7,726 research outputs found
Strong Orientation Effects in Ionization of H by Short, Intense, High-Frequency Light Sources
We present three dimensional time-dependent calculations of ionization of
arbitrarily spatially oriented H by attosecond, intense, high-frequency
laser fields. The ionization probability shows a strong dependence on both the
internuclear distance and the relative orientation between the laser field and
the internuclear axis.Comment: 4 pages, 4 figure
Ionization of hydrogen and hydrogenic ions by antiprotons
Presented here is a description of the ionization of hydrogen and hydrogenic
ions by antiproton-impact, based on very large scale numerical solutions of the
time-dependent Schr\"odinger equation in three spatial dimensions and on
analysis of the topology of the electronic eigenenergy surfaces in the plane of
complex internuclear distance. Comparison is made with other theories and very
recent measurements.Comment: RevTex document, 11 pages, 4 Postscript figures are available from
the authors, in press Phys. Rev. Let
Electronic structure and rovibrational predissociation of the 2sPi state in KLi
Adiabatic potential energy curves of the 3sSigma+, 3tSigma+, 2sPi and 2tPi
states correlating for large internuclear distance with the K(4s) + Li(2p)
atomic asymptote were calculated. Very good agreement between the calculated
and the experimental curve of the 2sPi state allowed for a reliable description
of the dissociation process through a small (20 cm-1 for J = 0) potential
energy barrier. The barrier supports several rovibrational quasi-bound states
and explicit time evolution of these states via the time-dependent nuclear
Schroedinger equation, showed that the state populations decay exponentially in
time. We were able to precisely describe the time-dependent dissociation
process of several rovibrational levels and found that our calculated spectrum
match very well with the assigned experimental spectrum. Moreover, our approach
is able to predict the positions of previously unassigned lines despite their
low intensit
Multiconfiguration Time-Dependent Hartree-Fock Treatment of Electronic and Nuclear Dynamics in Diatomic Molecules
The multiconfiguration time-dependent Hartree-Fock (MCTDHF) method is
formulated for treating the coupled electronic and nuclear dynamics of diatomic
molecules without the Born- Oppenheimer approximation. The method treats the
full dimensionality of the electronic motion, uses no model interactions, and
is in principle capable of an exact nonrelativistic description of diatomics in
electromagnetic fields. An expansion of the wave function in terms of
configurations of orbitals whose dependence on internuclear distance is only
that provided by the underlying prolate spheroidal coordinate system is
demonstrated to provide the key simplifications of the working equations that
allow their practical solution. Photoionization cross sections are also
computed from the MCTDHF wave function in calculations using short pulses.Comment: Submitted to Phys Rev
Nuclear classical dynamics of H in intense laser field
In the first part of this paper, the different distinguishable pathways and
regions of the single and sequential double ionization are determined and
discussed. It is shown that there are two distinguishable pathways for the
single ionization and four distinct pathways for the sequential double
ionization. It is also shown that there are two and three different regions of
space which are related to the single and double ionization respectively. In
the second part of the paper, the time dependent Schr\"{o}dinger and Newton
equations are solved simultaneously for the electrons and the nuclei of H
respectively. The electrons and nuclei dynamics are separated on the base of
the adiabatic approximation. The soft-core potential is used to model the
electrostatic interaction between the electrons and the nuclei. A variety of
wavelengths (390 nm, 532 nm and 780 nm) and intensities (
and ) of the ultrashort intense laser
pulses with a sinus second order envelope function are used. The behaviour of
the time dependent classical nuclear dynamics in the absence and present of the
laser field are investigated and compared. In the absence of the laser field,
there are three distinct sections for the nuclear dynamics on the electronic
ground state energy curve. The bond hardening phenomenon does not appear in
this classical nuclear dynamics simulation.Comment: 16 pages, 7 figure
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