Dense Packings of Superdisks and the Role of Symmetry

We construct the densest known two-dimensional packings of superdisks in the plane whose shapes are defined by |x^(2p) + y^(2p)| <= 1, which contains both convex-shaped particles (p > 0.5, with the circular-disk case p = 1) and concave-shaped particles (0 < p < 0.5). The packings of the convex cases with p 1 generated by a recently developed event-driven molecular dynamics (MD) simulation algorithm [Donev, Torquato and Stillinger, J. Comput. Phys. 202 (2005) 737] suggest exact constructions of the densest known packings. We find that the packing density (covering fraction of the particles) increases dramatically as the particle shape moves away from the "circular-disk" point (p = 1). In particular, we find that the maximal packing densities of superdisks for certain p 6 = 1 are achieved by one of the two families of Bravais lattice packings, which provides additional numerical evidence for Minkowski's conjecture concerning the critical determinant of the region occupied by a superdisk. Moreover, our analysis on the generated packings reveals that the broken rotational symmetry of superdisks influences the packing characteristics in a non-trivial way. We also propose an analytical method to construct dense packings of concave superdisks based on our observations of the structural properties of packings of convex superdisks.Comment: 15 pages, 8 figure

A Solidification Phenomenon in Random Packings

We prove that uniformly random packings of copies of a certain simply-connected figure in the plane exhibit global connectedness at all sufficiently high densities, but not at low densities

Hyperuniformity, quasi-long-range correlations, and void-space constraints in maximally random jammed particle packings. I. Polydisperse spheres

Hyperuniform many-particle distributions possess a local number variance that grows more slowly than the volume of an observation window, implying that the local density is effectively homogeneous beyond a few characteristic length scales. Previous work on maximally random strictly jammed sphere packings in three dimensions has shown that these systems are hyperuniform and possess unusual quasi-long-range pair correlations, resulting in anomalous logarithmic growth in the number variance. However, recent work on maximally random jammed sphere packings with a size distribution has suggested that such quasi-long-range correlations and hyperuniformity are not universal among jammed hard-particle systems. In this paper we show that such systems are indeed hyperuniform with signature quasi-long-range correlations by characterizing the more general local-volume-fraction fluctuations. We argue that the regularity of the void space induced by the constraints of saturation and strict jamming overcomes the local inhomogeneity of the disk centers to induce hyperuniformity in the medium with a linear small-wavenumber nonanalytic behavior in the spectral density, resulting in quasi-long-range spatial correlations. A numerical and analytical analysis of the pore-size distribution for a binary MRJ system in addition to a local characterization of the n-particle loops governing the void space surrounding the inclusions is presented in support of our argument. This paper is the first part of a series of two papers considering the relationships among hyperuniformity, jamming, and regularity of the void space in hard-particle packings.Comment: 40 pages, 15 figure

A method for dense packing discovery

The problem of packing a system of particles as densely as possible is foundational in the field of discrete geometry and is a powerful model in the material and biological sciences. As packing problems retreat from the reach of solution by analytic constructions, the importance of an efficient numerical method for conducting \textit{de novo} (from-scratch) searches for dense packings becomes crucial. In this paper, we use the \textit{divide and concur} framework to develop a general search method for the solution of periodic constraint problems, and we apply it to the discovery of dense periodic packings. An important feature of the method is the integration of the unit cell parameters with the other packing variables in the definition of the configuration space. The method we present led to improvements in the densest-known tetrahedron packing which are reported in [arXiv:0910.5226]. Here, we use the method to reproduce the densest known lattice sphere packings and the best known lattice kissing arrangements in up to 14 and 11 dimensions respectively (the first such numerical evidence for their optimality in some of these dimensions). For non-spherical particles, we report a new dense packing of regular four-dimensional simplices with density $\phi=128/219\approx0.5845$ and with a similar structure to the densest known tetrahedron packing.Comment: 15 pages, 5 figure

Statistical theory of correlations in random packings of hard particles

A random packing of hard particles represents a fundamental model for granular matter. Despite its importance, analytical modeling of random packings remains difficult due to the existence of strong correlations which preclude the development of a simple theory. Here, we take inspiration from liquid theories for the $n$-particle angular correlation function to develop a formalism of random packings of hard particles from the bottom-up. A progressive expansion into a shell of particles converges in the large layer limit under a Kirkwood-like approximation of higher-order correlations. We apply the formalism to hard disks and predict the density of two-dimensional random close packing (RCP), $\phi_{\rm rcp} = 0.85\pm0.01$, and random loose packing (RLP), $\phi_{\rm rlp} = 0.67\pm0.01$. Our theory also predicts a phase diagram and angular correlation functions that are in good agreement with experimental and numerical data.Comment: 9 pages, 6 figures, to appear in PR

In a search for a shape maximizing packing fraction for two-dimensional random sequential adsorption

Random sequential adsorption (RSA) of various two dimensional objects is studied in order to find a shape which maximizes the saturated packing fraction. This investigation was begun in our previous paper [Cie\'sla et al., Phys. Chem. Chem. Phys. 17, 24376 (2015)], where the densest packing was studied for smoothed dimers. Here this shape is compared with a smoothed $n$-mers, spherocylinders and ellipses. It is found that the highest packing fraction out of the studied shapes is $0.58405 \pm 0.0001$ and is obtained for ellipses having long-to-short axis ratio of $1.85$, which is also the largest anisotropy among the investigated shapes.Comment: 14 pages, 7 fiure

