Paramagnetic GaN:Fe and ferromagnetic (Ga,Fe)N - relation between structural, electronic, and magnetic properties

We report on the metalorganic chemical vapor deposition (MOCVD) of GaN:Fe and (Ga,Fe)N layers on c-sapphire substrates and their thorough characterization via high-resolution x-ray diffraction (HRXRD), transmission electron microscopy (TEM), spatially-resolved energy dispersive X-ray spectroscopy (EDS), secondary-ion mass spectroscopy (SIMS), photoluminescence (PL), Hall-effect, electron-paramagnetic resonance (EPR), and magnetometry employing a superconducting quantum interference device (SQUID). A combination of TEM and EDS reveals the presence of coherent nanocrystals presumably FexN with the composition and lattice parameter imposed by the host. From both TEM and SIMS studies, it is stated that the density of nanocrystals and, thus the Fe concentration increases towards the surface. In layers with iron content x<0.4% the presence of ferromagnetic signatures, such as magnetization hysteresis and spontaneous magnetization, have been detected. We link the presence of ferromagnetic signatures to the formation of Fe-rich nanocrystals, as evidenced by TEM and EDS studies. This interpretation is supported by magnetization measurements after cooling in- and without an external magnetic field, pointing to superparamagnetic properties of the system. It is argued that the high temperature ferromagnetic response due to spinodal decomposition into regions with small and large concentration of the magnetic component is a generic property of diluted magnetic semiconductors and diluted magnetic oxides showing high apparent Curie temperature.Comment: 21 pages, 30 figures, submitted to Phys. Rev.

A Transformerless PCB Based Medium-Voltage Multilevel Power Converter with A DC Capacitor Balancing Circuit and Algorithm

This dissertation presents a new method of constructing a transformerless, voltage-sourced, medium-voltage multilevel converter using existing discrete power semiconductor devices and printed circuit board technology. While the approach is general, it is particularly well-suited for medium-voltage converters and motor-drives in the 4.16 kV, 500 - 1000 kW range. A novel way of visualizing the power stage topology is developed which allows simplified mechanical layouts while managing the commutation paths. Using so many discrete devices typically drives cost and complexity of the gate-drive system including its control and isolation; a gate-drive circuit is presented to address this problem. As with most multilevel topologies, the dc-link voltages must be balanced during operation. This is accomplished using an auxiliary circuit made up of the same power stage and an associated control algorithm. Experimental results are presented for a 4.16 kV, 746 kW, five-level power converter prototype. This dissertation also analyzes a new capacitor voltage-balancing converter along with a novel capacitor voltage balancing control algorithm. Analysis of the inverter system provides a new description of capacitor voltage stability as a function of system operating conditions

Field-control, phase-transitions, and life's emergence

Instances of critical-like characteristics in living systems at each organizational level as well as the spontaneous emergence of computation (Langton), indicate the relevance of self-organized criticality (SOC). But extrapolating complex bio-systems to life's origins, brings up a paradox: how could simple organics--lacking the 'soft matter' response properties of today's bio-molecules--have dissipated energy from primordial reactions in a controlled manner for their 'ordering'? Nevertheless, a causal link of life's macroscopic irreversible dynamics to the microscopic reversible laws of statistical mechanics is indicated via the 'functional-takeover' of a soft magnetic scaffold by organics (c.f. Cairns-Smith's 'crystal-scaffold'). A field-controlled structure offers a mechanism for bootstrapping--bottom-up assembly with top-down control: its super-paramagnetic components obey reversible dynamics, but its dissipation of H-field energy for aggregation breaks time-reversal symmetry. The responsive adjustments of the controlled (host) mineral system to environmental changes would bring about mutual coupling between random organic sets supported by it; here the generation of long-range correlations within organic (guest) networks could include SOC-like mechanisms. And, such cooperative adjustments enable the selection of the functional configuration by altering the inorganic network's capacity to assist a spontaneous process. A non-equilibrium dynamics could now drive the kinetically-oriented system towards a series of phase-transitions with appropriate organic replacements 'taking-over' its functions.Comment: 54 pages, pdf fil

