Fixed-Charge Solid Transportation Problem with Budget Constraints Based on Carbon Emission in Neutrosophic Environment

This paper is to integrate among solid transportation problem, budget constraints and carbon emission with probable maximum profit. The limits of air pollution and climate variation are solely dependent by exerting CO2 gas and rest greenhouse gases due to myriad transportation system. Henceforth, it is our apt mission to minimize carbon emission for pollution free environment. Again transportation system with single objective is hardly applicable to the situation with more than one criterion. Therefore multi- objective decision making is incorporated for designing reallife transportation problem. Due to time pressure, data limitation, lack of information or measurement errors in practical problems, there exist some hesitations or suspicions. Based on the fact, decision maker considers indeterminacy in the designed problems. To overcome the restriction on occurrence and non-occurrence of fuzzy and intuitionistic fuzzy, neutrosophic set is very important and suitable to accommodate such general structure of problems. Therefore neutrosophic environment with neutrosophic linear programming, fuzzy programming and global criterion method are profiled to search the compromise solution of the multi- objective transportation problem (MOTP). Thereafter, the performance of the considered model is useful by evaluating a numerical example; and then the derived results are compared. Finally sensitivity analysis and conclusions with upcoming works of this research are stated hereafter.PID2020-112754GB-I0 B-TIC-640-UGR2

Post Production Heavy Oil Operations: A Case for Partial Upgrading

The transportation of heavy oil is a pressing problem. Various methods have been devised to mitigate the reluctance to flow of these highly dense and viscous oils. This study is focused on evaluating a case for post-production partial upgrading of heavy oil. Specifically, we analyze the impact of visbreaking, a mild thermal cracking method, on the economic and energy demands of the post-production process. Using conservative modeling techniques and principles we find significant cost and energy savings can potentially result out of visbreaking. Cost savings result as a consequence of reduced diluent usage. Even the most conservative modeling scenario under consideration exhibits significant cost savings in the form of reduced diluent usage; these savings not only offset operational costs but provide short payback periods on capital expenditures. Additionally, the lower gravity blend resulting from visbreaking can also bring about energy and cost savings in pipeline transportation and positively impact the heavy oil value chain from the producer to a refinery or regional upgrading facility. From this basic analysis of the potential of visbreaking, we can recommend investing resources to study its viability in the field. Using this analysis as a tipping off point and with a detailed look at the chemistry of the oil in question it is possible to make a very viable case for visbreaking. In a similar vein, this analysis can serve as a guide in making a case for other partial upgrading methods as well

California Methanol Assessment; Volume II, Technical Report

A joint effort by the Jet Propulsion Laboratory and the California Institute of Technology Division of Chemistry and Chemical Engineering has brought together sponsors from both the public and private sectors for an analysis of the prospects for methanol use as a fuel in California, primarily for the transportation and stationary application sectors. Increasing optimism in 1982 for a slower rise in oil prices and a more realistic understanding of the costs of methanol production have had a negative effect on methanol viability in the near term (before the year 2000). Methanol was determined to have some promise in the transportation sector, but is not forecasted for large-scale use until beyond the year 2000. Similarly, while alternative use of methanol can have a positive effect on air quality (reducing NOx, SOx, and other emissions), a best case estimate is for less than 4% reduction in peak ozone by 2000 at realistic neat methanol vehicle adoption rates. Methanol is not likely to be a viable fuel in the stationary application sector because it cannot compete economically with conventional fuels except in very limited cases. On the production end, it was determined that methanol produced from natural gas will continue to dominate supply options through the year 2000, and the present and planned industry capacity is somewhat in excess of all projected needs. Nonsubsidized coal-based methanol cannot compete with conventional feedstocks using current technology, but coal-based methanol has promise in the long term (after the year 2000), providing that industry is willing to take the technical and market risks and that government agencies will help facilitate the environment for methanol. Given that the prospects for viable major markets (stationary applications and neat fuel in passenger cars) are unlikely in the 1980s and early 1990s, the next steps for methanol are in further experimentation and research of production and utilization technologies, expanded use as an octane enhancer, and selected fleet implementation. In the view of the study, it is not advantageous at this time to establish policies within California that attempt to expand methanol use rapidly as a neat fuel for passenger cars or to induce electric utility use of methanol on a widespread basis

