Development and characterization of sensors fabricated from polymer based magnetoelectric nanocomposites

Tese de Doutoramento em Engenharia Electrónica e de ComputadoresSensors are increasingly used in many applications areas, integrated in structures, industrial machinery, or in the environment, contributing to improve the society level of well-being. It is expected that sensorization will play on of the most relevant roles in the fourth industrial revolution, and allow, together with mechanization and informatization, a full automation. Particularly, magnetic sensors allow measurements, without physical contact, of parameters such as direction, presence, rotation, angle, or current, in addition to magnetic field. In this way, for most applications, such sensors offer a safe, noninvasive and non-destructive measurement, as well as provide a reliable and almost maintenance-free technology. Industry demands for smaller, cheaper and low-powered magnetic sensors, motivating the exploration of new materials and different technologies, such as polymerbased magnetoelectric (ME) composites. These composites are flexible, versatile, lightweight, low cost, easy to model in complicated shapes, and typically involve a lowtemperature fabrication process, being in this way, a solution for innovative magnetic sensor device applications. Therefore, the main objective of this thesis is the development of polymer-based ME sensors to be incorporated into technological devices. Thus, the ME effect is increasingly being considered an attractive alternative for magnetic field and current sensing, being able to sense static and dynamic magnetic fields. In order to obtain a wide-range ME response, a nanocomposite of Tb0.3Dy0.7Fe1.92 (Terfenol-D)/CoFe2O4/poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) was produced and their morphological, piezoelectric, magnetic and magnetoelectric properties investigated. The obtained composites reveals a high piezoelectric response (≈-18 pC∙N- 1) that is independent of the weight ratio between the fillers. In turn, the magnetic properties of the composites are influenced by the composite composition. It was found that the magnetization saturation values decrease with increasing CoFe2O4 content (from 18.5 to 13.3 emu∙g-1) while the magnetization and coercive field values increase (from 3.7 to 5.5 emu∙g-1 and from 355.7 to 1225.2 Oe, respectively) with increasing CoFe2O4 content. Additionally, the films show a wide-range dual-peak ME response at room temperature with the ME coefficient increasing with increasing weight content of Terfenol-D, from 18.6 mV∙cm-1∙Oe-1 to 42.3 mV∙cm-1∙Oe-1. The anisotropic ME effect on a Fe61.6Co16.4Si10.8B11.2 (FCSB)/poly(vinylidene fluoride) (PVDF)/FCSB laminate composite has been used for the development of a magnetic field sensor able to detect both magnitude and direction of ac and dc magnetic fields. The accuracy (99% for both ac and dc sensors), linearity (92% for the dc sensor and 99% for the ac sensor), sensitivity (15 and 1400 mV∙Oe-1 for the dc and ac fields, respectively), and reproducibility (99% for both sensors) indicate the suitability of the sensor for applications. A dc magnetic field sensor based on a PVDF/Metglas composite and the corresponding readout electronic circuits for processing the output ME voltage were developed. The ME sensing composite presents an electromechanical resonance frequency close to 25.4 kHz, a linear response (r2=0.997) in the 0–2 Oe dc magnetic field range, and a maximum output voltage of 112 mV (ME voltage coefficient α33 of ≈30 V∙cm-1∙Oe-1). By incorporating a charge amplifier, an ac–rms converter and a microcontroller with an on chip analog-to-digital converter (ADC), the ME voltage response is not distorted, the linearity is maintained, and the ME output voltage increases to 3.3 V (α33effective=1000 V∙cm-1∙Oe-1). The sensing device, including the readout electronics, has a maximum drift of 0.12 Oe with an average total drift of 0.04 Oe, a sensitivity of 1.5 V∙Oe-1 (15 kV∙T-1), and a 70 nT resolution. Such properties allied to the accurate measurement of the dc magnetic field in the 0–2 Oe range makes this polymerbased device very attractive for applications, such as Earth magnetic field sensing, digital compasses, navigation, and magnetic field anomaly detectors. A dc current sensor device based on a ME PVDF/Metglas composite, a solenoid, and the corresponding electronic instrumentation were developed. The ME sample exhibits a maximum α33 of 34.48V∙cm-1∙Oe-1, a linear response (r2=0.998) and a sensitivity of 6.7 mV∙A-1. With the incorporation of a charge amplifier, a precision ac/dc converter and a microcontroller, the linearity is maintained (r2=0.997), the ME output voltage increases to a maximum of 2320 mV and the sensitivity is increased to 476.5 mV∙A-1. Such features indicate that the fabricated ME sensing device is suitable to be used in non-contact electric current measurement, motor operational status checking, and condition monitoring of rechargeable batteries, among others. In this