Three-Dimensional Modeling of Electrostatic Precipitator Using Hybrid Finite Element - Flux Corrected Transport Technique

This thesis presents the results of a three-dimensional simulation of the entire precipitation process inside a single-electrode one-stage electrostatic precipitator (ESP). The model was designed to predict the motion of ions, gas and solid particles. The precipitator consists of two parallel grounded collecting plates with a corona electrode mounted at the center, parallel to the plates and excited with a high dc voltage. The complex mutual interaction between the three coexisting phenomena of electrostatic field, fluid dynamics and the particulate transport, which affect the ESP process, were taken into account in all the simulations. The electrostatic field and ionic space charge density due to corona discharge were computed by numerically solving Poisson and current continuity equations, using a hybrid Finite Element (FEM) - Flux Corrected Transport (FCT) method. The detailed numerical approach and simulation procedure is discussed and applied throughout the thesis. Calculations of the gas flow were carried out by solving the Reynolds-averaged Navier-Stokes equations using the commercial FLUENT 6.2 software, which is based on the Finite Volume Method (FVM). The turbulence effect was included by using the k-ε model included in FLUENT. An additional source term was added to the gas flow equation to include the effect of the electric field, obtained by solving a coupled system of the electric field and charge transport equations, using the User-Defined-Function (UDF) feature of FLUENT. The particle phase was simulated using a Lagrangian-type Discrete Random Walk (DRW) model, where a large number of particles charged by combined field and diffusion charging mechanisms was traced with their motion affected by electrostatic and aerodynamic forces in turbulent flow using the Discrete Phase Model (DPM) and programming UDFs in FLUENT. The airflow patterns under the influence of electrohydrodynamic (EHD) secondary flow and external flows, particle charging and deposition along the channel, and ESP performance in removal of submicron particulates were compared for smooth and spiked discharge electrode configurations in the parallel plate precipitator assuming various particle concentrations at the inlet. Finally, a laboratory scale wire-cylinder ESP to collect conductive submicron diesel particles was modeled. The influence of different inlet gas velocities and excitation voltages on the particle migration velocity and precipitation performance were investigated. In some cases, the simulation results were compared with the existing experimental data published in literature

Measuring Aerosol Nanoparticles By Ultraviolet Photoionisation

Aerosol particulate matter adversely affects the climate, environment and human health. Mechanistic studies have indicated that ultrafine aerosol nanoparticles, those under 100 nm in diameter, may have significant health impacts due to their relatively high number concentration, surface area and potential for deep penetration into the human lung. However, epidemiological evidence remains limited due to the lack of measurement networks that monitor local concentrations of ultrafine particles. Direct ultraviolet (UV) photoionisation electrically charges aerosol nanoparticles for subsequent detection by a mechanism distinct from the ion-particle collisions of conventional methods. The aim of this work is to evaluate photoionisation theory in order to understand and interpret measurements from a low-cost aerosol particle sensor. To accomplish this, theoretical equations are analysed, modelled and compared with experimental results for validation. The photoelectric yield of aerosol particles is explored in terms of particle size, concentration, material, and morphology giving insight into the interaction of light and particles. This thesis introduces the first analysis of photoionisation, recombination, convection/diffusion and transport of particles in an electric field using analytical, numerical, and computational fluid dynamics (CFD) techniques. Characteristic times and dimensionless parameters are defined to determine regimes under which the measurement system is dominated by each of the charging or transport mechanisms. The level of modelling detail required for accurate prediction of aerosol charging and capture methods is demonstrated over a range of conditions. In a continuous flow of aerosol particles, an electric field is applied to capture charge as it is photoemitted from particles and before the emitted charge and particles can recombine. This method yields a novel current measurement directly representative of photoemission. The CFD model agrees well with electrical current measurements demonstrating that the physics of the problem is suitably represented. It is demonstrated that photoemission is linearly proportional to total (mobility) surface area for a large range of sizes and concentrations of particles of self-similar material and morphology, with agglomerated silver particles having 5$\times$ yield of agglomerated carbon from a propane flame. It is shown for the first time that agglomerated particles have a significantly higher photoelectric yield (2.6$\times$) than sintered, close-packed spheres of the same mobility diameter and material, directly contradicting two of the three previous relevant studies. Close-packed spheres have less material exposed to both the photon flux and the particle's surroundings than an agglomerate of the same particle mobility diameter, thereby reducing photoelectric activity. The photoelectrically active area is defined explicitly in this work to reflect the effect of a particle's morphology; the revised definition produces good agreement with experimental results.Alphasense Ltd., Cambridge Trust, Natural Sciences and Engineering Research Council of Canada (NSERC

