Two hard spheres in a pore: Exact Statistical Mechanics for different shaped cavities

The Partition function of two Hard Spheres in a Hard Wall Pore is studied appealing to a graph representation. The exact evaluation of the canonical partition function, and the one-body distribution function, in three different shaped pores are achieved. The analyzed simple geometries are the cuboidal, cylindrical and ellipsoidal cavities. Results have been compared with two previously studied geometries, the spherical pore and the spherical pore with a hard core. The search of common features in the analytic structure of the partition functions in terms of their length parameters and their volumes, surface area, edges length and curvatures is addressed too. A general framework for the exact thermodynamic analysis of systems with few and many particles in terms of a set of thermodynamic measures is discussed. We found that an exact thermodynamic description is feasible based in the adoption of an adequate set of measures and the search of the free energy dependence on the adopted measure set. A relation similar to the Laplace equation for the fluid-vapor interface is obtained which express the equilibrium between magnitudes that in extended systems are intensive variables. This exact description is applied to study the thermodynamic behavior of the two Hard Spheres in a Hard Wall Pore for the analyzed different geometries. We obtain analytically the external work, the pressure on the wall, the pressure in the homogeneous zone, the wall-fluid surface tension, the line tension and other similar properties

Non-retracing orbits in Andreev billiards

The validity of the retracing approximation in the semiclassical quantization of Andreev billiards is investigated. The exact energy spectrum and the eigenstates of normal-conducting, ballistic quantum dots in contact with a superconductor are calculated by solving the Bogoliubov-de Gennes equation and compared with the semiclassical Bohr-Sommerfeld quantization for periodic orbits which result from Andreev reflections. We find deviations that are due to the assumption of exact retracing electron-hole orbits rather than the semiclassical approximation, as a concurrently performed Einstein-Brillouin-Keller quantization demonstrates. We identify three different mechanisms producing non-retracing orbits which are directly identified through differences between electron and hole wave functions.Comment: 9 pages, 12 figures, Phys. Rev. B (in print), high resolution images available upon reques

Scaled Particle Theory for Hard Sphere Pairs. I. Mathematical Structure

We develop an extension of the original Reiss-Frisch-Lebowitz scaled particle theory that can serve as a predictive method for the hard sphere pair correlation function g(r). The reversible cavity creation work is analyzed both for a single spherical cavity of arbitrary size, as well as for a pair of identical such spherical cavities with variable center-to-center separation. These quantities lead directly to prediction of g(r). Smooth connection conditions have been identified between the small-cavity situation where the work can be exactly and completely expressed in terms of g(r), and the large-cavity regime where macroscopic properties become relevant. Closure conditions emerge which produce a nonlinear integral equation that must be satisfied by the pair correlation function. This integral equation has a structure which straightforwardly generates a solution that is a power series in density. The results of this series replicate the exact second and third virial coefficients for the hard sphere system via the contact value of the pair correlation function. The predicted fourth virial coefficient is approximately 0.6 percent lower than the known exact value. Detailed numerical analysis of the nonlinear integral equation has been deferred to the sequel (following paper

Photonic currents in driven and dissipative resonator lattices

Arrays of coupled photonic cavities driven by external lasers represent a highly controllable setup to explore photonic transport. In this paper we address (quasi)-steady states of this system that exhibit photonic currents introduced by engineering driving and dissipation. We investigate two approaches: in the first one, photonic currents arise as a consequence of a phase difference of applied lasers and in the second one, photons are injected locally and currents develop as they redistribute over the lattice. Effects of interactions are taken into account within a mean-field framework. In the first approach, we find that the current exhibits a resonant behavior with respect to the driving frequency. Weak interactions shift the resonant frequency toward higher values, while in the strongly interacting regime in our mean-field treatment the effect stems from multiphotonic resonances of a single driven cavity. For the second approach, we show that the overall lattice current can be controlled by incorporating few cavities with stronger dissipation rates into the system. These cavities serve as sinks for photonic currents and their effect is maximal at the onset of quantum Zeno dynamics.Comment: 12 pages, 11 figure