way, polymer-based ME composites proved to be suitable for magnetic field and current sensor applications.Os sensores estão a ser cada vez mais utilizados em diversas áreas, integrados em estruturas, máquinas industriais ou projetos ambientais, contribuindo para melhorar o nível de bem-estar e eficiência da nossa sociedade. Espera-se que a “sensorização” contribua decisivamente para a quarta revolução industrial, e que permita, em conjunto com a mecanização e a informatização, uma completa automação. Em particular, os sensores magnéticos permitem medir parâmetros como a direção, presença, rotação, ângulo ou corrente, para além do campo magnético, tudo isto sem qualquer contacto físico. Assim, para a maioria das aplicações, estes sensores oferecem uma medição segura, não invasiva e não destrutiva, para além de garantirem uma tecnologia confiável e de escassa manutenção. A indústria procura e exige sensores magnéticos mais pequenos, mais baratos e de baixo consumo, daí a motivação para explorar novos materiais e diferentes tecnologias, tais como os compósitos magnetoelétricos (ME) baseados em polímeros. Estes compósitos são flexíveis, versáteis, leves, de baixo custo, fáceis de se modelar em formas complexas e tipicamente envolvem um processo de fabricação a baixa temperatura, constituindo uma solução fiável e de qualidade para os sensores magnéticos. É da constatação deste potencial que surge este estudo e o objetivo desta tese: o desenvolvimento de sensores ME de base polimérica. O efeito ME é cada vez mais considerado como uma alternativa credível para a medição de campo magnético e da intensidade da corrente elétrica, podendo detetar campos magnéticos estáticos e dinâmicos. De modo a obter uma gama mais alargada de resposta ME, produziram-se nanocompósitos de Tb0.3Dy0.7Fe1.92 (Terfenol-D)/CoFe2O4/poli(fluoreto de vinilideno trifluor-etileno) (P(VDF-TrFE) e as suas propriedades morfológicas, piezoelétricas, magnéticas e magnetoelétricas foram investigadas. Os compósitos obtidos revelam uma elevada resposta piezoelétrica (≈-18 pC∙N-1) que é independente da percentagem de cada material magnetoestrictivo. Por sua vez, as propriedades magnéticas são influenciadas pela composição dos compósitos. Verificou-se que a magnetização de saturação diminuí com o aumento da percentagem de CoFe2O4 (de 18.5 para 13.3 emu∙g-1) enquanto que a magnetização e o campo coercivo aumentam (de 3.7 para 5.5 emu∙g-1 e de 355.7 para 1225.2 Oe, respetivamente) com o aumento da percentagem em massa de CoFe2O4. O efeito ME anisotrópico num compósito Fe61.6Co16.4Si10.8B11.2 (FCSB)/ poli(fluoreto de vinilideno) (PVDF)/FCSB laminado foi utilizado para desenvolver um sensor de campo magnético capaz de detetar tanto a magnitude como a direção de campos magnéticos ac e dc. A exatidão (99% para ambos os sensores ac e dc), linearidade (92% para o sensor dc e 99% para o ac), sensibilidade (15 e 1400 mV∙Oe-1 para o sensor dc e ac, respetivamente) e reprodutibilidade (99% para ambos os sensores) indicam a aptidão destes sensores para aplicações avançadas. Desenvolveu-se ainda um sensor de campo magnético dc baseado num compósito ME de PVDF/Metglas, bem como a correspondente eletrónica de leitura para processar a tensão de saída ME. O compósito ME apresenta uma ressonância eletromecânica de aproximadamente 25.4 kHz, uma resposta linear (r2=0.997) para uma gama de campos magnéticos dc entre 0–2 Oe e uma tensão de saída máxima de 112 mV (coeficiente ME α33≈30 V∙cm-1∙Oe-1). Ao incorporar um amplificador de carga, um conversor ac–rms e um microcontrolador com um conversor analógico-digital (ADC), a tensão ME não é distorcida, a linearidade manteve-se e a tensão ME aumentou para 3.3 V (α33efectivo=1000 V∙cm-1∙Oe-1). O sensor, incluindo a eletrónica de leitura, obteve um desvio máximo de 0.12 Oe com um desvio total médio de 0.04 Oe, uma sensibilidade de 1.5 V∙Oe-1 (15 kV∙T-1) e 70 nT de resolução. Tais propriedades aliadas à medida exata do campo magnético dc entre 0–2 Oe tornam este dispositivo indicado para aplicações como sensores de campo magnético terrestre, compassos digitais, navegação e detetores de anomalia no campo magnético. Foi ainda possível desenvolver e otimizar um sensor de corrente baseado num compósito ME de PVDF/Metglas, num solenoide e na correspondente eletrónica de instrumentação. A amostra ME exibe um α33 máximo de 34.48V∙cm-1∙Oe-1, uma resposta linear (r2=0.998) e uma sensibilidade de 6.7 mV∙A-1. Com a incorporação de um amplificador de carga, um conversor ac/dc de precisão e um microcontrolador, a linearidade manteve-se, a tensão ME aumentou para um máximo de 2320 mV e a sensibilidade subiu para 476.5 mV∙A-1. Estas propriedades tornam este sensor ME apropriado para a medição de corrente elétrica sem contato, para a verificação do estado de funcionamento de motores e para monitorização da condição de baterias recarregáveis, entre outros. Concluindo-se deste modo que os compósitos de ME com base em polímeros provaram ser adequados para aplicações na medição de campos magnéticos e intensidade de corrente elétrica

