new concept of liquid sensor. The sensor is fabricated using standard etching techniques and then using FDM method in conjunction with nanoparticle conductive ink. Finally, a new concept displacement sensor using an FSS coupled with a retracting substrate complement is introduced. The displacement sensor is a 3D structure which is conveniently fabricated using AM techniques

A review of aerosol jet printing—a non-traditional hybrid process for micro-manufacturing

Aerosol Jet Printing (AJP) is an emerging contactless direct write approach aimed at the production of fine features on a wide range of substrates. Originally developed for the manufacture of electronic circuitry, the technology has been explored for a range of applications, including, active and passive electronic components, actuators, sensors, as well as a variety of selective chemical and biological responses. Freeform deposition, coupled with a relatively large stand-off distance, is enabling researchers to produce devices with increased geometric complexity compared to conventional manufacturing or more commonly used direct write approaches. Wide material compatibility, high resolution and independence of orientation have provided novelty in a number of applications when AJP is conducted as a digitally driven approach for integrated manufacture. This overview of the technology will summarise the underlying principles of AJP, review applications of the technology and discuss the hurdles to more widespread industry adoption. Finally, this paper will hypothesise where gains may be realised through this assistive manufacturing process