35 research outputs found
Adaptive Heterogeneous Multi-Population Cultural Algorithm
Optimization problems is a class of problems where the goal is to make a system as effective as possible. The goal of this research area is to design an algorithm to solve optimization problems effectively and efficiently. Being effective means that the algorithm should be able to find the optimal solution (or near optimal solutions), while efficiency refers to the computational effort required by the algorithm to find an optimal solution. In other words, an optimization algorithm should be able to find the optimal solution in an acceptable time. Therefore, the aim of this dissertation is to come up with a new algorithm which presents an effective as well as efficient performance. There are various kinds of algorithms proposed to deal with optimization problems. Evolutionary Algorithms (EAs) is a subset of population-based methods which are successfully applied to solve optimization problems. In this dissertation the area of evolutionary methods and specially Cultural Algorithms (CAs) are investigated. The results of this investigation reveal that there are some room for improving the existing EAs. Consequently, a number of EAs are proposed to deal with different optimization problems. The proposed EAs offer better performance compared to the state-of-the-art methods. The main contribution of this dissertation is to introduce a new architecture for optimization algorithms which is called Heterogeneous Multi-Population Cultural Algorithm (HMP-CA). The new architecture first incorporates a decomposition technique to divide the given problem into a number of sub-problems, and then it assigns the sub-problems to different local CAs to be optimized separately in parallel. In order to evaluate the proposed architecture, it is applied on numerical optimization problems. The evaluation results reveal that HMP-CA is fully effective such that it can find the optimal solution for every single run. Furthermore, HMP-CA outperforms the state-of-the-art methods by offering a more efficient performance. The proposed HMP-CA is further improved by incorporating an adaptive decomposition technique. The improved version which is called Adaptive HMP-CA (A-HMP-CA) is evaluated over large scale global optimization problems. The results of this evaluation show that HMP-CA significantly outperforms the state-of-the-art methods in terms of both effectiveness and efficiency
Model-based approach for the plant-wide economic control of fluid catalytic cracking unit
Fluid catalytic cracking (FCC) is one of the most important processes in the petroleum refining industry for the conversion of heavy gasoil to gasoline and diesel. Furthermore, valuable gases such as ethylene, propylene and isobutylene are produced. The performance of the FCC units plays a major role on the overall economics of refinery plants. Any improvement in operation or control of FCC units will result in dramatic economic benefits. Present studies are concerned with the general behaviour of the industrial FCC plant, and have dealt with the modelling of the FCC units, which are very useful in elucidating the main characteristics of these systems for better design, operation, and control. Traditional control theory is no longer suitable for the increasingly sophisticated operating conditions and product specifications of the FCC unit. Due to the large economic benefits, these trends make the process control more challenging. There is now strong demand for advanced control strategies with higher quality to meet the challenges imposed by the growing technological and market competition. According to these highlights, the thesis objectives were to develop a new mathematical model for the FCC process, which was used to study the dynamic behaviour of the process and to demonstrate the benefits of the advanced control (particularly Model Predictive Control based on the nonlinear process model) for the FCC unit. The model describes the seven main sections of the entire FCC unit: (1) the feed and preheating system, (2) reactor, (3) regenerator, (4) air blower, (5) wet gas compressor, (6) catalyst circulation lines and (7) main fractionators. The novelty of the developed model consists in that besides the complex dynamics of the reactorregenerator system, it includes the dynamic model of the fractionator, as well as a new five lump kinetic model for the riser, which incorporates the temperature effect on the reaction kinetics; hence, it is able to predict the final production rate of the main products (gasoline and diesel), and can be used to analyze the effect of changing process conditions on the product distribution. The FCC unit model has been developed incorporating the temperature effect on reactor kinetics reference construction and operation data from an industrial unit. The resulting global model of the FCC unit is described by a complex system of partial-differential-equations, which was solved by discretising the kinetic models in the riser and regenerator on a fixed grid along the height of the units, using finite differences. The resulting model is a high order DAE, with 942 ODEs (142 from material and energy balances and 800 resulting from the discretisation of the kinetic models). The model offers the possibility of investigating the way that advanced control strategies can be implemented, while also ensuring that the operation of the unit is environmentally safe. All the investigated