A Contribution Towards Intelligent Autonomous Sensors Based on Perovskite Solar Cells and Ta2O5/ZnO Thin Film Transistors

Many broad applications in the field of robotics, brain-machine interfaces, cognitive computing, image and speech processing and wearables require edge devices with very constrained power and hardware requirements that are challenging to realize. This is because these applications require sub-conscious awareness and require to be always “on”, especially when integrated with a sensor node that detects an event in the environment. Present day edge intelligent devices are typically based on hybrid CMOS-memristor arrays that have been so far designed for fast switching, typically in the range of nanoseconds, low energy consumption (typically in nano-Joules), high density and endurance (exceeding 1015 cycles). On the other hand, sensory-processing systems that have the same time constants and dynamics as their input signals, are best placed to learn or extract information from them. To meet this requirement, many applications are implemented using external “delay” in the memristor, in a process which enables each synapse to be modeled as a combination of a temporal delay and a spatial weight parameter. This thesis demonstrates a synaptic thin film transistor capable of inherent logic functions as well as compute-in-memory on similar time scales as biological events. Even beyond a conventional crossbar array architecture, we have relied on new concepts in reservoir computing to demonstrate a delay system reservoir with the highest learning efficiency of 95% reported to date, in comparison to equivalent two terminal memristors, using a single device for the task of image processing. The crux of our findings relied on enhancing our capability to model the unique physics of the device, in the scope of the current thesis, that is not amenable to conventional TCAD simulations. The model provides new insight into the redox characteristics of the gate current and paves way for assessment of device performance in compute-in-memory applications. The diffusion-based mechanism of the device, effectively enables time constants that have potential in applications such as gesture recognition and detection of cardiac arrythmia. The thesis also reports a new orientation of a solution processed perovskite solar cell with an efficiency of 14.9% that is easily integrable into an intelligent sensor node. We examine the influence of the growth orientation on film morphology and solar cell efficiency. Collectively, our work aids the development of more energy-efficient, powerful edge-computing sensor systems for upcoming applications of the IOT

Low Frequency Electric Field Imaging

abstract: Electric field imaging allows for a low cost, compact, non-invasive, non-ionizing alternative to other methods of imaging. It has many promising industrial applications including security, safely imaging power lines at construction sites, finding sources of electromagnetic interference, geo-prospecting, and medical imaging. The work presented in this dissertation concerns low frequency electric field imaging: the physics, hardware, and various methods of achieving it. Electric fields have historically been notoriously difficult to work with due to how intrinsically noisy the data is in electric field sensors. As a first contribution, an in-depth study demonstrates just how prevalent electric field noise is. In field tests, various cables were placed underneath power lines. Despite being shielded, the 60 Hz power line signal readily penetrated several types of cables. The challenges of high noise levels were largely addressed by connecting the output of an electric field sensor to a lock-in amplifier. Using the more accurate means of collecting electric field data, D-dot sensors were arrayed in a compact grid to resolve electric field images as a second contribution. This imager has successfully captured electric field images of live concealed wires and electromagnetic interference. An active method was developed as a third contribution. In this method, distortions created by objects when placed in a known electric field are read. This expands the domain of what can be imaged because the object does not need to be a time-varying electric field source. Images of dielectrics (e.g. bodies of water) and DC wires were captured using this new method. The final contribution uses a collection of one-dimensional electric field images, i.e. projections, to reconstruct a two-dimensional image. This was achieved using algorithms based in computed tomography such as filtered backprojection. An algebraic approach was also used to enforce sparsity regularization with the L1 norm, further improving the quality of some images.Dissertation/ThesisDoctoral Dissertation Electrical Engineering 201

Wearable, low-power CMOS ISFETs and compensation circuits for on-body sweat analysis