A Multi-Objective HBMO-Based New FC-MCR Compensator for Damping of Power System Oscillations

In this paper, a novel compensator based on Magnetically Controlled Reactor with Fixed Capacitor banks (FC-MCR) is introduced and then power system stability in presence of this compensator is studied using an intelligent control method. The problem of robust FC-MCR-based damping controller design is formulated as a multi-objective optimization problem. The multi-objective problem is concocted to optimize a composite set of two eigenvalue-based objective functions comprising the desired damping factor, and the desired damping ratio of the lightly damped and undamped electromechanical modes. The controller is automatically tuned by optimization of an eigenvalue-based multi-objective function using Honey Bee Mating Optimization (HBMO) to simultaneously shift the lightly damped and undamped electromechanical modes to a prescribed zone in the s-plane so that the relative stability is guaranteed and the time domain specifications concurrently secured. The effectiveness of the proposed controller in damping low frequency oscillations under different operating conditions is demonstrated through eigenvalue analysis and nonlinear time simulation studies. The results show that the tuned HBMO-based FC-MCR controller which is designed by using the proposed multi-objective function has an outstanding capability in damping power system low frequency oscillations and significantly improves the power systems dynamic stability

Insights into dynamic tuning of magnetic-resonant wireless power transfer receivers based on switch-mode gyrators

Magnetic-resonant wireless power transfer (WPT) has become a reliable contactless source of power for a wide range of applications. WPT spans different power levels ranging from low-power implantable devices up to high-power electric vehicles (EV) battery charging. The transmission range and efficiency of WPT have been reasonably enhanced by resonating the transmitter and receiver coils at a common frequency. Nevertheless, matching between resonance in the transmitter and receiver is quite cumbersome, particularly in single-transmitter multi-receiver systems. The resonance frequency in transmitter and receiver tank circuits has to be perfectly matched, otherwise power transfer capability is greatly degraded. This paper discusses the mistuning effect of parallel-compensated receivers, and thereof a novel dynamic frequency tuning method and related circuit topology and control is proposed and characterized in the system application. The proposed method is based on the concept of switch-mode gyrator emulating variable lossless inductors oriented to enable self-tunability in WPT receiversPeer ReviewedPostprint (published version

Load Management System with Integration of Renewable Energy Resources

This article presents, a load management system is designed and implemented to integrate renewable energy resources (RES) (solar and wind), which manage the load according to the supply/demand and the user's priorities. The system is implemented on a hybrid system integrating wind energy, solar energy, utility supply, and battery energy storage system. Load management is carried out via switching of the loads. The sources can also be turned ON and OFF. During excess power, the battery module works as an energy storage unit or backup energy supply unit during demand. Loads can be turned ON and OFF wirelessly via GSM. The grid operator can switch the loads by simply sending a command via a short service message (SMS). In the end, the system is tested, and the results are presented.&nbsp;&nbsp; The hybrid system is simulated in MATLAB/Simulink first and then hardware implementation is carried out, which involves integrating renewable resources via converters and load management by switching using a microcontroller (Arduino)

Unique Properties of Thermally Tailored Copper: Magnetically Active Regions and Anomalous X-ray Fluorescence Emissions

When high-purity copper (≥99.98%wt) is melted, held in its liquid state for a few hours with iterative thermal cycling, then allowed to resolidify, the ingot surface is found to have many small regions that are magnetically active. X-ray fluorescence analysis of these regions exhibit remarkably intense lines from “sensitized elements” (SE), including in part or fully the contiguous series V, Cr, Mn, Fe, and Co. The XRF emissions from SE are far more intense than expected from known impurity levels. Comparison with blanks and standards show that the thermal “tailoring” also introduces strongly enhanced SE emissions in samples taken from the interior of the copper ingots. For some magnetic regions, the location as well as the SE emissions, although persistent, vary irregularly with time. Also, for some regions extraordinarily intense “sensitized iron” (SFe) emissions occur, accompanied by drastic attenuation of Cu emissions