disturbances showed considerable influence on the products composition. Taking into account the very high volume production of an industrial FCC unit, these disturbances can have a significant economic impact. The fresh feed coke formation factor is one of the most important disturbances analysed. It shows significant effect on the process variables. The objective regarding the control of the unit has to consider not only to improve productivity by increasing the reaction temperature, but also to assure that the operation of the unit is environmentally safe, by keeping the concentration of CO in the stack gas below a certain limit. The model was used to investigate different control input-output pairing using classical controllability analysis based on relative gain array (RGA). Several multi-loop control schemes were first investigated by implementing advanced PID control using anti-windup. A tuning approach for the simultaneous tuning of multiple interacting PID controllers was proposed using a genetic algorithm based nonlinear optimisation approach. Linear model predictive control (LMPC) was investigated as a potential multi-variate control scheme applicable for the FCCU, using classical square as well as novel non-square control structures. The analysis of the LMPC control performance highlighted that although the multivariate nature of the MPC approach using manipulated and controlled outputs which satisfy controllability criteria based on RGA analysis can enhance the control performance, by decreasing the coupling between the individual low level control loops operated by the higher level MPC. However the limitations of using the linear model in the MPC scheme were also highlighted and hence a nonlinear model based predictive control scheme was developed and evaluated.EThOS - Electronic Theses Online ServiceGBUnited Kingdo
New Strategies for Global Optimization of Chemical Engineering Applications by Differential Evolution
Ph.DDOCTOR OF PHILOSOPH
Chemical production complex optimization, pollution reduction and sustainable development
The objective of this research is to propose, develop and demonstrate chemical production complex optimization to determine the optimal configuration of chemical plants in a superstructure of possible plants. The Chemical Complex Analysis System is a new methodology that has been developed to determine the best configuration of plants in a chemical production complex based on the AIChE Total Cost Assessment (TCA) for economic, energy, environmental and sustainable costs. All new, energy-efficient, and environmentally acceptable plants using greenhouse gases that can produce potentially commercial products designed with HYSYS were integrated into the chemical complex using the System. The optimum configuration of plants was determined based on the triple bottom line that includes sales, economic, environmental and sustainable costs using the System. From eighteen new processes in the superstructure, the optimum structure had seven potentially new processes including acetic acid, graphite, formic acid, methylamines, propylene and synthesis gas production. With the additional plants in the optimal structure the triple bottom line increased from 506 million per year and energy increased from 2,150 to 5,791 TJ/year. Multicriteria optimization has been used with Monte Carlo simulation to determine the sensitivity of the optimal structure of a chemical production complex to prices, costs, and sustainable credits/cost. In essence, for each Pareto optimal solution, there is a cumulative probability distribution function that is the probability as a function of the triple bottom line. This information provides a quantitative assessment of the optimum profit versus sustainable credits/cost, and the risk (probability) that the triple bottom line will meet expectations. The capabilities of the System have been demonstrated, and this methodology could be applied to other chemical production complexes in the world for reduced emissions and energy savings. With this System, engineers will have a new capability to consider projects in depths significantly beyond current capabilities. They will be able to convert their company’s goals and capital into viable projects that meet economic, environmental and sustainable requirements
Book of abstracts of the 10th International Chemical and Biological Engineering Conference: CHEMPOR 2008
This book contains the extended abstracts presented at the 10th International Chemical and Biological
Engineering Conference - CHEMPOR 2008, held in Braga, Portugal, over 3 days, from the 4th to the 6th of
September, 2008. Previous editions took place in Lisboa (1975, 1889, 1998), Braga (1978), Póvoa de
Varzim (1981), Coimbra (1985, 2005), Porto (1993), and Aveiro (2001).
The conference was jointly organized by the University of Minho, “Ordem dos Engenheiros”, and the IBB -
Institute for Biotechnology and Bioengineering with the usual support of the “Sociedade Portuguesa de
Química” and, by the first time, of the “Sociedade Portuguesa de Biotecnologia”.
Thirty years elapsed since CHEMPOR was held at the University of Minho, organized by T.R. Bott, D. Allen,
A. Bridgwater, J.J.B. Romero, L.J.S. Soares and J.D.R.S. Pinheiro. We are fortunate to have Profs. Bott, Soares
and Pinheiro in the Honor Committee of this 10th edition, under the high Patronage of his Excellency the
President of the Portuguese Republic, Prof. Aníbal Cavaco Silva. The opening ceremony will confer Prof.