Complementary metal-oxide-semiconductor (CMOS) technology has been a key driver behind the trend of reduced power consumption and increased integration of electronics in consumer devices and sensors. In the late 1990s, the integration of ion-sensitive field-effect transistors (ISFETs) into unmodified CMOS helped to create advancements in lab-on-chip technology through highly parallelised and low-cost designs. Using CMOS techniques to reduce power and size in chemical sensing applications has already aided the realisation of portable, battery-powered analysis platforms, however the possibility of integrating these sensors into wearable devices has until recently remained unexplored. This thesis investigates the use of CMOS ISFETs as wearable electrochemical sensors, specifically for on-body sweat analysis. The investigation begins by evaluating the ISFET sensor for wearable applications, identifying the key advantages and challenges that arise in this pursuit. A key requirement for wearable devices is a low power consumption, to enable a suitable operational life and small form factor. From this perspective, ISFETs are investigated for low power operation, to determine the limitations when trying to push down the consumption of individual sensors. Batteryless ISFET operation is explored through the design and implementation of a 0.35 \si{\micro\metre} CMOS ISFET sensing array, operating in weak-inversion and consuming 6 \si{\micro\watt}. Using this application-specific integrated circuit (ASIC), the first ISFET array powered by body heat is demonstrated and the feasibility of using near-field communication (NFC) for wireless powering and data transfer is shown. The thesis also presents circuits and systems for combatting three key non-ideal effects experienced by CMOS ISFETs, namely temperature variation, threshold voltage offset and drift. An improvement in temperature sensitivity by a factor of three compared to an uncompensated design is shown through measured results, while adding less than 70 \si{\nano\watt} to the design. A method of automatically biasing the sensors is presented and an approach to using spatial separation of sensors in arrays in applications with flowing fluids is proposed for distinguishing between signal and sensor drift. A wearable device using the ISFET-based system is designed and tested with both artificial and natural sweat, identifying the remaining challenges that exist with both the sensors themselves and accompanying components such as microfluidics and reference electrode. A new ASIC is designed based on the discoveries of this work and aimed at detecting multiple analytes on a single chip. %Removed In the latter half of the thesis, Finally, the future directions of wearable electrochemical sensors is discussed with a look towards embedded machine learning to aid the interpretation of complex fluid with time-domain sensor arrays. The contributions of this thesis aim to form a foundation for the use of ISFETs in wearable devices to enable non-invasive physiological monitoring.Open Acces

Ultra-thin and flexible CMOS technology: ISFET-based microsystem for biomedical applications

A new paradigm of silicon technology is the ultra-thin chip (UTC) technology and the emerging applications. Very thin integrated circuits (ICs) with through-silicon vias (TSVs) will allow the stacking and interconnection of multiple dies in a compact format allowing a migration towards three-dimensional ICs (3D-ICs). Also, extremely thin and therefore mechanically bendable silicon chips in conjunction with the emerging thin-film and organic semiconductor technologies will enhance the performance and functionality of large-area flexible electronic systems. However, UTC technology requires special attention related to the circuit design, fabrication, dicing and handling of ultra-thin chips as they have different physical properties compared to their bulky counterparts. Also, transistors and other active devices on UTCs experiencing variable bending stresses will suffer from the piezoresistive effect of silicon substrate which results in a shift of their operating point and therefore, an additional aspect should be considered during circuit design. This thesis tries to address some of these challenges related to UTC technology by focusing initially on modelling of transistors on mechanically bendable Si-UTCs. The developed behavioural models are a combination of mathematical equations and extracted parameters from BSIM4 and BSIM6 modified by a set of equations describing the bending-induced stresses on silicon. The transistor models are written in Verilog-A and compiled in Cadence Virtuoso environment where they were simulated at different bending conditions. To complement this, the verification of these models through experimental results is also presented. Two chips were designed using a 180 nm CMOS technology. The first chip includes nMOS and pMOS transistors with fixed channel width and two different channel lengths and two different channel orientations (0° and 90°) with respect to the wafer crystal orientation. The second chip includes inverter logic gates with different transistor sizes and orientations, as in the previous chip. Both chips were thinned down to ∼20m using dicing-before-grinding (DBG) prior to electrical characterisation at different bending conditions. Furthermore, this thesis presents the first reported fully integrated CMOS-based ISFET microsystem on UTC technology. The design of the integrated CMOS-based ISFET chip with 512 integrated on-chip ISFET sensors along with their read-out and digitisation scheme is presented. The integrated circuits (ICs) are thinned down to ∼30m and the bulky, as well as thinned ICs, are electrically and electrochemically characterised. Also, the thesis presents the first reported mechanically bendable CMOS-based ISFET device demonstrating that mechanical deformation of the die can result in drift compensation through the exploitation of the piezoresistive nature of silicon. Finally, this thesis presents the studies towards the development of on-chip reference electrodes and biodegradable and ultra-thin biosensors for the detection of neurotransmitters such as dopamine and serotonin

