680,196 research outputs found

    Dc self-field critical current in superconductor dirac-cone material/superconductor junctions

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    Recently, several research groups have reported on anomalous enhancement of the self-field critical currents, Ic(sf,T), at low temperatures in superconductor/Dirac-cone material/superconductor (S/DCM/S) junctions. Some papers attributed the enhancement to the low-energy Andreev bound states arising from winding of the electronic wave function around DCM. In this paper, Ic(sf,T) in S/DCM/S junctions have been analyzed by two approaches: Modified Ambegaokar-Baratoff and ballistic Titov-Beenakker models. It is shown that the ballistic model is an inadequate tool to analyze experimental data from S/DCM/S junctions. The primary mechanism for limiting superconducting current in S/DCM/S junctions is different from the conventional view that the latter is the maximum value within the order parameter phase variation. Thus, there is a need to develop a new model for self-field critical currents in S/DCM/S systems. © 2019 by the authors. Licensee MDPI, Basel, Switzerland.02.A03.21.0006AAAA-A18-118020190104-3Funding: This research was funded by the State Assignment of Minobrnauki of Russia, theme “Pressure” No. AAAA-A18-118020190104-3, and by Act 211 Government of the Russian Federation, contract No. 02.A03.21.0006

    Oxidation kinetics of chromium and morphological phenomena

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    The oxidation kinetics of chromium at 900°C are independent of the oxygen partial pressure. Although this observation gives evidence for a defect mechanism where chromium interstitials account for the chromium transport in the oxide scale, the experimental phenomena do not support one single model. The occurrence of oxide whiskers and oxide ridges are explained by the energy of activation for the breakup of the oxidant molecule. Large oxide pegs are formed at metal multiple-grain junctions after scale breakdown.\u

    Ab initio study of the mechanism of carboxylic acids cross-ketonization on monoclinic zirconia via condensation to beta-keto acids followed by decarboxylation

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    Catalytic mechanism of acetic and isobutyric acids mixture conversion into two symmetrical and one cross-ketone product on monoclinic zirconia (111) surface was extensively modeled by Density Functional Theory for periodic structures. Several options were evaluated for each mechanistic step by calculating their reaction rate constants. The best option for each kinetically relevant step was chosen by matching calculated rates of reaction with experimental values. Four zirconium surface atoms define each catalytic site. The most favorable pathway includes condensation between surface carboxylates, one of which is enolized through alpha-hydrogen abstraction by lattice oxygen. Condensation of gas phase molecules with the enolized carboxylate on surface is less attainable. The kinetic scheme considers all steps being reversible, except for decarboxylation. The equilibrium constant of the enolization step and the rate constant of the condensation step define the global reaction rate for non-bulky acetic acid. For bulky isobutyric acid, decarboxylation step is added to the kinetic scheme as kinetically significant, while hydrocarbonate departure may also compete with the decarboxylation. Electronic and steric effect of alkyl substituents on the decarboxylation step is disclosed. The cross-selectivity is controlled by both condensation and decarboxylation steps. None of the mechanistic steps require metal oxide to be reducible/oxidizable

    CP Violation

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    Several pieces of direct and indirect evidence now suggest that the Kobayashi-Maskawa mechanism plays a distinguished role for CP violation at the electroweak scale. This talk provides a general overview of CP violation in its various contexts, emphasizing CP violation in flavour-violating interactions, such as due to the Kobayashi-Maskawa mechanism. I then review a few recent theoretical developments relevant to the interpretation of CP violation.Comment: 27 pages, LaTeX; plenary talk presented at the International Europhysics Conference on High Energy Physics, Budapest, July 2001; manuscript has some overlap with hep-lat/020101

    Eruption of a Kink-Unstable Filament in Active Region NOAA 10696

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    We present rapid-cadence Transition Region And Coronal Explorer (TRACE) observations which show evidence of a filament eruption from active region NOAA 10696, accompanied by an X2.5 flare, on 2004 November 10. The eruptive filament, which manifests as a fast coronal mass ejection some minutes later, rises as a kinking structure with an apparently exponential growth of height within TRACE's field of view. We compare the characteristics of this filament eruption with MHD numerical simulations of a kink-unstable magnetic flux rope, finding excellent qualitative agreement. We suggest that, while tether weakening by breakout-like quadrupolar reconnection may be the release mechanism for the previously confined flux rope, the driver of the expansion is most likely the MHD helical kink instability.Comment: Accepted by ApJ Letters. 4 figures (Fig. 3 in two parts). For MPEG files associated with Figure 1, see: http://www.mssl.ucl.ac.uk/~drw/papers/kink/ktrace.mpg http://www.mssl.ucl.ac.uk/~drw/papers/kink/kmdi.mpg http://www.mssl.ucl.ac.uk/~drw/papers/kink/ksimu.mp

    Monetary policy transmission mechanism in Samoa

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    In recent years, Samoa has emerged to be the most successful economy amongst all Pacific island countries. Its achievements of low inflation and high growth rates were due to sustained fiscal adjustment and appropriate monetary policy measures. This paper undertakes an empirical study of transmission mechanism of monetary policy by adopting a VAR approach and using quarterly data over a 17-year period (1990-2006). The study findings are that money and exchange rate channels are important channels in transmitting monetary impulses to Samoa’s real sector, followed by credit and interest rate channels
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