Sensores de fibra ótica para meios desafiantes

With the present work, the development of fiber optic sensor solutions for the application in challenging media was intended. New sensor structures based on the post-processing of optical fibers were addressed, taking into account their sensitivity to variations in the external environment. In a first stage, fiber Bragg gratings were embedded in lithium batteries, to monitor temperature in situ and operando. Due to the harsh chemical environment of the battery, fiber optic sensors revealed to be the most advantageous alternative, when comparing to the electronic sensors. Fiber sensors exhibited good sensitivities and fast responses, besides being less invasive, thus they did not compromise the battery response. Furthermore, they were chemically stable. Still in the framework of this theme, and with the objective of monitoring possible strain and pressure variations inside the batteries, new sensors based on in-line Fabry-Perot cavities have been proposed. These sensors were characterized in lateral load, strain, and temperature. In a later stage, the study focused on the development of configurations that allowed to obtain high-resolution and/or sensitivity sensors. One of such configurations was obtained by creating a hollow microsphere at the fiber tip. The sensor was used to detected concentration variations and refractive index of glycerin and water mixtures. The influence of the diaphragm size in the sensor response was also studied, as well as the temperature response. New sensors based on multimode interference have also been characterized, using a coreless silica fiber tip. First, the influence of different parameters, such as length and diameters were analyzed. The sensors were tested in different solutions of glucose and water. It was observed that the sensor diameter is a decisive factor in obtaining devices that are more sensitive to refractive index and, consequently, to concentration. The determination of the thermo-optic coefficient of water/ethanol mixtures was also addressed using a multimode fiber interferometer sensor. Finally, a multimode interferometer sensor was functionalized by depositing agarose throughout the structure, allowing to optimize the response of the sensors to the external environment.Com o presente trabalho pretendeu-se explorar soluções de sensores em fibra ótica para a aplicação em meios desafiantes. Novas estruturas sensoras baseadas em pós-processamento de fibra ótica foram abordadas, tendo em consideração a sua sensibilidade a variações do meio externo. Numa primeira etapa, foram embebidas redes de Bragg no interior de baterias de lítio, para monitorizar variações de temperatura in situ e operando. Devido ao complexo meio químico da bateria, os sensores em fibra ótica revelaram ser uma alternativa mais vantajosa em relação aos sensores elétricos, não só pela sensibilidade e rápida resposta, mas também pelo fato de não afetarem o desempenho da bateria. Além disso, os sensores usados revelaram ser pouco invasivos e quimicamente estáveis. Ainda no âmbito deste tema, e com o objetivo de monitorizar possíveis deformações e variações de pressão no interior da bateria de lítio, foram desenvolvidos novos sensores baseados em cavidades de Fabry-Perot do tipo in-line. Esses sensores foram caraterizados em pressão lateral, deformação e temperatura. Numa fase posterior, o estudo centrou-se no desenvolvimento de configurações que permitissem a obtenção de sensores com elevada resolução e/ou sensibilidade. Uma das configurações consistiu na formação de uma microesfera oca na ponta de uma fibra ótica. Esse sensor foi utilizado para detetar variações de concentração e índice de refração de misturas de glicerina e água. A influência do tamanho do diafragma na resposta do sensor também foi estudada, assim como a resposta em temperatura. Em seguida, desenvolveram-se novos sensores baseados em interferência multimodo, utilizando para tal uma ponta de fibra de sílica sem núcleo. Numa primeira abordagem analisou-se a influência de diferentes parâmetros, como o comprimento e o diâmetro dos sensores. Os sensores foram expostos a diferentes soluções de glucose e água. Verificou-se que o diâmetro do sensor é um fator decisivo para a obtenção de dispositivos mais sensíveis ao índice de refração e, consequentemente, à concentração. Foi também desenvolvido um sensor baseado em interferência multimodo que permitiu determinar o coeficiente termo-ótico de misturas de etanol e água. Por fim, procedeu-se à funcionalização de um sensor baseado em interferência multimodo através da deposição de agarose ao longo da estrutura, permitindo assim otimizar a sua resposta a variações do meio externo.Programa Doutoral em Engenharia Físic

