Structure of MnO nanoparticles embedded into channel-type matrices

X-ray diffraction experiments were performed on MnO confined in mesoporous silica SBA-15 and MCM-41 matrices with different channel diameters. The measured patterns were analyzed by profile analysis and compared to numerical simulations of the diffraction from confined nanoparticles. From the lineshape and the specific shift of the diffraction reflections it was shown that the embedded objects form ribbon-like structures in the SBA-15 matrices with channels diameters of 47-87 {\AA}, and nanowire-like structures in the MCM-41 matrices with channels diameters of 24-35 {\AA}. In the latter case the confined nanoparticles appear to be narrower than the channel diameters. The physical reasons for the two different shapes of the confined nanoparticles are discussed.Comment: 8 pages, including 9 postscript figures, uses revtex4.cl

Far-Field Plasmonic Resonance Enhanced Nano-Particle Image Velocimetry within a Micro Channel

In this paper, a novel far-field plasmonic resonance enhanced nanoparticle-seeded Particle Image Velocimetry (nPIV) has been demonstrated to measure the velocity profile in a micro channel. Chemically synthesized silver nanoparticles have been used to seed the flow in the micro channel. By using Discrete Dipole Approximation (DDA), plasmonic resonance enhanced light scattering has been calculated for spherical silver nanoparticles with diameters ranging from 15nm to 200nm. Optimum scattering wavelength is specified for the nanoparticles in two media: water and air. The diffraction-limited plasmonic resonance enhanced images of silver nanoparticles at different diameters have been recorded and analyzed. By using standard PIV techniques, the velocity profile within the micro channel has been determined from the images.Comment: submitted to Review of Scientific Instrument

Multiple jet impingement heat transfer characteristic: Experimental investigation of in-line and staggered arrays with crossflow

Heat transfer characteristics were obtained for configurations designed to model the impingement cooled midchord region of air cooled gas turbine airfoils. The configurations tested were inline and staggered two-dimensional arrays of circular jets with ten spanwise rows of holes. The cooling air was constrained to exit in the chordwise direction along the channel formed by the jet orifice plate and the heat transfer surface. Tests were run for chordwise jet hole spacings of five, ten, and fifteen hole diameters; spanwise spacings of four, six, and eight diameters; and channel heights of one, two, three, and six diameters. Mean jet Reynolds numbers ranged from 5000 to 50,000. The thermal boundary condition at the heat transfer test surface was isothermal. Tests were run for sets of geometrically similar configurations of different sizes. Mean and chordwise resolved Nusselt numbers were determined utilizing a specially constructed test surface which was segmented in the chordwise direction

Computer program MCAP provides for steady state thermal and flow analysis of multiple parallel channels in heat generating solid

Computer program /MCAP/ calculates the temperature distribution in a heat generating solid complicated by nonuniform power and flow distributions between multiple channels. It determines the channel diameters coefficients, the effects of tolerences, the pressure drop at a given flowrate, or the flowrate for a specific pressure drop

Evolution of the magnetic phase transition in MnO confined to channel type matrices. Neutron diffraction study

Neutron diffraction studies of antiferromagnetic MnO confined to MCM-41 type matrices with channel diameters 24-87 A demonstrate a continuous magnetic phase transition in contrast to a discontinuous first order transition in the bulk. The character of the magnetic transition transforms with decreasing channel diameter, showing the decreasing critical exponent and transition temperature, however the latter turns out to be above the N\'eel temperature for the bulk. This enhancement is explained within the framework of Landau theory taking into consideration the ternary interaction of the magnetic and associated structural order parameters.Comment: 6 pages pdf file, including 4 figures, uses revtex4.cl

Theory of cooling by flow through narrow pores

We consider the possibility of adding a stage to a dilution refrigerator to provide additional cooling by ``filtering out'' hot atoms. Three methods are considered: 1) Effusion, where holes having diameters larger than a mean-free path allow atoms to pass through easily; 2) Particle waveguide-like motion using very narrow channels that greatly restrict the quantum states of the atoms in a channel. 3) Wall-limited diffusion through channels, in which the wall scattering is disordered so that local density equilibrium is established in a channel. We assume that channel dimension are smaller than the mean-free path for atom-atom interactions. The particle waveguide and the wall-limited diffusion methods using channels on order of the de Broglie wavelength give cooling. Recent advances in nano-filters give this method some hope of being practical.Comment: 10 pages, 3 figures. Corrected typos and made some minor wording change

Crucial role of side walls for granular surface flows: consequences for the rheology

In this paper we study the steady uniform flows that develop when granular material is released from a hopper on top of a static pile in a channel. We more specifically focus on the role of side walls by carrying out experiments in setup of different widths, from narrow channels 20 particle diameters wide to channels 600 particle diameters wide. Results show that steady flows on pile are entirely controlled by side wall effects. A theoretical model, taking into account the wall friction and based on a simple local constitutive law recently proposed for other granular flow configurations (GDR MiDi 2004), gives predictions in quantitative agreement with the measurements. This result gives new insights in our understanding of free surface granular flows and strongly supports the relevance of the constitutive law proposed.Comment: a forgotten square root in Appendix B (Eq B4), and corrected coefficients in Appendix C; 25 pages, 17 figures, published in J. Fluid Mec

Morphology of rain water channelization in systematically varied model sandy soils

We visualize the formation of fingered flow in dry model sandy soils under different raining conditions using a quasi-2d experimental set-up, and systematically determine the impact of soil grain diameter and surface wetting property on water channelization phenomenon. The model sandy soils we use are random closely-packed glass beads with varied diameters and surface treatments. For hydrophilic sandy soils, our experiments show that rain water infiltrates into a shallow top layer of soil and creates a horizontal water wetting front that grows downward homogeneously until instabilities occur to form fingered flows. For hydrophobic sandy soils, in contrast, we observe that rain water ponds on the top of soil surface until the hydraulic pressure is strong enough to overcome the capillary repellency of soil and create narrow water channels that penetrate the soil packing. Varying the raindrop impinging speed has little influence on water channel formation. However, varying the rain rate causes significant changes in water infiltration depth, water channel width, and water channel separation. At a fixed raining condition, we combine the effects of grain diameter and surface hydrophobicity into a single parameter and determine its influence on water infiltration depth, water channel width, and water channel separation. We also demonstrate the efficiency of several soil water improvement methods that relate to rain water channelization phenomenon, including pre-wetting sandy soils at different level before rainfall, modifying soil surface flatness, and applying superabsorbent hydrogel particles as soil modifiers