A novel power state evaluation method for the lithium battery packs based on the improved external measurable parameter coupling model.

The power state evaluation plays a decisive influence on the safety implication of the lithium battery packs, and there is no effective online evaluation method so far due to the imbalance phenomenon among the internal connected battery cells, which cannot be abstained by the advancement of the materials and techniques. A novel power state mathematical evaluation method is proposed in this paper by investigating the improved external parameter coupling treatment, in which the mutual relationship description is conducted by the parameter information feature decomposition together with the Bayesian sequential decision algorithm. The complicated power state evaluation model with the coupling relationship decomposition is constructed by investigating the non-convex optimization treatment under complex working conditions for the lithium battery packs. The evidence combination is realized by introducing the information fusion strategy, according to which the multi criteria decision is realized by using the evidence theory. As can be seen from the experimental results, the voltage difference is within 10 mV in both of the first and the second phases, which increases rapidly in the third phase and reaches a maximum of 120 mV. Meanwhile, its power state evaluation accuracy is 95.00% and has a good output voltage tracking effect in the complex working conditions. The power state evaluation can be realized effectively by the proposed model constructing method, which is suitable for the complex battery cell combination structures and environmental influences, protecting the reliable and hierarchical working state monitoring and management of the lithium battery packs. It provides safety protection and energy management basis for the reliable power supply in the cleaner production of the power lithium battery packs

Optimized energy management strategies and sizing of hybrid storage systems for transport applications

205 p. El contenido del capítulo 4, sección 4.3 está sujeto a confidencialidad.Esta tesis doctoral aborda la temática acerca del óptimo dimensionamiento y operación de sistemashíbridos de almacenamiento de energía (HESS), combinando baterías y supercapacitores, con el objetivode ser integrados en vehículos para movilidad pública en entornos urbanos. Por una parte, se propone unainnovadora estrategia energética, basada en lógica difusa, para gestionar la división de la demanda depotencia entre las fuentes de energía disponibles a bordo del vehículo. La estrategia adaptativa que sepropone evalúa la información energética actual y futura (estimada) para adaptar, de una formaoptimizada y eficiente, la operación del sistema con el objetivo de mejorar el aprovechamiento de laenergía almacenada en los recursos a bordo del vehículo.Por otro lado, se ha propuesto una metodología para la co-optimización de la estrategia de gestión ydimensionamiento del HESS. Esta metodología de optimización evalúa tanto técnica comoeconómicamente las posibles soluciones mediante un problema multi-objetivo basado en algoritmosgenéticos. Para determinar el costo de reemplazo del HESS han sido aplicados modelo de envejecimientoy estimación de vida y se ha considerado la vida útil del vehículo.Con el objetivo de validar la propuesta de esta tesis doctoral, dos casos de estudio relevantes en latransportación pública han sido seleccionados: Tranvía Eléctrico Híbrido y Autobús Eléctrico Híbrido

Multiphysics simulation optimization framework for lithium-ion battery pack design for electric vehicle applications

Large-scale commercialization of electric vehicles (EVs) seeks to develop battery systems with higher energy efficiency and improved thermal performance. Integrating simulation-based design optimization in battery development process expands the possibilities for novel design exploration. This study presents a dual-stage multiphysics simulation optimization methodology for comprehensive concept design of Lithium-ion (Li-ion) battery packs for EV applications. At the first stage, multi-objective optimization of electrochemical thermally coupled cells is performed using genetic algorithm considering the specific energy and the maximum temperature of the cells as design objectives. At the second stage, the energy efficiency and the thermal performances of each optimally designed cell are evaluated under pack operation to account for cell-to-pack interactions under realistic working scenarios. When operating at 1.5 C discharge current, the battery pack comprising optimally designed cells for which the specific energy and the maximum temperature are equally weighted delivers the highest specific energy with enhanced thermal performance. The most favorable pack design shows 8% reduction in maximum pack temperature and 16.1% reduction in module-to-module temperature variations compared to commercially available pack. The methodology for design optimization presented in this work is generic, providing valuable knowledge for future cell and pack designs that employ different chemistries and configurations