Dynamic Characterisation of Fibre-Optic Temperature Sensors for Physiological Monitoring

Fast, miniature temperature sensors are required for various biomedical applications. Fibre-optics are particularly suited to minimally invasive procedures, and many types of fibre-optic temperature sensors have been demonstrated. In applications where rapidly varying temperatures are present, a fast and well-known response time is important; however, in many cases, the dynamic behaviour of the sensor is not well-known. In this article, we investigate the dynamic response of a polymer-based interferometric temperature sensor, using both an experimental technique employing optical heating with a pulsed laser, and a computational heat transfer model based on the finite element method. Our results show that the sensor has a time constant on the order of milliseconds and a −6 dB bandwidth of up to 178 Hz, indicating its suitability for applications such as flow measurement by thermal techniques, photothermal spectroscopy, and monitoring of thermal treatments

Optical Coherence Tomography for Polymer Film Evaluation

Development of functional polymer films and film stacks has been under increasing demand to create new generations of novel, compact, light-weight optics. Optical coherence tomography (OCT) is capable of evaluating all the important optical properties of a film or film stack, including topology of surfaces or layer-to-layer interfaces, the refractive index and thickness, and polarization property. By engineering the scanning architecture of an OCT system, high-precision metrology of films of either flat or spherical geometry is achieved. In this chapter, the system design, metrology methodologies, and examples of OCT for film metrology are discussed to provide both the knowledge foundation and the engineering perspectives. The advanced film metrology capabilities offered by OCT play a key role in the manufacturing process maturity of newly developed films. Rapid advancement in the field of OCT is foreseen to drive the application toward in-line film metrology and facilitate the rapid growth of innovative films in the industry

Polymer Materials in Sensors, Actuators and Energy Conversion

Polymer-based materials applications in sensors, actuators, and energy conversion play a key role in recently developing areas of smart materials and electronic devices. These areas cover the synthesis, structures, and properties of polymers and composites, including energy-harvesting devices and energy-storage devices for electromechanical (electrical to mechanical energy conversion) and magneto-mechanical (magnetic to mechanical energy conversion), light-emitting devices, and electrically driving sensors. Therefore, the modulation of polymer-based materials and devices for controlling the detection, actuation, and energy with functionalized relative device can be achieved with the present reprint, comprising 12 chapters.This reprint is principally concerned with the topic of materials of materials, especially polymers. The contents not only involve essential information but also possess many novel academic applications in the fields. This Special Issue's title is "Polymer Materials in Sensors, Actuators and Energy Conversion" and covers the research field of polymers .Finally, I am very proud of my dear wife Winnie, son Vincent, and daughter Ruby. I thank them for supporting me in finishing the reprint. The reprint, involving 2 reviews and 10 regular papers, has been accomplished, and I am deeply thankful to all the authors for their assistance in producing a reprint with considerable number of chapters. I also hope that readers can achieve some useful understanding of polymer materials in sensors, actuators, and energy conversion, and that that they will be employed by scientists and researchers