Design study of a magnetoelectric-electromagnetic vibration energy converter for energy harvesting

The aim of this paper is to design a combination of a magnetoelectric-electromagnetic (ME-EM) vibration converter in order to reach an improved energy outcome. In this paper, the influence of magnets polarization and magnetoelectric transducer and coil direction are investigated. For this purpose, a finite element model is developed using one coil, one ME transducer in a magnetic circuit. Simulation results show that a better magnetic field distribution and variation is reached, if the magnetic circuit magnets are placed in attraction. Radial polarization shows decisive advantages in comparison with axial polarization. The placement of coil parallel to the magnetic circuit direction and the magnetization of the ME transducer along its width is the optimal direction relative to the magnetic circuit

Piezoelectric and Magnetoelectric Thick Films for Fabricating Power Sources in Wireless Sensor Nodes

In this manuscript, we review the progress made in the synthesis of thick film-based piezoelectric and magnetoelectric structures for harvesting energy from mechanical vibrations and magnetic field. Piezoelectric compositions in the system Pb(Zr,Ti)O3–Pb(Zn1/3Nb2/3)O3 (PZNT) have shown promise for providing enhanced efficiency due to higher energy density and thus form the base of transducers designed for capturing the mechanical energy. Laminate structures of PZNT with magnetostrictive ferrite materials provide large magnitudes of magnetoelectric coupling and are being targeted to capture the stray magnetic field energy. We analyze the models used to predict the performance of the energy harvesters and present a full system description

Design and Modelling of a Novel Hybrid Vibration Converter based on Electromagnetic and Magnetoelectric Principles

