Direct Experimental Evidence for Differing Reactivity Alterations of Minerals following Irradiation: The Case of Calcite and Quartz

Concrete, a mixture formed by mixing cement, water, and fine and coarse mineral aggregates is used in the construction of nuclear power plants (NPPs), e.g., to construct the reactor cavity concrete that encases the reactor pressure vessel, etc. In such environments, concrete may be exposed to radiation (e.g., neutrons) emanating from the reactor core. Until recently, concrete has been assumed relatively immune to radiation exposure. Direct evidence acquired on Ar$^+$-ion irradiated calcite and quartz indicates, on the contrary, that, such minerals, which constitute aggregates in concrete, may be significantly altered by irradiation. Specifically, while quartz undergoes disordering of its atomic structure resulting in a near complete lack of periodicity, i.e., similar to glassy silica, calcite only experiences random rotations, and distortions of its carbonate groups. As a result, irradiated quartz shows a reduction in density of around 15%, and an increase in chemical reactivity, described by its dissolution rate, similar to a glassy silica; i.e., an increase of around 3 orders of magnitude. Calcite however, shows little change in dissolution rates - although its density noted to reduce by around 9%. These differences are correlated with the nature of bonds in these minerals, i.e., being dominantly ionic or covalent, and the rigidity of the mineral's atomic network that is characterized by the number of topological constraints (n$_c$) that are imposed on the atoms in the network. The outcomes are discussed within the context of the durability of concrete structural elements formed with calcitic/quartzitic aggregates in nuclear power plants

Towards a Unified Quark-Hadron Matter Equation of State for Applications in Astrophysics and Heavy-Ion Collisions

We outline an approach to a unified equation of state for quark-hadron matter on the basis of a $\Phi-$derivable approach to the generalized Beth-Uhlenbeck equation of state for a cluster decomposition of thermodynamic quantities like the density. To this end we summarize the cluster virial expansion for nuclear matter and demonstrate the equivalence of the Green's function approach and the $\Phi-$derivable formulation. For an example, the formation and dissociation of deuterons in nuclear matter is discussed. We formulate the cluster $\Phi-$derivable approach to quark-hadron matter which allows to take into account the specifics of chiral symmetry restoration and deconfinement in triggering the Mott-dissociation of hadrons. This approach unifies the description of a strongly coupled quark-gluon plasma with that of a medium-modified hadron resonance gas description which are contained as limiting cases. The developed formalism shall replace the common two-phase approach to the description of the deconfinement and chiral phase transition that requires a phase transition construction between separately developed equations of state for hadronic and quark matter phases. Applications to the phenomenology of heavy-ion collisions and astrophysics are outlined.Comment: 35 pages, 3 figures, Special Issue "Compact Stars in the QCD Phase Diagram

Charmonium Suppression and Regeneration from SPS to RHIC

The production of charmonia is investigated for heavy-ion collisions from SPS to RHIC energies. Our approach incorporates two sources of $J/\Psi$ yield: (i) a direct contribution arising from early (hard) parton-parton collisions, subject to subsequent nuclear absorption, quark-gluon plasma and hadronic dissociation, and (ii) statistical production at the hadronization transition by coalescence of $c$ and $\bar{c}$ quarks. Within an expanding thermal fireball framework, the model reproduces $J/\Psi$ centrality dependencies observed at the SPS in Pb-Pb and S-U collisions reasonably well. The study of the $\Psi'/\Psi$ ratio at SPS points at the importance of the hadronic phase for $\Psi'$ interactions, possibly related to effects of chiral symmetry restoration. Predictions are given for the centrality dependence of the $N_{J/\Psi}/N_{c\bar{c}}$ ratio at full RHIC energy. We also calculate the excitation function of this ratio. The latter exhibits a characteristic minimum structure signalling the transition from the standard $J/\Psi$ suppression scenario prevailing at SPS to dominantly thermal regeneration at collider energies.Comment: 17 pages, 15 figure

Composition and thermodynamics of nuclear matter with light clusters

We investigate nuclear matter at finite temperature and density, including the formation of light clusters up to the alpha particle The novel feature of this work is to include the formation of clusters as well as their dissolution due to medium effects in a systematic way using two many-body theories: a microscopic quantum statistical (QS) approach and a generalized relativistic mean field (RMF) model. Nucleons and clusters are modified by medium effects. Both approaches reproduce the limiting cases of nuclear statistical equilibrium (NSE) at low densities and cluster-free nuclear matter at high densities. The treatment of the cluster dissociation is based on the Mott effect due to Pauli blocking, implemented in slightly different ways in the QS and the generalized RMF approaches. We compare the numerical results of these models for cluster abundances and thermodynamics in the region of medium excitation energies with temperatures T <= 20 MeV and baryon number densities from zero to a few times saturation density. The effect of cluster formation on the liquid-gas phase transition and on the density dependence of the symmetry energy is studied. Comparison is made with other theoretical approaches, in particular those, which are commonly used in astrophysical calculations. The results are relevant for heavy-ion collisions and astrophysical applications.Comment: 32 pages, 15 figures, minor corrections, accepted for publication in Physical Review