Hybrid Optical Fiber Sensors for Smart Materials and Structures

There has been a rapid growth in the use of advanced composite materials in a variety of load-bearing structures, for example in aviation for structures such as rotor blades, aircraft fuselage and wing structures. Composite materials embedded with fiber-optic sensors (FOS) have been recognized as one of the prominent enabling technologies for smart materials and structures. The rapid increase in the interest in composite materials embedded with FOS has been driven by numerous applications, such as intelligent composite manufacturing/processing, and safety-related areas in aircrafts. Research has been focused recently on using several optical sensor types working together to form so called “hybrid optical fiber sensors” in order to overcome the limitations of the individual sensor technologies. The main aim of the research described in this thesis is to investigate a hybrid sensing scheme that utilizes polarimetric sensors and FBG sensors working in a complimentary fashion to measure multiple physical parameters in a composite material, with a particular focus on measuring the complex indirect parameters thermal expansion and vibration. The research described in this thesis investigates the performance of a hybrid sensing scheme based on polarimetric sensors and FBG sensors after embedding in a composite material. It is shown that the influence of thermal expansion within a composite material on embedded polarimetric sensors is the main source of errors for embedded fiber sensor strain measurements and that for practical strain sensing applications buffer coated PM-PCF are more suitable for embedding in composite. Further, using a buffer stripped PM-PCF polarimetric sensor, a measurement scheme to measure a composite material\u27s thermal elongation induced strain is proposed. A novel hybrid sensor for simultaneous measurement of strain, temperature and thermal strain is demonstrated by integrating polarimetric sensors based on acrylate coated high bi-refringent polarization maintaining photonic crystal fiber (HB-PM-PCF), and a coating stripped HB-PM-PCF sensor together with an FBG sensor. Flexible demodulation modules that can be embedded or surface attached is a challenge for composite materials containing fiber-optic sensors. In this thesis an interrogation method that allows intensity domain operation of hybrid sensor is demonstrated. Further focusing towards the miniaturization of the hybrid sensor interrogator, a miniaturized flexible interrogator for the demonstrated hybrid sensing scheme embedded in a composite material is also designed. Low frequency vibration measurements are performed for glass fibre-reinforced composite material samples with two different strain-sensitive polarimetric sensor types embedded. It is shown that the strain sensitivity of polarimetric sensors limits the vibration measurements to a certain range of vibration amplitudes. A polarimetric sensor based buffer stripped HB-PM-PCF is demonstrated for monitoring the different stages of the curing process for a Mageneto-Rheological composite material. By providing information about multiple parameters such as strain, temperature, thermal strain, vibration amplitude and vibration frequency the proposed and demonstrated hybrid sensing approach has a high potential to change the paradigm for smart material design in the future

Multiplexed optical fibre sensors for civil engineering applications

Fibre-optic sensors have been the focus of a lot of research, but their associated high cost has stifled their transferral from the laboratory to real world applications. This thesis addresses the issue of multiplexing, a technology that would lower the cost per unit sensor of a sensor system dramatically. An overview of the current state of research of, and the principles behind, multiplexed sensor networks is given. A new scheme of multiplexing, designated W*DM, is developed and implemented for a fibre Bragg grating (FBG) optical fibre sensor network. Using harmonic analysis, multiplexing is performed in the domain dual to that of the wavelength domain of a sensor. This scheme for multiplexing is compatible with the most commonly used existing schemes of WDM and TDM and thus offers an expansion over, and a resultant cost decrease from, the sensor systems currently in use. This research covered a theoretical development of the scheme, a proof of principle, simulated and experimental analysis of the performance of the multiplexed system, investigation into sensor design requirements and related issues, fabrication of the sensors according to the requirements of the scheme and the successful multiplexing of eight devices (thus offering an eightfold increase over current network capacities) using this scheme. Extensions of this scheme to other fibre sensors such as Long Period Gratings (LPGs) and blazed gratings were also investigated. Two LPGs having a moiré structure were successfully multiplexed and it was shown that a blazed Fabry Perot grating could be used as a tuneable dual strain/refractive index sensor. In performing these tests, it was discovered that moiré LPGs exhibited a unique thermal switching behaviour, hereto unseen. Finally the application of fibre sensors to the civil engineering field was investigated. The skill of embedding optical fibre in concrete was painstakingly developed and the thermal properties of concrete were investigated using these sensors. Field tests for the structural health monitoring of a road bridge made from a novel concrete material were performed. The phenomenon of shrinkage, creep and cracking in concrete was investigated showing the potential for optical fibre sensors to be used as a viable research tool for the civil engineer

Investigation into Smart Multifunctional Optical System-On-A-Chip Sensor Platform and Its Applications in Optical Wireless Sensor Networks