Supplying wireless sensors from ambient energy is nowadays highly demanded for a higher flexibility of use and low system maintenance costs. Vibration sources are thereby especially attractive due to their availability and the relatively high energy density they can provide. The aim of this work is to realize a hybrid energy converter for vibration sources having low amplitude and low frequency. The idea is to combine two diverse harvesters to realize a higher energy density and at the same time to improve the converter reliability. We focus on the design, modeling, and test of the hybrid vibration converter. For an appropriate converter design, the vibration profiles of several ambient vibration sources are characterized. The results show that the typical frequency and acceleration ranges are between 5 Hz to 60 Hz and 0.1 g to 1.5 g respectively. The proposed converter is based on the magnetoelectric (ME) and electromagnetic (EM) principles. These two principles can be easily combined within almost the same volume, because they generate energy form the same varying magnetic field coupled to the mechanical vibration of the source. Thereby, the energy density is improved as the ME converter is incorporated within the relatively large coil housing of the electromagnetic converter. The proposed converter is based on the use of a magnetic spring instead of the typically used mechanical springs, which applies the repulsive force to the seismic mass of the converter. The applied vibration is transmitted to the converter based on the magnetic spring principle instead of the conventional mechanical springs. Due to the nonlinearity of the magnetic spring, the converter is able to operate for a frequency bandwidth instead of resonant frequency which is the case while using a mechanical spring. Hence, this leads to realize a high converter efficiency even under random vibrations characterized by frequency bandwidth. As well, using magnetic spring principle enables to adjust the resonant frequency of the converter relative to the applied vibration source easily by just adjusting the moving magnet size. For the converter design, a parametric study is conducted using finite element analysis. Two main criteria are thereby taken into account, which are the compactness and the efficiency of the converter. Parameters affecting these two criteria are classified in mechanical, electromagnetic and magnetoelectric parameters. Results show that the combination of the EM and ME principles leads to an improvement of the energy output compared to a single EM or ME converter. The novel hybrid converter is realized and tested under harmonic and real vibration profiles. It comprises two main parts: A fixed part, where the coils and the ME transducer are fixed in order to ensure a good reliability of the converter by avoiding wire movements. A moving part, where the moving magnet of the magnetic spring and the magnetic circuit are placed. The presented converter is reliable and compact, which is able to harvest energy with a maximum output power density of 0.11 mW/cm³ within a frequency bandwidth of 12 Hz for a resonance frequency of 24 Hz under an applied harmonic vibration with an amplitude of 1 mm.Die Versorgung von drahtlosen Sensoren aus der Umgebungsenergie ermöglicht heutzutage eine hohe Einsatzflexibilität und die Senkung des Systemwartungsaufwands. Schwingungsquellen sind aufgrund ihrer Verfügbarkeit und der damit erreichbaren Energiedichte besonders attraktiv. Ziel dieser Arbeit ist es, einen hybriden Energiewandler für Vibrationsquellen mit geringer Amplitude und niedriger Frequenz zu realisieren. Der Ansatz dabei ist, zwei verschiedene Wandler zu kombinieren, um eine höhere Energiedichte zu erreichen und die Zuverlässigkeit zu verbessern. Der Entwurf konzentriert sich auf die Modellierung und den Test des hybriden Vibrationswandlers. Für einen geeigneten Wandlerentwurf werden die Schwingungsprofileigenschaften mehrerer Umgebungsschwingungsquellen untersucht. Die Ergebnisse zeigen, dass die typische Frequenz zwischen 5 Hz und 60 Hz und der Beschleunigungsbereich zwischen 0,1 g und 1,5 g liegen. Der vorgeschlagene Wandler kombiniert das magnetoelektrischen (ME) Prinzip mit dem elektromagnetischen (EM) Prinzip. Diese beiden Prinzipien können innerhalb des fast gleichen Volumens leicht integriert werden, da sie Energie aus der Variation des gleichen Magnetfeldes, das mit der mechanischen Schwingung gekoppelt ist, erzeugen können. Dadurch wird die Energiedichte verbessert, da der ME-Wandler in das relativ große Spulengehäuse des elektromagnetischen Wandlers eingesetzt werden kann. Darüber hinaus basiert der vorgeschlagene Wandler auf der Verwendung von Magnetfedern, um die Repulsivkraft auf die seismische Masse zu realisieren. Aufgrund der Nichtlinearität der Magnetfeder, kann der Wandler in einem breiteren Frequenzbereich betrieben werden, anstatt nur bei der Resonanzfrequenz, wie es bei der Verwendung einer mechanischen Feder der Fall ist. Dies führt dazu, dass der Wandler auch bei zufälligen breitbandigen Schwingungsquellen effizient betrieben werden kann. Darüber hinaus ermöglicht die Verwendung des Magnetfederprinzips eine einfache Einstellung der Resonanzfrequenz des Wandlers in Bezug auf die Schwingungsquelle, durch Einstellen der Größe des beweglichen Magneten. Für den Wandlerentwurf wird eine Parameterstudie mit Hilfe der Finite-Elemente-Analyse durchgeführt. Zwei Hauptkriterien werden dabei berücksichtigt: Die Kompaktheit und die Energieeffizienz des Wandlers. Parameter die diese beiden Kriterien beeinflussen, können in mechanische, elektromagnetische und magnetoelektrische unterteilt werden. Die Ergebnisse haben gezeigt, dass die Kombination der EM- und ME-Prinzipien zu einer Verbesserung der Energieausbeute im Vergleich zu einem einzelnen EM- oder ME-Wandler geführt hat. Der neuartige Hybrid-Wandler wurde realisiert und unter harmonischen und realen Schwingungsprofilen getestet. Der Wandler besteht aus zwei Hauptteilen: Ein festes Teil, an dem die Spulen und der ME-Wandler befestigt sind, um eine hohe Zuverlässigkeit zu gewährleisten indem auf einen beweglichen Draht verzichtet wird, und ein bewegliches Teil, das sich aus einem beweglichen Magneten zusammensetzt. Der vorgestellte Wandler ist zuverlässig, kompakt und in der Lage, Energie mit einer maximalen Ausgangsleistungsdichte von 0,11 mW/cm 3 und einer Bandbreite von 12 Hz bei einer Resonanzfrequenz von 24 Hz unter einer angelegten harmonischen Schwingung mit einer Amplitude von 1 mm zu gewinnen

