Single and double heterojunction nanorods for optoelectronics

Understanding charge separation and recombination processes and developing materials that can efficiently direct charge carriers with nanoscale precision are of fundamental importance in advancing next-generation electronics, optoelectronics and energy technologies. As semiconductor heterostructures have enabled today’s electronics and optoelectronics, the introduction of active heterojunctions can impart new and improved capabilities that will facilitate integration of colloidal quantum dots into high performance devices. With anisotropic shapes that can be exploited for assembly, charge carrier manipulation and optical anisotropy, incorporating heterojunctions in colloidal semiconductor nanorods presents a promising direction. Various motifs of epitaxial heterojunctions introduced in nanorods through solution chemistry will be presented along with unusual properties and prospects arising from the formation of heterointerfaces. Assembly into thin films and integration into photovoltaics and light-emitting diodes will also be discusse

Development of High-Performance Graphene-HgCdTe Detector Technology for Mid-Wave Infrared Applications

A high-performance graphene-based HgCdTe detector technology is being developed for sensing over the mid-wave infrared (MWIR) band for NASA Earth Science, defense, and commercial applications. This technology involves the integration of graphene into HgCdTe photodetectors that combines the best of both materials and allows for higher MWIR(2-5 m) detection performance compared to photodetectors using only HgCdTe material. The interfacial barrier between the HgCdTe-based absorber and the graphene layer reduces recombination of photogenerated carriers in the detector. The graphene layer also acts as high mobility channel that whisks away carriers before they recombine, further enhancing the detector performance. Likewise, HgCdTe has shown promise for the development of MWIR detectors with improvements in carrier mobility and lifetime. The room temperature operational capability of HgCdTe-based detectors and arrays can help minimize size, weight, power and cost for MWIR sensing applications such as remote sensing and earth observation, e.g., in smaller satellite platforms. The objective of this work is to demonstrate graphene-based HgCdTe room temperature MWIR detectors and arrays through modeling, material development, and device optimization. The primary driver for this technology development is the enablement of a scalable, low cost, low power, and small footprint infrared technology component that offers high performance, while opening doors for new earth observation measurement capabilities

Effect of Electrolyte Concentration on the Capacitance and Mobility of Graphene

The use of graphene field-effect transistors as a biosensor is increasingly being used to study biological phenomena, due to the sensitivity and low reactivity of graphene. To further improve sensitivity in biological environments, we examined how different salt concentrations affect the mobility of capacitance of the graphene. Samples were also measured after an annealing process. We report on the positive correlation between sensitivity and electrolyte concentration and speculate on methods to improve future detectors. Mobility of the device was found to change from 1.07*103cm2/ (V*s) in de-ionized water to 2.78*103cm2/ (V*s) in a 500 mM potassium phosphate buffer solution

Space Shuttle separation mechanisms

The development of space shuttle separation devices is reviewed to illustrate the mechanisms involved in separating the orbiter from the Boeing 747 carrier aircraft and from the externally mounted propellant tank. Other aspects of the separation device development discussed include design evolution, operational experience during the orbiter approach and landing tests, and the work to be accomplished before an operational system becomes a reality

Simulation of nanostructure-based high-efficiency solar cells: challenges, existing approaches and future directions

Many advanced concepts for high-efficiency photovoltaic devices exploit the peculiar optoelectronic properties of semiconductor nanostructures such as quantum wells, wires and dots. While the optics of such devices is only modestly affected due to the small size of the structures, the optical transitions and electronic transport can strongly deviate from the simple bulk picture known from conventional solar cell devices. This review article discusses the challenges for an adequate theoretical description of the photovoltaic device operation arising from the introduction of nanostructure absorber and/or conductor components and gives an overview of existing device simulation approaches.Comment: Invited paper, accepted for publication in IEEE Journal of Selected Topics in Quantum Electronic

SLM-based Digital Adaptive Coronagraphy: Current Status and Capabilities

Active coronagraphy is deemed to play a key role for the next generation of high-contrast instruments, notably in order to deal with large segmented mirrors that might exhibit time-dependent pupil merit function, caused by missing or defective segments. To this purpose, we recently introduced a new technological framework called digital adaptive coronagraphy (DAC), making use of liquid-crystal spatial light modulators (SLMs) display panels operating as active focal-plane phase mask coronagraphs. Here, we first review the latest contrast performance, measured in laboratory conditions with monochromatic visible light, and describe a few potential pathways to improve SLM coronagraphic nulling in the future. We then unveil a few unique capabilities of SLM-based DAC that were recently, or are currently in the process of being, demonstrated in our laboratory, including NCPA wavefront sensing, aperture-matched adaptive phase masks, coronagraphic nulling of multiple star systems, and coherent differential imaging (CDI).Comment: 14 pages, 9 figures, to appear in Proceedings of the SPIE, paper 10706-9

Electron-electron interactions in decoupled graphene layers

Multi-layer graphene on the carbon face of silicon carbide is an intriguing electronic system which typically consists of a stack of ten or more layers. Rotational stacking faults in this system dramatically reduce inter-layer coherence. In this article we report on the influence of inter-layer interactions, which remain strong even when coherence is negligible, on the Fermi liquid properties of charged graphene layers. We find that inter-layer interactions increase the magnitudes of correlation energies and decrease quasiparticle velocities, even when remote-layer carrier densities are small, and that they lessen the influence of exchange and correlation on the distribution of carriers across layers.Comment: 8 pages, 4 figures, submitte