On the corrections to Strong-Stretching Theory for end-confined, charged polymers in a uniform electric field

We investigate the properties of a system of semi-diluted polymers in the presence of charged groups and counter-ions, by means of self-consistent field theory. We study a system of polyelectrolyte chains grafted to a similarly, as well as an oppositely charged surface, solving a set of saddle-point equations that couple the modified diffusion equation for the polymer partition function to the Poisson-Boltzmann equation describing the charge distribution in the system. A numerical study of this set of equations is presented and comparison is made with previous studies. We then consider the case of semi-diluted, grafted polymer chains in the presence of charge-end-groups. We study the problem with self-consistent field as well as strong-stretching theory. We derive the corrections to the Milner-Witten-Cates (MWC) theory for weakly charged chains and show that the monomer-density deviates from the parabolic profile expected in the uncharged case. The corresponding corrections are shown to be dictated by an Abel-Volterra integral equation of the second kind. The validity of our theoretical findings is confirmed comparing the predictions with the results obtained within numerical self-consistent field theory.Comment: 15 Pages, 12 figure

Methods in Mathematica for Solving Ordinary Differential Equations

An overview of the solution methods for ordinary differential equations in the Mathematica function DSolve is presented.Comment: 13 page

A comparison between numerical solutions to fractional differential equations: Adams-type predictor-corrector and multi-step generalized differential transform method

In this note, two numerical methods of solving fractional differential equations (FDEs) are briefly described, namely predictor-corrector approach of Adams-Bashforth-Moulton type and multi-step generalized differential transform method (MSGDTM), and then a demonstrating example is given to compare the results of the methods. It is shown that the MSGDTM, which is an enhancement of the generalized differential transform method, neglects the effect of non-local structure of fractional differentiation operators and fails to accurately solve the FDEs over large domains.Comment: 12 pages, 2 figure