Bott with a “Long Term Achievement” award acknowledging the important contribution Prof. Bott brought
along more than 30 years to the development of the Chemical Engineering science, to the launch of
CHEMPOR series and specially to the University of Minho. Prof. Bott’s inaugural lecture will address the
importance of effective energy management in processing operations, particularly in the effectiveness of
heat recovery and the associated reduction in greenhouse gas emission from combustion processes.
The CHEMPOR series traditionally brings together both young and established researchers and end users
to discuss recent developments in different areas of Chemical Engineering. The scope of this edition is
broadening out by including the Biological Engineering research. One of the major core areas of the
conference program is life quality, due to the importance that Chemical and Biological Engineering plays in
this area. “Integration of Life Sciences & Engineering” and “Sustainable Process-Product Development
through Green Chemistry” are two of the leading themes with papers addressing such important issues.
This is complemented with additional leading themes including “Advancing the Chemical and Biological
Engineering Fundamentals”, “Multi-Scale and/or Multi-Disciplinary Approach to Process-Product
Innovation”, “Systematic Methods and Tools for Managing the Complexity”, and “Educating Chemical and
Biological Engineers for Coming Challenges” which define the extended abstracts arrangements along this
book.
A total of 516 extended abstracts are included in the book, consisting of 7 invited lecturers, 15 keynote,
105 short oral presentations given in 5 parallel sessions, along with 6 slots for viewing 389 poster
presentations. Full papers are jointly included in the companion Proceedings in CD-ROM. All papers have
been reviewed and we are grateful to the members of scientific and organizing committees for their
evaluations. It was an intensive task since 610 submitted abstracts from 45 countries were received.
It has been an honor for us to contribute to setting up CHEMPOR 2008 during almost two years. We wish
to thank the authors who have contributed to yield a high scientific standard to the program. We are
thankful to the sponsors who have contributed decisively to this event. We also extend our gratefulness to
all those who, through their dedicated efforts, have assisted us in this task.
On behalf of the Scientific and Organizing Committees we wish you that together with an interesting
reading, the scientific program and the social moments organized will be memorable for all.Fundação para a Ciência e a Tecnologia (FCT
The socio-technical dynamics of chemical feedstock transitions : the case of renewable raw materials in the UK
Much public and private effort is being directed towards the development of more sustainable
chemical feedstocks, yet the associated complexities of technological transitions and the
technical, institutional and policy-related challenges they raise are often not wholly
recognised. This thesis aims to develop an understanding of the key dynamics of
technological change in the chemical industry, with respect to changes in feedstocks and the
influence of the changing energy (and climate policy) landscape. It builds on, and contributes
to, the ‘innovations’ literature that seeks to translate empirical research on past technological
transitions into practical guidance for policy-makers. In particular, this thesis explores the
relevance of the close relationship – or ‘co-evolution’ – between chemicals and liquid fuels
production, which has not been analysed elsewhere.
Transitions between technological systems involve evolutionary processes. The past both
shapes the current system and influences future options and pathways. This thesis
investigates the historical transition from coal-based to petrochemical feedstocks in the UK
(1921-1967), applying a system dynamics approach to extract and elucidate the key
interrelationships between technologies, policy and society. The findings are then used to
inform a series of interviews with key organisations to gain insights into expectations for
renewable raw materials (RRM) in the UK. The results provide a strong indication of the
decision-making procedures of actors, and tensions between different industrial activities.
They thus provide an empirical basis for developing foresight scenarios that might help
inform the current debate about technological transitions, especially those to RRM.
This thesis shows that the technological trajectory of the organic chemical industry has for
many decades been influenced heavily by governmental attempts to steer technological
change towards a changing set of policy priorities. This process has been accompanied by
attempts of industrialists to steer policy priorities towards preferred technological trajectories.
