2,468 research outputs found

    Kalman-variant estimators for state of charge in lithium-sulfur batteries

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    Lithium-sulfur batteries are now commercially available, offering high specific energy density, low production costs and high safety. However, there is no commercially-available battery management system for them, and there are no published methods for determining state of charge in situ. This paper describes a study to address this gap. The properties and behaviours of lithium-sulfur are briefly introduced, and the applicability of ‘standard’ lithium-ion state-of-charge estimation methods is explored. Open-circuit voltage methods and ‘Coulomb counting’ are found to have a poor fit for lithium-sulfur, and model-based methods, particularly recursive Bayesian filters, are identified as showing strong promise. Three recursive Bayesian filters are implemented: an extended Kalman filter (EKF), an unscented Kalman filter (UKF) and a particle filter (PF). These estimators are tested through practical experimentation, considering both a pulse-discharge test and a test based on the New European Driving Cycle (NEDC). Experimentation is carried out at a constant temperature, mirroring the environment expected in the authors' target automotive application. It is shown that the estimators, which are based on a relatively simple equivalent-circuit–network model, can deliver useful results. If the three estimators implemented, the unscented Kalman filter gives the most robust and accurate performance, with an acceptable computational effort

    SoC estimation for lithium-ion batteries : review and future challenges

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    ABSTRACT: Energy storage emerged as a top concern for the modern cities, and the choice of the lithium-ion chemistry battery technology as an effective solution for storage applications proved to be a highly efficient option. State of charge (SoC) represents the available battery capacity and is one of the most important states that need to be monitored to optimize the performance and extend the lifetime of batteries. This review summarizes the methods for SoC estimation for lithium-ion batteries (LiBs). The SoC estimation methods are presented focusing on the description of the techniques and the elaboration of their weaknesses for the use in on-line battery management systems (BMS) applications. SoC estimation is a challenging task hindered by considerable changes in battery characteristics over its lifetime due to aging and to the distinct nonlinear behavior. This has led scholars to propose different methods that clearly raised the challenge of establishing a relationship between the accuracy and robustness of the methods, and their low complexity to be implemented. This paper publishes an exhaustive review of the works presented during the last five years, where the tendency of the estimation techniques has been oriented toward a mixture of probabilistic techniques and some artificial intelligence

    Identifiability and parameter estimation of the single particle lithium-ion battery model

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    This paper investigates the identifiability and estimation of the parameters of the single particle model (SPM) for lithium-ion battery simulation. Identifiability is addressed both in principle and in practice. The approach begins by grouping parameters and partially non-dimensionalising the SPM to determine the maximum expected degrees of freedom in the problem. We discover that, excluding open circuit voltage, there are only six independent parameters. We then examine the structural identifiability by considering whether the transfer function of the linearised SPM is unique. It is found that the model is unique provided that the electrode open circuit voltage functions have a known non-zero gradient, the parameters are ordered, and the electrode kinetics are lumped into a single charge transfer resistance parameter. We then demonstrate the practical estimation of model parameters from measured frequency-domain experimental electrochemical impedance spectroscopy (EIS) data, and show additionally that the parametrised model provides good predictive capabilities in the time domain, exhibiting a maximum voltage error of 20 mV between model and experiment over a 10 minute dynamic discharge.Comment: 16 pages, 9 figures, pre-print submitted to the IEEE Transactions on Control Systems Technolog

    Modelling and estimation in lithium-ion batteries: a literature review

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    Lithium-ion batteries are widely recognised as the leading technology for electrochemical energy storage. Their applications in the automotive industry and integration with renewable energy grids highlight their current significance and anticipate their substantial future impact. However, battery management systems, which are in charge of the monitoring and control of batteries, need to consider several states, like the state of charge and the state of health, which cannot be directly measured. To estimate these indicators, algorithms utilising mathematical models of the battery and basic measurements like voltage, current or temperature are employed. This review focuses on a comprehensive examination of various models, from complex but close to the physicochemical phenomena to computationally simpler but ignorant of the physics; the estimation problem and a formal basis for the development of algorithms; and algorithms used in Li-ion battery monitoring. The objective is to provide a practical guide that elucidates the different models and helps to navigate the different existing estimation techniques, simplifying the process for the development of new Li-ion battery applications.This research received support from the Spanish Ministry of Science and Innovation under projects MAFALDA (PID2021-126001OB-C31 funded by MCIN/AEI/10.13039/501100011033/ ERDF,EU) and MASHED (TED2021-129927B-I00), and by FI Joan Oró grant (code 2023 FI-1 00827), cofinanced by the European Union.Peer ReviewedPostprint (published version

    Modeling and control of fuel cell-battery hybrid energy sources

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    Environmental, political, and availability concerns regarding fossil fuels in recent decades have garnered substantial research and development in the area of alternative energy systems. Among various alternative energy systems, fuel cells and batteries have attracted significant attention both in academia and industry considering their superior performances and numerous advantages. In this dissertation, the modeling and control of these two electrochemical sources as the main constituents of fuel cell-battery hybrid energy sources are studied with ultimate goals of improving their performance, reducing their development and operational costs and consequently, easing their widespread commercialization. More specifically, Paper I provides a comprehensive background and literature review about Li-ion battery and its Battery Management System (BMS). Furthermore, the development of an experimental BMS design testbench is introduced in this paper. Paper II discusses the design of a novel observer for Li-ion battery State of Charge (SOC) estimation, as one of the most important functionalities of BMSs. Paper III addresses the control-oriented modeling and analysis of open-cathode fuel cells in order to provide a comprehensive system-level understanding of their real-time operation and to establish a basis for control design. Finally, in Paper IV a feedback controller, combined with a novel output-injection observer, is designed and implemented for open-cathode fuel cell temperature control. It is shown that temperature control not only ensures the fuel cell temperature reference is properly maintained, but, along with an uncertainty estimator, can also be used to adaptively stabilize the output voltage --Abstract, page iv

    Capacity Fade Analysis and Model Based Optimization of Lithium-ion Batteries

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    Electrochemical power sources have had significant improvements in design, economy, and operating range and are expected to play a vital role in the future in a wide range of applications. The lithium-ion battery is an ideal candidate for a wide variety of applications due to its high energy/power density and operating voltage. Some limitations of existing lithium-ion battery technology include underutilization, stress-induced material damage, capacity fade, and the potential for thermal runaway. This dissertation contributes to the efforts in the modeling, simulation and optimization of lithium-ion batteries and their use in the design of better batteries for the future. While physics-based models have been widely developed and studied for these systems, the rigorous models have not been employed for parameter estimation or dynamic optimization of operating conditions. The first chapter discusses a systems engineering based approach to illustrate different critical issues possible ways to overcome them using modeling, simulation and optimization of lithium-ion batteries. The chapters 2-5, explain some of these ways to facilitate: i) capacity fade analysis of Li-ion batteries using different approaches for modeling capacity fade in lithium-ion batteries,: ii) model based optimal design in Li-ion batteries and: iii) optimum operating conditions: current profile) for lithium-ion batteries based on dynamic optimization techniques. The major outcomes of this thesis will be,: i) comparison of different types of modeling efforts that will help predict and understand capacity fade in lithium-ion batteries that will help design better batteries for the future,: ii) a methodology for the optimal design of next-generation porous electrodes for lithium-ion batteries, with spatially graded porosity distributions with improved energy efficiency and battery lifetime and: iii) optimized operating conditions of batteries for high energy and utilization efficiency, safer operation without thermal runaway and longer life
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