Periodic Planar Disk Packings

Several conditions are given when a packing of equal disks in a torus is locally maximally dense, where the torus is defined as the quotient of the plane by a two-dimensional lattice. Conjectures are presented that claim that the density of any strictly jammed packings, whose graph does not consist of all triangles and the torus lattice is the standard triangular lattice, is at most $\frac{n}{n+1}\frac{\pi}{\sqrt{12}}$, where $n$ is the number of packing disks. Several classes of collectively jammed packings are presented where the conjecture holds.Comment: 26 pages, 13 figure

Basic Understanding of Condensed Phases of Matter via Packing Models

Packing problems have been a source of fascination for millenia and their study has produced a rich literature that spans numerous disciplines. Investigations of hard-particle packing models have provided basic insights into the structure and bulk properties of condensed phases of matter, including low-temperature states (e.g., molecular and colloidal liquids, crystals and glasses), multiphase heterogeneous media, granular media, and biological systems. The densest packings are of great interest in pure mathematics, including discrete geometry and number theory. This perspective reviews pertinent theoretical and computational literature concerning the equilibrium, metastable and nonequilibrium packings of hard-particle packings in various Euclidean space dimensions. In the case of jammed packings, emphasis will be placed on the "geometric-structure" approach, which provides a powerful and unified means to quantitatively characterize individual packings via jamming categories and "order" maps. It incorporates extremal jammed states, including the densest packings, maximally random jammed states, and lowest-density jammed structures. Packings of identical spheres, spheres with a size distribution, and nonspherical particles are also surveyed. We close this review by identifying challenges and open questions for future research.Comment: 33 pages, 20 figures, Invited "Perspective" submitted to the Journal of Chemical Physics. arXiv admin note: text overlap with arXiv:1008.298

Hyperuniformity, quasi-long-range correlations, and void-space constraints in maximally random jammed particle packings. II. Anisotropy in particle shape

We extend the results from the first part of this series of two papers by examining hyperuniformity in heterogeneous media composed of impenetrable anisotropic inclusions. Specifically, we consider maximally random jammed packings of hard ellipses and superdisks and show that these systems both possess vanishing infinite-wavelength local-volume-fraction fluctuations and quasi-long-range pair correlations. Our results suggest a strong generalization of a conjecture by Torquato and Stillinger [Phys. Rev. E. 68, 041113 (2003)], namely that all strictly jammed saturated packings of hard particles, including those with size- and shape-distributions, are hyperuniform with signature quasi-long-range correlations. We show that our arguments concerning the constrained distribution of the void space in MRJ packings directly extend to hard ellipse and superdisk packings, thereby providing a direct structural explanation for the appearance of hyperuniformity and quasi-long-range correlations in these systems. Additionally, we examine general heterogeneous media with anisotropic inclusions and show for the first time that one can decorate a periodic point pattern to obtain a hard-particle system that is not hyperuniform with respect to local-volume-fraction fluctuations. This apparent discrepancy can also be rationalized by appealing to the irregular distribution of the void space arising from the anisotropic shapes of the particles. Our work suggests the intriguing possibility that the MRJ states of hard particles share certain universal features independent of the local properties of the packings, including the packing fraction and average contact number per particle.Comment: 29 pages, 9 figure

Critical slowing down and hyperuniformity on approach to jamming

Hyperuniformity characterizes a state of matter that is poised at a critical point at which density or volume-fraction fluctuations are anomalously suppressed at infinite wavelengths. Recently, much attention has been given to the link between strict jamming and hyperuniformity in frictionless hard-particle packings. Doing so requires one to study very large packings, which can be difficult to jam properly. We modify the rigorous linear programming method of Donev et al. [J. Comp. Phys. 197, 139 (2004)] in order to test for jamming in putatively jammed packings of hard-disks in two dimensions. We find that various standard packing protocols struggle to reliably create packings that are jammed for even modest system sizes; importantly, these packings appear to be jammed by conventional tests. We present evidence that suggests that deviations from hyperuniformity in putative maximally random jammed (MRJ) packings can in part be explained by a shortcoming in generating exactly-jammed configurations due to a type of "critical slowing down" as the necessary rearrangements become difficult to realize by numerical protocols. Additionally, various protocols are able to produce packings exhibiting hyperuniformity to different extents, but this is because certain protocols are better able to approach exactly-jammed configurations. Nonetheless, while one should not generally expect exact hyperuniformity for disordered packings with rattlers, we find that when jamming is ensured, our packings are very nearly hyperuniform, and deviations from hyperuniformity correlate with an inability to ensure jamming, suggesting that strict jamming and hyperuniformity are indeed linked. This raises the possibility that the ideal MRJ packings have no rattlers. Our work provides the impetus for the development of packing algorithms that produce large disordered strictly jammed packings that are rattler-free.Comment: 15 pages, 11 figures. Accepted for publication in Phys. Rev.