Metallic glass/PVDF magnetoelectric laminates for resonant sensors and actuators: a review

Among magnetoelectric (ME) heterostructures, ME laminates of the type Metglas-like / PVDF (magnetostrictive+piezoelectric constituents) have shown the highest induced ME voltages, usually detected at the magnetoelastic resonance of the magnetostrictive constituent. This ME coupling happens because of the high cross-correlation coupling between magnetostrictive and piezoelectric material, and is usually associated with a promising application scenario for sensors or actuators. In this work we detail the basis of the operation of such devices, as well as some arising questions (as size effects) concerning their best performance. Also, some examples of their use as very sensitive magnetic fields sensors or innovative energy harvesting devices will be reviewed. At the end, the challenges, future perspectives and technical difficulties that will determine the success of ME composites for sensor applications are discussed.J.G., A.L. and J.M.B. would like to thank the financial support from the Basque Government under ACTIMAT and MICRO4FAB projects (Etortek program) and Research Groups IT711-13 project. A. Lasheras wants to thank the Basque Government for financial support under FPI Grant. Technical and human support provided by SGIker (UPV/EHU, MICINN, GV/EJ, ESF) is gratefully acknowledged. P.M., N.P. and S. L.-M. thank the Portuguese Fundação para a Ciência e Tecnologia (FCT) for financial Sensors 2017, 13 19 support under Strategic Funding UID/FIS/04650/2013 and project PTDC/EEI-SII/5582/2014, including FEDER funds, UE. P. Martins acknowledges also support from FCT (SFRH/BPD/96227/2013 grant). Financial support from the Spanish Ministry of Economy and Competitiveness (MINECO) through the project MAT2016-76039-C4-3-R (AEI/FEDER, UE) (including the FEDER financial support) is also acknowledgedinfo:eu-repo/semantics/publishedVersio