Wet electrostatic scrubbing for high efficiency submicron particle capture

Exposure to fine particulate matter has been associated with serious health effects, including respiratory and cardiovascular disease, and mortality. Very fine inhalable particles can remain suspended in the atmosphere for a long time, travel long distances from the emitting sources and, once inhaled, they can reach the deepest regions of the lungs and even enter in the circulatory system. Therefore, the smaller the particle size, the higher its toxicity. In typical combustion units used in process industry, the end-of-pipe technologies include trains of consecutive abatements devices. Nevertheless, the traditional particle abatement devices are mainly designed and optimized to treat particles with sizes above or around 1µm, and they are far less effective towards the submicron dimensions. Among the end-of-pipe technologies, the Wet Scrubbers (WS) are widely utilized in industry due to their capacity to capture simultaneously gaseous pollutants and particles. The main particle collection mechanisms involved in WS are those related to directional interception and inertial impact, which allow high particle abatement efficiency for particles in micrometric range. Both the mechanisms are instead ineffective in the submicron range, thus resulting in low collection efficiencies. It the past 40 years, it was demonstrated that the presence of electric charge of opposite polarities on the particles and the sprayed droplets can increase the capture efficiency due to Coulomb forces between the two phases. The presence of this additional contribution in a scrubber is an upgrade of the traditional wet scrubbing and the new process is commonly referred as Wet Electrostatic Scrubbing (WES). Experimental investigation of the pertinent literature confirmed the ability of WES to increase the particle capture efficiency respect to the classic wet scrubber, but submicron range is generally not directly investigated so that the best operating conditions to increase submicron particle abatement efficiency is still an unsolved problem. This optimization problem is mainly related to the difficulties to model wet electrostatic scrubbing process due to the high number of the variables involved, resulting in a complex experimental evaluation of the main collection mechanisms that are responsible of the particle capture. Above all, a significant hindrance to the assessment of a proper description of wet electrostatic scrubbing is the complexity of the electro-hydrodynamics of the charged water spray. In this work, a new experimental methodology was adopted to perform experiments in controlled conditions in order to allow an easier investigation of the effects of the main physical variables on the abatement of submicron particles emission. This experimental approach is based on the use of a lab scale batch reactor, in which charged particles produced by combustion are inserted. In the reactor, a train of uniform droplet size and charge is used to remove the suspended particles. This approach has the main advantages to make possible to investigate specific parameters (like the effect of droplet charge or its size) under well-defined conditions and therefore model the particle abatement process. Therefore, the objective of this work is the experimental analysis and the modeling of wet electrostatic scrubbing process for submicron particles with the new methodology developed and the evaluation of the influence of the main physical variables on the capture of submicron particles. The results obtained confirm that the particle abatement is significantly enhanced by charging both particles and droplets, and that the particle abatement rate is directly proportional to the particles and droplet charges and droplet concentration. Furthermore, tests with uncharged particles and charged droplets do not show any relevant increase in the scrubbing efficiency with respect to common wet scrubbing in the investigated conditions. The experimental results obtained were compared with the predictions of classical particle scavenging models valid for ambient temperature and humidity conditions. These models were rarely applied to submicron particles and found a reliable experimental support from the performed experiments. On the other hand, this comparison also confirm the reliability of the experimental methodology in the study of wet electrostatic scrubbing and encourage the development of further tests in experimental conditions more similar to that of industrial scrubbers

Ultrafine particle generation and measurement

Ultrafine particles (UFPs) with diameters smaller than 100 nm are omnipresent in ambient air. They are important sources for fine particles produced through the agglomeration and/or vapor condensation. With their unique properties, UFPs have also been manufactured for industrial applications. But, from the toxicological and health perspective, ultrafine particles with high surface-to-volume ratios often have high bio-availability and toxicity. Many recent epidemiologic studies have evidence UFPs are highly relevant to human health and disease. In order to better investigate UFPs, better instrumentation and measurement techniques for UFPs are thus in need. The overall objective of this dissertation is to advance out current knowledge on UFPs generation and measurement. Accordingly, it has two major parts: (1) ultrafine particle generation for laboratory aerosol research via electrospray (ES), and (2) ultrafine particle measurement for ambient aerosol monitor and personal exposure study via the development of a cost-effective and compact electrical mobility particle sizer. In the first part, to provide monodisperse nanoparticles, a new single capillary electrospray with a soft X-ray photoionizer as a charge reduction scheme has been developed. The soft X-ray effects on electrospray operation, particle size distribution and particle charge reduction were evaluated. To generate ultrafine particles with sufficient mass concentration for exposure/toxicity study, a TSE twin-head electrospray (THES) was evaluated, as well. The configuration and operational variables of the studied THES has been optimized. Three different nanoparticle suspensions were sprayed to investigate material difference. In the second part, to develop a miniature electrical mobility based ultrafine particle sizer (mini e-UPS), a new mini-plate aerosol charger and a new mini-plate differential mobility analyzer (DMA) have been developed. The performances of mini-plate charger and mini-plate DMA were carefully evaluated for ultrafine particles, including intrinsic/extrinsic charging, extrinsic charge distribution, DMA sizing accuracy and DMA transfer function. A prototype mini e-UPS was then assembled and tested by laboratory generated aerosol. Also a constrained least square method was applied to recover the particle size distribution from the current measured by a mini Faraday Cage aerosol electrometer