Políticas de Copyright de Publicações Científicas em Repositórios Institucionais: O Caso do INESC TEC

A progressiva transformação das práticas científicas, impulsionada pelo desenvolvimento das novas Tecnologias de Informação e Comunicação (TIC), têm possibilitado aumentar o acesso à informação, caminhando gradualmente para uma abertura do ciclo de pesquisa. Isto permitirá resolver a longo prazo uma adversidade que se tem colocado aos investigadores, que passa pela existência de barreiras que limitam as condições de acesso, sejam estas geográficas ou financeiras. Apesar da produção científica ser dominada, maioritariamente, por grandes editoras comerciais, estando sujeita às regras por estas impostas, o Movimento do Acesso Aberto cuja primeira declaração pública, a Declaração de Budapeste (BOAI), é de 2002, vem propor alterações significativas que beneficiam os autores e os leitores. Este Movimento vem a ganhar importância em Portugal desde 2003, com a constituição do primeiro repositório institucional a nível nacional. Os repositórios institucionais surgiram como uma ferramenta de divulgação da produção científica de uma instituição, com o intuito de permitir abrir aos resultados da investigação, quer antes da publicação e do próprio processo de arbitragem (preprint), quer depois (postprint), e, consequentemente, aumentar a visibilidade do trabalho desenvolvido por um investigador e a respetiva instituição. O estudo apresentado, que passou por uma análise das políticas de copyright das publicações científicas mais relevantes do INESC TEC, permitiu não só perceber que as editoras adotam cada vez mais políticas que possibilitam o auto-arquivo das publicações em repositórios institucionais, como também que existe todo um trabalho de sensibilização a percorrer, não só para os investigadores, como para a instituição e toda a sociedade. A produção de um conjunto de recomendações, que passam pela implementação de uma política institucional que incentive o auto-arquivo das publicações desenvolvidas no âmbito institucional no repositório, serve como mote para uma maior valorização da produção científica do INESC TEC.The progressive transformation of scientific practices, driven by the development of new Information and Communication Technologies (ICT), which made it possible to increase access to information, gradually moving towards an opening of the research cycle. This opening makes it possible to resolve, in the long term, the adversity that has been placed on researchers, which involves the existence of barriers that limit access conditions, whether geographical or financial. Although large commercial publishers predominantly dominate scientific production and subject it to the rules imposed by them, the Open Access movement whose first public declaration, the Budapest Declaration (BOAI), was in 2002, proposes significant changes that benefit the authors and the readers. This Movement has gained importance in Portugal since 2003, with the constitution of the first institutional repository at the national level. Institutional repositories have emerged as a tool for disseminating the scientific production of an institution to open the results of the research, both before publication and the preprint process and postprint, increase the visibility of work done by an investigator and his or her institution. The present study, which underwent an analysis of the copyright policies of INESC TEC most relevant scientific publications, allowed not only to realize that publishers are increasingly adopting policies that make it possible to self-archive publications in institutional repositories, all the work of raising awareness, not only for researchers but also for the institution and the whole society. The production of a set of recommendations, which go through the implementation of an institutional policy that encourages the self-archiving of the publications developed in the institutional scope in the repository, serves as a motto for a greater appreciation of the scientific production of INESC TEC