Modeling of magnetoelectric composite structures

Novel models to predict magnetoelectric (ME) properties of composites made of piezoelectric (PE) and piezomagnetic (PM) phases is proposed. Two different composite arrangements are used: laminate and particulate. ME properties for laminate arrangement are obtained by applying the multiphysics equations for all four possible laminate configurations (TT, LT, TL, and LL), with appropriate boundary conditions. Closed form, explicit formulas are derived for the calculation of the ME charge and voltage coefficients as a function of material properties of both phases and PM volume fraction. A new coefficient, the ME coupling factor, is proposed in order to assess the conversion of magnetic work into electric work. The predicted ME voltage coefficient is in agreement with previous work and experimental data. A new approach is proposed to take into account the conductivity of the PM phase, resulting in calculated ME charge coefficients within 30\% of experimental data. The voltage, current, and electric power generated by unit of magnetic field applied to the composite define the intrinsic voltage, current, and power conversion factors. Since the PM phase of the composite has a higher magnetic permeability than the surrounding medium, a far filed magnetic field is not fully utilized due to demagnetization. Thus, novel explicit equations are developed here to calculate the extrinsic voltage, current, and power conversion factors accounting for demagnetization. The proposed formulation is applied to various materials and geometries to illustrate the process of material and device-geometry selection leading to an optimum design. The magnetoelectric (ME) properties of particulate composites are calculated using Eshelby theory and two homogenization techniques: dilute approximation and Mori-Tanaka mean field theory. A method that allows the calculation of all ME properties under any boundary conditions is proposed. These boundary conditions are dictated by the experimental configuration, e.g. films on a substrate, free-standing composites, etc. Predictions are compared with calculations reported by Harshe et al. and Nan et al., and good correlation is obtained with those, but to achieve good correlation with experimental data, the conductivity of the piezomagnetic (PM) phase must be taken into account, and a method is proposed to that effect. Percolated composites do not have any piezoelectric (PE) or ME properties because the charge leaks through the conductive PM phase. The experimental parameters that influence the percolation threshold are discussed and the best particulate composite design is proposed. Unlike previous models that did not account for conductivity, correlation between the proposed model and experimental data is much better

A Magneto-Mechanical Piezoelectric Energy Harvester Designed to Scavenge AC Magnetic Field from Thermal Power Plant with Power-Line Cables

Piezoelectric energy harvesters have attracted much attention because they are crucial in portable industrial applications. Here, we report on a high-power device based on a magneto-mechanical piezoelectric energy harvester to scavenge the AC magnetic field from a power-line cable for industrial applications. The electrical output performance of the harvester (×4 layers) reached an output voltage of 60.8 Vmax, an output power of 215 mWmax (98 mWrms), and a power density of 94.5 mWmax/cm3 (43.5 mWrms/cm3) at an impedance matching of 5 kΩ under a magnetic field of 80 μT. The multilayer energy harvester enables high-output performance, presenting an obvious advantage given this improved level of output power. Finite element simulations were also performed to support the experimental observations. The generator was successfully used to power a wireless sensor network (WSN) for use on an IoT device composed of a temperature sensor in a thermal power station. The result shows that the magneto-mechanical piezoelectric energy harvester (MPEH) demonstrated is capable of meeting the requirements of self-powered monitoring systems under a small magnetic field, and is quite promising for use in actual industrial applications

Magnetoelectric metallic glass/polymer laminated composites: from fabrication to applications

131 p

Optimization of magnetoelectric composites based on electroactive polymers for energy harvesting and sensor application