The effect of cell-to-cell variations and thermal gradients on the performance and degradation of lithium-ion battery packs

The performance of lithium-ion battery packs are often extrapolated from single cell performance however uneven currents in parallel strings due to cell-to-cell variations, thermal gradients and/or cell interconnects can reduce the overall performance of a large scale lithium-ion battery pack. In this work, we investigate the performance implications caused by these factors by simulating six parallel connected batteries based on a thermally coupled single particle model with the solid electrolyte interphase growth degradation mechanism modelled. Experimentally validated simulations show that cells closest to the load points of a pack experience higher currents than cells further away due to uneven overpotentials caused by the interconnects. When a cell with a four times greater internal impedance was placed in the location with the higher currents this actually helped to equalise the cell-to-cell current distribution, however if this was placed at a location furthest from the load point this would cause a ~6% reduction in accessible energy at 1.5 C. The influence of thermal gradients can further affect this current heterogeneity leading to accelerated aging. Simulations show that in all cases, cells degrade at different rates in a pack due to the uneven currents, with this being amplified by thermal gradients. In the presented work a 5.2% increase in degradation rate, from -7.71 mWh/cycle (isothermal) to - 8.11 mWh/cycle (non-isothermal) can be observed. Therefore, the insights from this paper highlight the highly coupled nature of battery pack performance and can inform designs for higher performance and longer lasting battery packs

Unballanced performance of parallel connected large format lithium ion batteries for electric vehicle application

The integration of cells that exhibit differing electrical characteristics, such as variations in energy capacity and internal resistance can degrade the overall performance of the energy storage system (ESS) when those cells are aggregated into single battery pack. When cells are connected electrically in parallel, such variations can lead to significant individual differences in battery load current, state of charge (SOC) and heat generation. Further, if consideration is given to small variations in cell interconnection resistance, the detrimental effect on load imbalance is amplified. Given that cell resistance is known to be a function of both SOC and temperature, the impact of the imbalance is compounded as the performance of cells further diverge under load. During extended periods of excitation, variations in cell depth of discharge (DOD) and the occurrence of temperature gradients across the parallel connection will accelerate cell ageing and, if unmanaged, may present safety concerns such as the onset of thermal runaway. In this paper the impact of varied SOC and temperature on the overall performance of the ESS with parallel connected cells has been investigated. The results highlight that 8% variation in the initial SOC can result in a current difference of 62% among the cells, while a temperature variation of 8℃ results in a current deviation of 14%. Moreover, it was found that the interconnection resistance can significantly increase the inhomogeneity

A novel endurance prediction method of series connected lithium-ion batteries based on the voltage change rate and iterative calculation.

High-power lithium-ion battery packs are widely used in large and medium-sized unmanned aerial vehicles and other fields, but there is a safety hazard problem with the application that needs to be solved. The generation mechanism and prevention measurement research is carried out on the battery management system for the unmanned aerial vehicles and the lithium-ion battery state monitoring. According to the group equivalent modeling demand of the battery packs, a new idea of compound equivalent circuit modeling is proposed and the model constructed to realize the accurate description of the working characteristics. In order to realize the high-precision state prediction, the improved unscented Kalman feedback correction mechanism is introduced, in which the simplified particle transforming is introduced and the voltage change rate is calculated to construct a new endurance prediction model. Considering the influence of the consistency difference between battery cells, a novel equilibrium state evaluation idea is applied, the calculation results of which are embedded in the equivalent modeling and iterative calculation to improve the prediction accuracy. The model parameters are identified by the Hybrid Pulse Power Characteristic test, in which the conclusion is that the mean value of the ohm internal resistance is 20.68mΩ. The average internal resistance is 1.36mΩ, and the mean capacitance value is 47747.9F. The state of charge prediction error is less than 2%, which provides a feasible way for the equivalent modeling, battery management system design and practical application of pack working lithium-ion batteries