Parallels can be drawn with the current attempts of policymakers to achieve greater societal
sustainability. Results indicate that the innovation system around RRM is already
experiencing the socio-technical dynamics of regime disruption and competing designs
California Methanol Assessment; Volume II, Technical Report
A joint effort by the Jet Propulsion Laboratory and the California Institute of Technology Division of Chemistry and Chemical Engineering has brought together sponsors from both the public and private sectors for an analysis of the prospects for methanol use as a fuel in California, primarily for the transportation and stationary application sectors. Increasing optimism in 1982 for a slower rise in oil prices and a more realistic understanding of the costs of methanol production have had a negative effect on methanol viability in the near term (before the year 2000). Methanol was determined to have some promise in the transportation sector, but is not forecasted for large-scale use until beyond the year 2000. Similarly, while alternative use of methanol can have a positive effect on air quality (reducing NOx, SOx, and other emissions), a best case estimate is for less than 4% reduction in peak ozone by 2000 at realistic neat methanol vehicle adoption rates. Methanol is not likely to be a viable fuel in the stationary application sector because it cannot compete economically with conventional fuels except in very limited cases. On the production end, it was determined that methanol produced from natural gas will continue to dominate supply options through the year 2000, and the present and planned industry capacity is somewhat in excess of all projected needs. Nonsubsidized coal-based methanol cannot compete with conventional feedstocks using current technology, but coal-based methanol has promise in the long term (after the year 2000), providing that industry is willing to take the technical and market risks and that government agencies will help facilitate the environment for methanol.
Given that the prospects for viable major markets (stationary applications and neat fuel in passenger cars) are unlikely in the 1980s and early 1990s, the next steps for methanol are in further experimentation and research of production and utilization technologies, expanded use as an octane enhancer, and selected fleet implementation. In the view of the study, it is not advantageous at this time to establish policies within California that attempt to expand methanol use rapidly as a neat fuel for passenger cars or to induce electric utility use of methanol on a widespread basis
Non-covalent interactions in organotin(IV) derivatives of 5,7-ditertbutyl- and 5,7-diphenyl-1,2,4-triazolo[1,5-a]pyrimidine as recognition motifs in crystalline self- assembly and their in vitro antistaphylococcal activity
Non-covalent interactions are known to play a key role in biological compounds due to their
stabilization of the tertiary and quaternary structure of proteins [1]. Ligands similar to purine rings,
such as triazolo pyrimidine ones, are very versatile in their interactions with metals and can act as
model systems for natural bio-inorganic compounds [2]. A considerable series (twelve novel
compounds are reported) of 5,7-ditertbutyl-1,2,4-triazolo[1,5-a]pyrimidine (dbtp) and 5,7-diphenyl-
1,2,4-triazolo[1,5-a]pyrimidine (dptp) were synthesized and investigated by FT-IR and 119Sn
M\uf6ssbauer in the solid state and by 1H and 13C NMR spectroscopy, in solution [3]. The X-ray
crystal and molecular structures of Et2SnCl2(dbtp)2 and Ph2SnCl2(EtOH)2(dptp)2 were described, in
this latter pyrimidine molecules are not directly bound to the metal center but strictly H-bonded,
through N(3), to the -OH group of the ethanol moieties. The network of hydrogen bonding and
aromatic interactions involving pyrimidine and phenyl
rings in both complexes drives their self-assembly. Noncovalent
interactions involving aromatic rings are key
processes in both chemical and biological recognition,
contributing to overall complex stability and forming
recognition motifs. It is noteworthy that in
Ph2SnCl2(EtOH)2(dptp)2 \u3c0\u2013\u3c0 stacking interactions between
pairs of antiparallel triazolopyrimidine rings mimick basepair
interactions physiologically occurring in DNA (Fig.1).
M\uf6ssbauer spectra suggest for Et2SnCl2(dbtp)2 a
distorted octahedral structure, with C-Sn-C bond angles
lower than 180\ub0. The estimated angle for Et2SnCl2(dbtp)2
is virtually identical to that determined by X-ray diffraction. Ph2SnCl2(EtOH)2(dptp)2 is
characterized by an essentially linear C-Sn-C fragment according to the X-ray all-trans structure.
The compounds were screened for their in vitro antibacterial activity on a group of reference
staphylococcal strains susceptible or resistant to methicillin and against two reference Gramnegative
pathogens [4] . We tested the biological activity of all the specimen against a group of
staphylococcal reference strains (S. aureus ATCC 25923, S. aureus ATCC 29213, methicillin
resistant S. aureus 43866 and S. epidermidis RP62A) along with Gram-negative pathogens (P.
aeruginosa ATCC9027 and E. coli ATCC25922). Ph2SnCl2(EtOH)2(dptp)2 showed good
antibacterial activity with a MIC value of 5 \u3bcg mL-1 against S. aureus ATCC29213 and also
resulted active against methicillin resistant S. epidermidis RP62A
Energy: A continuing bibliography with indexes
This bibliography lists 1546 reports, articles, and other documents introduced into the NASA scientific and technical information system from April 1, 1981 through June 30, 1981