Tese de Doutoramento em Engenharia de Materiais.Low power portable electronic devices and wireless sensors networks, for application in implantable biomedical sensors and monitoring for agricultural, environmental, building, military and industrial processes are typically powered by batteries, which have a finite supply of energy. The combination of an energy harvesting system with a rechargeable battery is the best way to self-power devices for their entirely lifetime. These harvesters collect energy (in the order of μW to mW) from ambient sources (thermal, mechanical or electromagnetic, among others). Among them, energy harvesting from electromagnetic signals is one of the most challenging and interesting harvesting systems and has been poorly addressed. Magnetoelectric (ME) composite materials are an innovative tool that can convert such electromagnetic singnals into an electrical voltage and can be also be used as novel sensors and actuators. The main objective of this work is to optimize ME laminated composites for sensor, actuators and energy harvesting devices. It is also an objective to find new applications for this ME effect. From the different composite structures, laminated ME composites, comprising bonded piezoelectric and magnetostrictive layers, are the ones with the highest ME response, thus being the most studied materials for their implementation into technological applications. With high ME coupling, easy fabrication, large scale production ability, low-temperature processing into a variety of forms and, in some cases, biocompatibility, polymer based ME materials emerged as an original approach. In this work Vitrovac and Metglas were used as magnetostrictive materials due to their high magnetostriction at low fields, and .poly(vinylidene fluoride) was used as the polymeric piezoelectric material, due to his high piezoelectric constant compared to other polymers. Thus, the effect of the bonding layer type and piezoelectric layer thickness is reported. Vitrovac/poly(vinylidene fluoride) magnetoelectric laminate were produced and experimental results show that the ME response increases with increasing piezoelectric thickness, the highest ME response of 53 V·cm−1·Oe−1 being obtained for an 110 μm thick piezoelectric bonded with M- Bond epoxy. The behavior of the ME laminates with increasing temperatures up to 90 °C shows a decrease larger than 80% in the ME response. A finite element method (FEM) was used to evaluate the experimental results. The obtained results show the critical role of the bonding layer and piezoelectric layer thickness in the ME performance of laminate composites From the ME measurements it was concluded that tri-layered composites structures (Vitrovac/poly(vinylidene fluoride)/Vitrovac ), show a high ME response (75 V cm-1 Oe-1) and that the ME voltage coefficient decreases with increasing longitudinal size aspect ratio and increases with the lowest transversal aspect ratio between piezoelectric and magnetostrictive layers. Relevant parameters such as sensibility, accuracy, linearity, hysteresis and resolution have been vaguely or never discussed in polymer-based ME composites. This work reports on those parameters on a Metglas/poly(vinylidene fluoride)/Metglas magnetoelectric laminate, the polymer-based composite with the highest ME response. The sensibility and resolution determined for the DC (30 mV.Oe-1 and 8 μOe) and AC magnetic field sensor (992 mV.Oe-1 and 0.3 μOe) are favorably comparable with the most recent and sensitive polymer-based ME sensors. The design and performance of five interface circuits, a full-wave bridge rectifier, two Cockcroft-Walton voltage multipliers (with 1 and 2 stages) and two Dickson voltage multipliers (with 2 and 3 stages), for the energy harvesting from a Metglas/PVDF/Metglas ME composite were discussed. Maximum power and power density values of 12 μW and 0.9 mW.cm-3 were obtained with the two stages Dickson voltage multiplier. Finally, it is successfully demonstrated that nanoparticle’s magnetostriction can be accurately determined based on the magnetoelectric effect measured on polymer composite materials. This represents a novel, simple and versatile method for the determination of particle’s magnetostriction at the nano scale and in their dispersed state. Thus, the developed polymer based magnetoelectric laminate composites showed suitable characteristics for applications in sensors and energy harvesting devices.Dispositivos eletrônicos portáteis de baixa potência e sensores de redes sem fio para implementação em sensores biomédicos, monitorização ambiental, gestão de agricultura, construção, aplicações militares e de processos industriais, normalmente são alimentados por baterias, que têm uma fonte finita de energia. A combinação de um sistema de “energy harvesting” com uma bateria recarregável é a melhor forma de auto-alimentar um dispositivo durante o seu tempo de vida útil. Estes dispositivos (“harvesters”) armazenam a energia proveniente de fontes presentes no ambiente (como térmica, mecânica e eletromagnética, entre outras). A energia produzida é na ordem de μW a mW. Entre estes sistemas, energy harvesting a partir de sinais eletromagnéticos é um dos desafios mais interessantes e tem sido pouco investigado. Materiais compósitos magnetelétricos (ME) são uma ferramenta inovadora que pode converter sinais eletromagnéticos em uma voltagem elétrica e também podem ser usados como novos sensores e atuadores. O principal objetivo deste trabalho é otimizar compósitos laminados ME para sensores, atuadores e dispositivos de captação de energia. É também um objetivo de encontrar novas aplicações baseadas nestes materiais. De todas as diferentes estruturas compósitas, os compósitos laminados ME compostos pela colagem de camadas piezoelétricas e magnetostrictivas, são aqueles que apresentam a maior resposta ME, sendo desta forma os materiais mais estudados para a sua implementação em aplicações tecnológicas. Com elevado acoplamento ME, fabrico fácil, capacidade de produção em grande escala, processamento a baixa temperatura numa grande variedade de formas e, em alguns casos, biocompatibilidade, materiais ME de base polimérica emergem como uma abordagem original. Neste trabalho, Vitrovac e Metglas foram usados como materiais magnetostrictivos devido à sua elevada magnetostrição a baixos campos magnéticos. O poli (fluoreto de vinilideno) - PVDF foi usado como polímero piezoelétrico devido à sua elevada constante piezoelétrica entre os materiais poliméricos. De forma a resposta ME dos compósitos, o efeito do tipo da camada de adesão e a espessura da camada piezoelétrica foi avaliado. Foi produzido um laminado magnetoelétrico (Vitrovac/PVDF) e os resultados experimentais mostram que a resposta ME aumenta com o aumento da espessura da camada piezoelétrica, a maior resposta ME foi de 53 V·cm−1·Oe−1 para o laminado com uma espessura piezoelétrica de 110 μm colado com a resina epoxy M-Bond. Com o aumento da temperatura até 90ºC, os laminados ME mostram uma perda de resposta ME até 80%. O método dos elementos finitos (MEF) foi usado para avaliar os resultados experimentais. Os resultados obtidos mostram o papel crítico da camada de ligação e a espessura da camada piezoelétrica no desempenho de compósitos laminados ME. Através das medidas ME foi concluído que os compósitos de três camadas (Vitrovac/PVDF/Vitrovac), mostram a maior resposta ME (75 V cm-1 Oe-1), e o coeficiente ME diminui com o aumento do aspect ratio longitudinal e aumenta com a diminuição do aspect ratio transversal entre a camada piezoelétrica e magnetostritiva. Parâmetros relevantes, como sensibilidade, precisão, linearidade, histerese e resolução, tem sido pouco estudada em compósitos poliémicos ME,. Este trabalho investiga esses parâmetros num laminado ME (Metglas/PVDF/Metglas), o compósito polímero com a resposta.ME mais alta. A sensibilidade e resolução determinada para sensores de campo magnético DC (30 mV.Oe-1 and 8 μOe) e AC (992 mV.Oe-1 and 0.3 μOe) são favoravelmente comparadas com os mais recentes e sensíveis sensores baseados em compósitos ME de base polimérica. O design e a performance de cinco circuitos: retificador full-wave bridge, dois multiplicadores Cockcroft-Walton (com 1 e 2 andares) e dois multiplicadores Dickson (com 2 e 3 andares), para energy harvesting através de um laminado ME (Metglas/PVDF/Metglas) foi estudado e discutido. A máxima potencia e densidade de potência obtida foram 12μW e 0.9 mW.cm-3 usando um multiplicador Dickson de dois andares. Por fim, é demonstrado com sucesso que a magnetostrição de nanopartículas pode ser determinada com precisão com base no efeito magnetoelétrico medido em materiais compósitos poliméricos. Isto representa um novo, versátil e simples método para a determinação de magnetostrição de partículas no seu estado disperso à escala nanométrica. Assim, os compósitos laminados ME de base polimérica desenvolvidos, apresentam características adequadas para aplicações em sensores e dispositivos de energy harvesting.Fundação para a Ciência e a Tecnologia (FCT) SFRH/BD/70303/2010