Modeling of diesel particulate emissions aftertreatment system using non-thermal plasma

There is a growing demand for energy usage in the world, primarily due to increasing economic activity. This need can be met by pursuing increased power generation. However the impact of emissions from power generation sources on the health of human beings and environmental continues to be a major concern. In order to maintain and enhance environmental quality there is a need for the development of clean energy products. A diesel aftertreatment device was developed at RIT to reduce particulate matter (PM) in the emissions of generators and diesel engines by using the combination of non-thermal plasma oxidation and emission catalyst technologies. The non-thermal plasma (corona discharge) created by a high voltage electrode produces ionized gas or plasma in the charging section of the device. Simultaneously gas atoms are excited, producing highly reactive O, OH, and NO2 radicals. These radicals oxidize PM to gaseous products including CO, and CO2. The device has a low pressure drop compared with other diesel aftertreatment devices since it selfregenerates and there is no accumulation of PM in the system. The scope of this thesis is to develop a numerical model to simulate the performance of this diesel aftertreatment device. The model calculates the diesel exhaust conditions, plasma generation condition, electric field, power consumption, particulate collection, and particle removal. The model results agree with the experimental data, which proves that the model can be used for system performance prediction. Based on keeping the same PM removal efficiency and back pressure effects on diesel engine, a method was developed for system scale-up or scale-down

Smoke Aerosol Characterization for Spacecraft Fire Detection Systems

Appropriate design of fire detection systems requires knowledge of both the expected fire signature and the background aerosol levels. Terrestrial fire detection systems have been developed based on extensive study of terrestrial fires. Unfortunately there is no corresponding data set for spacecraft fires and consequently the fire detectors in current spacecraft were developed based upon terrestrial designs. There are a number of factors that affect the smoke particle size distribution in spacecraft fires. In low gravity, buoyant flow is negligible which causes particles to concentrate at the smoke source, increasing their residence time, and increasing the transport time to smoke detectors. Microgravity fires have significantly different structure than those in 1-g which can change the formation history of the smoke particles. Finally the materials used in spacecraft are different from typical terrestrial environments where smoke properties have been evaluated. It is critically important to detect a fire in its early phase before a flame is established, given the fixed volume of air on any spacecraft. Consequently, the primary target for spacecraft fire detection is pyrolysis products rather than soot. This dissertation is a compilation of experimental investigations performed at three different NASA facilities which characterize smoke aerosols from overheating common spacecraft materials. The earliest effort consists of aerosol measurements in low gravity, called the Smoke Aerosol Measurement Experiment (SAME), and subsequent ground-based testing of SAME smoke in 55-gallon drums with an aerosol reference instrument. The feasibility of the moment method for characterizing smoke from limited data, including the lognormal assumption, is explored. Experiments in low gravity are very rare and expensive, so detailed studies to exploit every possible aspect of the data to increase the science outcome are warranted. Another set of experiments were performed at NASA’s Johnson Space Center White Sands Test Facility (WSTF), with additional fuels and an alternate smoke production method. Measurements of these smoke products include mass and number concentration, and a thermal precipitator was designed for this investigation to capture particles for microscopic analysis. Smoke particle morphology and chemical composition are analyzed for various fuels. The final data presented are from NASA’s Gases and Aerosols from Smoldering Polymers (GASP) Laboratory, with selected results focusing on realistic fuel preparations and heating profiles with regards to early detection of smoke. Additional research on ambient air quality in the International Space Station (ISS) is presented which sheds light on background aerosols that may interfere with smoke detection in spacecraft