Rubberised bitumen manufacturing assisted by rheological measurements

This paper investigates the effect of processing temperature and time on the rheological properties of recycled tyre rubber-modified bitumens (RTR-MBs) produced using two different base binders and an ambient ground crumb rubber modifier (CRM). The production of the RTR-MBs was accomplished by means of a standard Brookfield rotational viscometer together with a modified impeller, dual helical impeller, to allow mixing as well as real-time viscosity measurements of the produced RTR-MBs. The rheological properties of the final RTR-MBs were determined by means of standard dynamic mechanical analysis oscillatory and multiple stress creep recovery testing using a dynamic shear rheometer. The results indicate that the low processing conditions (160°C and 60 min) are not appropriate for developing RTR-MBs with enhanced physical and rheological properties. However, allowing the crumb rubber to interact with the base binder for longer mixing times (140 min) led to the development of an enhanced rubber (polymer) network structure within the blend (i.e. swelling of the CRM particles) and superior rheological properties. At the other extreme, using high-processing conditions (200°C and 140 min) led to RTR-MBs in which the rubber network had been subjected to devulcanisation and depolymerisation with a subsequent reduction in modification

Modelling of Energy-Crops in Agricultural Sector Models - A Review of Existing Methodologies

The present report provides an overview of the different methodologies applied in partial and general equilibrium models used to analyse biofuel policies in Europe, as well as their methodological pros and cons. While the LEITAP model is included as a general equilibrium model covering biofuel demand, partial equilibrium models are represented by ESIM, FAPRI, AGLINK/COSIMO, RAUMIS, AGMEMOD (agricultural models); POLES and PRIMES (energy sector); and EUFASOM/ENFA (forestry sector). The study is highly relevant for the current modelling work at IPTS, where models such as ESIM and AGLINK play an important role in the Integrated Modelling Platform for Agro-economic Commodity and Policy Analysis (iMAP) of the AGRILIFE Unit. Additionally, the POLES model is currently part of the model portfolio used by the Competitiveness & Sustainability Unit in several studies analysing possible technological pathways of energy production and demand for bioenergy in Europe, a result of implementing the biofuel directive. This compilation of information is also important since the implicit and explicit treatment of bioenergy, either as a demand shock to the processing of oilseeds or feedstock for bioethanol and biodiesel, or as the introduction of a biofuel-sector into a computational general equilibrium (CGE) is foreseen in the short-term by other economic models used at IPTS.JRC.J.5-Agriculture and Life Sciences in the Econom

Development of a mix design methodology for asphalt mixtures with analytically formulated aggregate structures

This research documents an extensive study on the design and characterization of asphalt mixtures for use as road pavement material. Several aspects of asphalt mixtures were addressed using the state of the art laboratory test equipment and technical literature from different information sources. The research was divided into two phases. Phase one included the design and detailed analysis of compaction and performance characteristics of asphalt concrete mixtures with aggregate structures that were designed using an analytical method of aggregate blending. Three aggregate types were considered in this study: limestone, sandstone, and granite. All the aggregates were crushed aggregates. Three different aggregate structures were designed for each aggregate type using the Bailey method of aggregate gradation evaluation. The Bailey method is a comprehensive gradation. Sandstone and Granite mixtures had a nominal maximum aggregate size (NMAS) of 12.5mm and were designed for high traffic level, while two types of Limestone mixtures were designed (25.4 mm and 12.5 mm NMAS) for two traffic levels (high and low traffic volumes). For the heavy traffic mixtures the binder type selected was PG 76-22M while PG70-22 was used for low volume mixtures. The outcome of this research suggests that suitable mixes can be developed with dense aggregate structures using the Bailey method of aggregate gradation that provides good resistance to permanent deformation while still maintaining adequate levels of durability. A systematic, simplified design approach was recommended in which asphalt mixtures are designed based on the locking point concept, analytical aggregate gradation method and fundamental mechanistic properties that describe the behavior of asphalt mixtures based on sound engineering principles

Multi-objective fully intuitionistic fuzzy fixed-charge solid transportation problem