Energy harvesting utilizing reciprocating flow-induced torsional vibration on a T-shaped cantilever beam

This paper proposes a T-shaped cantilever energy harvester powered by flow-induced torsional vibration. To collect and convert the mechanical (kinetic) energy into electric power, a pair of symmetrical acrylic cylindrical bluff bodies were installed onto the bottom surface of the T-shaped cantilever beam, one at each end; There is also one patch of Macro Fiber Composite (MFC) used as an energy collector and converter which was attached to the fixed end of the cantilever beam. This proposed setup of the energy harvester is able to generate sustainable electric power by harvesting natural mechanical power resulted from the torsional vibration of the beam due to fluid's vortex shedding effects. The proposed energy harvester has the novelty in that our approach harvests fluid flow's energy in a reciprocal fashion making full use of renewable energy incurred in areas surrounding the two bluff bodies. Both the theoretical and experimental analyses on the proposed energy harvesting structure were performed and demonstrated in this paper. The case in the test rig we studied on the proposed energy harvester was able to generate sustainable electric power of approximately 1.0 µW when flow speed was measured to be 0.33 m/s flowing through two bluff bodies each of 29.5 mm diameter. This work also looks into and discusses pros and cons of various scenarios in terms of structural geometric variations for system optimization of the proposed energy harvester