Fundamentals of air pollution engineering

Analysis and abatement of air pollution involve a variety of technical disciplines. Formation of the most prevalent pollutants occurs during the combustion process, a tightly coupled system involving fluid flow, mass and energy transport, and chemical kinetics. Its complexity is exemplified by the fact that, in many respects, the simplest hydrocarbon combustion, the methane-oxygen flame, has been quantitatively modeled only within the last several years. Nonetheless, the development of combustion modifications aimed at minimizing the formation of the unwanted by-products of burning fuels requires an understanding of the combustion process. Fuel may be available in solid, liquid, or gaseous form; it may be mixed with the air ahead of time or only within the combustion chamber; the chamber itself may vary from the piston and cylinder arrangement in an automobile engine to a 10-story-high boiler in the largest power plant; the unwanted byproducts may remain as gases, or they may, upon cooling, form small particles. The only effective way to control air pollution is to prevent the release of pollutants at the source. Where pollutants are generated in combustion, modifications to the combustion process itself, for example in the manner in which the fuel and air are mixed, can be quite effective in reducing their formation. Most situations, whether a combustion or an industrial process, however, require some degree of treatment of the exhaust gases before they are released to the atmosphere. Such treatment can involve intimately contacting the effluent gases with liquids or solids capable of selectively removing gaseous pollutants or, in the case of particulate pollutants, directing the effluent flow through a device in which the particles are captured on surfaces. The study of the generation and control of air pollutants can be termed air pollution engineering and is the subject of this book. Our goal here is to present a rigorous and fundamental analysis of the production of air pollutants and their control. The book is intended for use at the senior or first-year graduate level in chemical, civil, environmental, and mechanical engineering curricula. We assume that the student has had basic first courses in thermodynamics, fluid mechanics, and heat transfer. The material treated in the book can serve as the subject of either a full-year or a one-term course, depending on the choice of topics covered. In the first chapter we introduce the concept of air pollution engineering and summarize those species classified as air pollutants. Chapter 1 also contains four appendices that present certain basic material that will be called upon later in the book. This material includes chemical kinetics, the basic equations of heat and mass transfer, and some elementary ideas from probability and turbulence. Chapter 2 is a basic treatment of combustion, including its chemistry and the role of mixing processes and flame structure. Building on the foundation laid in Chapter 2, we present in Chapter 3 a comprehensive analysis of the formation of gaseous pollutants in combustion. Continuing in this vein, Chapter 4 contains a thorough treatment of the internal combustion engine, including its principles of operation and the mechanisms of formation of pollutants therein. Control methods based on combustion modification are discussed in both Chapters 3 and 4. Particulate matter (aerosols) constitutes the second major category of air pollutants when classified on the basis of physical state. Chapter 5 is devoted to an introduction to aerosols and principles of aerosol behavior, including the mechanics of particles in flowing fluids, the migration of particles in external force fields, Brownian motion of small particles, size distributions, coagulation, and formation of new particles from the vapor by homogeneous nucleation. Chapter 6 then treats the formation of particles in combustion processes. Chapters 7 and 8 present the basic theories of the removal of particulate and gaseous pollutants, respectively, from effluent streams. We cover all the major air pollution control operations, such as gravitational and centrifugal deposition, electrostatic precipitation, filtration, wet scrubbing, gas absorption and adsorption, and chemical reaction methods. Our goal in these two chapters, above all, is to carefully derive the basic equations governing the design of the control methods. Limited attention is given to actual equipment specification, although with the material in Chapters 7 and 8 serving as a basis, one will be able to proceed to design handbooks for such specifications. Chapters 2 through 8 treat air pollution engineering from a process-by-process point of view. Chapter 9 views the air pollution control problem for an entire region or airshed. To comply with national ambient air quality standards that prescribe, on the basis of health effects, the maximum atmospheric concentration level to be attained in a region, it is necessary for the relevant governmental authority to specify the degree to which the emissions from each of the sources in the region must be controlled. Thus it is generally necessary to choose among many alternatives that may lead to the same total quantity of emission over the region. Chapter 9 establishes a framework by which an optimal air pollution control plan for an airshed may be determined. In short, we seek the least-cost combination of abatement measures that meets the necessary constraint that the total emissions not exceed those required to meet an ambient air quality standard. Once pollutants are released into the atmosphere, they are acted on by a variety of chemical and physical phenomena. The atmospheric chemistry and physics of air pollution is indeed a rich arena, encompassing the disciplines of chemistry, meteorology, fluid mechanics, and aerosol science. As noted above, the subject matter of the present book ends at the stack (or the tailpipe); those readers desiring a treatment of the atmospheric behavior of air pollutants are referred to J. H. Seinfeld, Atmospheric Chemistry and Physics of Air Pollution (Wiley-Interscience, New York, 1986). We wish to gratefully acknowledge David Huang, Carol Jones, Sonya Kreidenweis, Ranajit Sahu, and Ken Wolfenbarger for their assistance with calculations in the book. Finally, to Christina Conti, our secretary and copy editor, who, more than anyone else, kept safe the beauty and precision of language as an effective means of communication, we owe an enormous debt of gratitude. She nurtured this book as her own; through those times when the task seemed unending, she was always there to make the road a little smoother. R. C. Flagan J. H. Seinfel