During past few decades, fuzzy decision is an important attention in the areas of science, engineering, economic system, business, etc. To solve day-to-day problem, researchers use fuzzy data in transportation problem for presenting the uncontrollable factors; and most of multi-objective transportation problems are solved using goal programming. However, when the problem contains interval-valued data, then the obtained solution was provided by goal programming may not satisfy by all decision-makers. In such condition, we consider a fixed-charge solid transportation problem in multi-objective environment where all the data are intuitionistic fuzzy numbers with membership and non-membership function. The intuitionistic fuzzy transportation problem transforms into interval-valued problem using (α, β)-cut, and thereafter, it reduces into a deterministic problem using accuracy function. Also the optimum value of alternative corresponds to the optimum value of accuracy function. A numerical example is included to illustrate the usefulness of our proposed model. Finally, conclusions and future works with the study are described.Portuguese Foundation for Science and Technology ("FCT-Fundacao para a Ciencia e a Tecnologia"), through the CIDMA-Center for Research and Development in Mathematics and Applications UID/MAT/ 04106/2019Spanish Ministry of Economy and Competitiveness, FEDER funds from the European Union TIN2014-55024-P TIN2017-86647-

Characteristics and Fouling Tendencies of Selected Malaysian Crude Oils

Fouling on the surfaces of heat exchangers, particularly in crude pre-heat train is one of the major challenges faced in crude oil refining. The accumulation of unwanted deposits on the surfaces of heat exchangers is referred to as foulant which causes obstacle to the heat transfer mechanism resulting in lost efficiency. Virgin foulant deposits collected from a local refinery were characterized for its physical and chemical properties using various sophisticated equipment to understand the properties and deposition mechanisms. From this studied it was found that wax formation was the major foulant material. The wax deposition follows two different mechanism routes and reactions i.e. in tube side a slow and steady deposition aided by polymerization reaction, while in the shell side a rapid sedimentation due to film boiling is observed. Based on the fouling tendency its compositions and properties, selected properties of a crude oil associated to it were identified. Three Malaysian crude oils tagged as A, B and C was selected. Each of chosen crude were characterized individually and later blended in accordance to common practice in a local refinery. Asphaltene compatibility parameter was done for fouling tendencies. From the study it was found that all 3 crudes at the predefined blending ratio are compatibility. Further test to understand asphaltene precipitation behavior was also conducted using Design of Experiment (DOE), Taguchi Orthogonal Array L-16 under the influence of temperature, solvent type and resident time. It was found that temperature has the highest impact and that asphaltene deposition; it decreases with increase in temperature. Asphaltene precipitation was also concluded to be significantly influenced by the presence of low molecular hydrocarbon

Emerging technologies for the non-invasive characterization of physical-mechanical properties of tablets

The density, porosity, breaking force, viscoelastic properties, and the presence or absence of any structural defects or irregularities are important physical-mechanical quality attributes of popular solid dosage forms like tablets. The irregularities associated with these attributes may influence the drug product functionality. Thus, an accurate and efficient characterization of these properties is critical for successful development and manufacturing of a robust tablets. These properties are mainly analyzed and monitored with traditional pharmacopeial and non-pharmacopeial methods. Such methods are associated with several challenges such as lack of spatial resolution, efficiency, or sample-sparing attributes. Recent advances in technology, design, instrumentation, and software have led to the emergence of newer techniques for non-invasive characterization of physical-mechanical properties of tablets. These techniques include near infrared spectroscopy, Raman spectroscopy, X-ray microtomography, nuclear magnetic resonance (NMR) imaging, terahertz pulsed imaging, laser-induced breakdown spectroscopy, and various acoustic- and thermal-based techniques. Such state-of-the-art techniques are currently applied at various stages of development and manufacturing of tablets at industrial scale. Each technique has specific advantages or challenges with respect to operational efficiency and cost, compared to traditional analytical methods. Currently, most of these techniques are used as secondary analytical tools to support the traditional methods in characterizing or monitoring tablet quality attributes. Therefore, further development in the instrumentation and software, and studies on the applications are necessary for their adoption in routine analysis and monitoring of tablet physical-mechanical properties