Wireless sensor networks (WSNs) have been widely used in various applications to acquire distributed information through cooperative efforts of sensor nodes. Most of the sensor nodes used in WSNs are based on mechanical or electrical sensing mechanisms, which are susceptible to electromagnetic interference (EMI) and can hardly be used in harsh environments. Although these disadvantages of conventional sensor nodes can be overcome by employing optical sensing methods, traditional optical systems are usually bulky and expensive, which can hardly be implemented in WSNs. Recently, the emerging technologies of silicon photonics and photonic crystal promise a solution of integrating a complete optical system through a complementary metal-oxide-semiconductor (CMOS) process. However, such an integration still remains a challenge. The overall objective of this dissertation work is to develop a smart multifunctional optical system-on-a-chip (SOC) sensor platform capable of both phase modulation and wavelength tuningfor heterogeneous sensing, and implement this platform in a sensor node to achieve an optical WSN for various applications, including those in harsh environments. The contributions of this dissertation work are summarized as follows. i)A smart multifunctional optical SOC sensor platform for heterogeneous sensing has beendeveloped for the first time. This platform can be used to perform phase modulation and demodulation in a low coherence interferometric configuration or wavelength tuning in a spectrum sensing configuration.The multifunctional optical sensor platform is developed through hybrid integration of a light source, an optical modulator, and multiple photodetectors. As the key component of the SOC platform, two types of modulators, namely, the opto-mechanical and electro-optical modulators, are investigated. For the first time, interrogating different types of heterogeneous sensors, including various Fabry-Perot (FP) sensors and fiber Bragg grating (FBG) sensors, with a single SOC sensor platform, is demonstrated. ii)Enhanced understanding of the principles of the multifunctional optical platform withanopto-mechanical modulator has been achieved.As a representative of opto-mechanical modulators, a microelectromechanical systems (MEMS) based FP tunable filter is thoroughly investigated through mechanical and optical modeling. The FP tunable filter is studied for both phase modulation and wavelength tuning, and design guidelines are developed based on the modeling and parametric studies. It is found that the MEMS tunable filter can achieve a large modulation depth, but it suffers from a trade-off between modulation depth and speed. iii) A novel silicon electro-optical modulator based on microring structures for optical phase modulation and wavelength tuning has been designed. To overcome the limitations of the opto-mechanical modulators including low modulation speed and mechanical instability, a CMOS compatible high speed electro-optical silicon modulator is designed, which combines microring and photonic crystal structures for phase modulation in interferometric sensors and makes use of two cascaded microrings for wavelength tuning in sensors that require spectrum domain signal processing. iv)A novel optical SOC WSN node has been developed. The optical SOC sensor platform and the associated electric circuit are integrated with a conventional WSN module to achieve an optical WSN node, enabling optical WSNs for various applications. v) A novel cross-axial dual-cavity FP sensor has been developed for simultaneous pressure and temperature sensing.Across-axial sensor is useful in measuring static pressures without picking up dynamic pressures in the presence of surface flows. The dual-cavity sensing structure is used for both temperature and pressure measurements without the need for another temperature sensor for temperature drift compensation. This sensor can be used in moderate to high temperature environments, which demonstrates the potential of using the optical WSN sensor node in a harsh environment

Micro-/Nano-Fiber Sensors and Optical Integration Devices

The development of micro/nanofiber sensors and associated integrated systems is a major project spanning photonics, engineering, and materials science, and has become a key academic research trend. During the development of miniature optical sensors, different materials and micro/nanostructures have been reasonably designed and functionalized on the ordinary single-mode optical fibers. The combination of various special optical fibers and new micro/nanomaterials has greatly improved the performance of the sensors. In terms of optical integration, micro/nanofibers play roles in independent and movable optical waveguide devices, and can be conveniently integrated into two-dimensional chips to realize the efficient transmission and information exchange of optical signals based on optical evanescent field coupling technology. In terms of systematic integration, the unique optical transmission mode of optical fiber has shown great potential in the array and networking of multiple sensor units.In this book, more than ten research papers were collected and studied, presenting research on optical micro/nanofiber devices and related integrated systems, covering high-performance optical micro/nanofiber sensors, fine characterization technologies for optical micro/nanostructures, weak signal detection technologies in photonic structures, as well as fiber-assisted highly integrated optical detection systems