Bioinspired Multifunctional Janus Particles for Droplet Manipulation

Inspired by the nipple arrays covering mosquitoes’ eyes and the heterogeneous textured bumps on beetles’ backs, we have developed a new kind of Janus particle with multiplexed features, such as different boss arrays and wettability compartmentalized on the same surface, and an anisotropic color and magnetic properties. The prepared Janus particles can be anchored at the air–water interface and act as a highly flexible barrier for preventing coalescence of water droplets. The incorporation of magnetic nanoparticles can give the Janus particles magnetic responsiveness for controlled transportation and coalescence of liquid marbles, while the structural colors in the Janus particles can be employed for barcoding of the encapsulated liquid marbles. We believe that these small Janus particles have great potential as components for constructing intelligent interfacial objects

Bioinspired Multifunctional Janus Particles for Droplet Manipulation

Inspired by the nipple arrays covering mosquitoes’ eyes and the heterogeneous textured bumps on beetles’ backs, we have developed a new kind of Janus particle with multiplexed features, such as different boss arrays and wettability compartmentalized on the same surface, and an anisotropic color and magnetic properties. The prepared Janus particles can be anchored at the air–water interface and act as a highly flexible barrier for preventing coalescence of water droplets. The incorporation of magnetic nanoparticles can give the Janus particles magnetic responsiveness for controlled transportation and coalescence of liquid marbles, while the structural colors in the Janus particles can be employed for barcoding of the encapsulated liquid marbles. We believe that these small Janus particles have great potential as components for constructing intelligent interfacial objects

Bioinspired Noniridescent Structural Color with Hidden Patterns for Anticounterfeiting

Noniridescent structural colors, by virtue of their pigment-like features and simple preparation techniques, have pivotal roles in color-related applications. However, because of the wide bandwidth resulting from coherent scattering, noniridescent structural colors lack the angle-altered color feature, which plays a critical role in angle-altered colored identification of structural color. Therefore, developing a novel strategy for noniridescent structural colors in security applications remains a challenge. Inspired by Diphylleia grayi, we developed a thickness-controlled silica@polydopamine (SiO2@PDA) amorphous arrays anticounterfeiting system. Owing to the melanin absorption of PDA, the SiO2@PDA amorphous arrays exhibit visual noniridescent structural colors in air but the brownish-black color of PDA in water. More importantly, when the arrays’ thickness exceeds 9 μm, the SiO2@PDA amorphous arrays display thickness-independent structural color in air but thickness-dependent PDA (brownish-black) color in water. On the basis of this finding, any designs of patterns with uniform or multicolored structural color can be encrypted by employing the distinct thicknesses and selectively disclosed in a liquid solvent environment. We believe these simple, user-interactive noniridescent structurally colored arrays are appealing for various security-related applications, such as anticounterfeiting

Bioinspired Multifunctional Janus Particles for Droplet Manipulation

Inspired by the nipple arrays covering mosquitoes’ eyes and the heterogeneous textured bumps on beetles’ backs, we have developed a new kind of Janus particle with multiplexed features, such as different boss arrays and wettability compartmentalized on the same surface, and an anisotropic color and magnetic properties. The prepared Janus particles can be anchored at the air–water interface and act as a highly flexible barrier for preventing coalescence of water droplets. The incorporation of magnetic nanoparticles can give the Janus particles magnetic responsiveness for controlled transportation and coalescence of liquid marbles, while the structural colors in the Janus particles can be employed for barcoding of the encapsulated liquid marbles. We believe that these small Janus particles have great potential as components for constructing intelligent interfacial objects

Bioinspired Multifunctional Janus Particles for Droplet Manipulation

Inspired by the nipple arrays covering mosquitoes’ eyes and the heterogeneous textured bumps on beetles’ backs, we have developed a new kind of Janus particle with multiplexed features, such as different boss arrays and wettability compartmentalized on the same surface, and an anisotropic color and magnetic properties. The prepared Janus particles can be anchored at the air–water interface and act as a highly flexible barrier for preventing coalescence of water droplets. The incorporation of magnetic nanoparticles can give the Janus particles magnetic responsiveness for controlled transportation and coalescence of liquid marbles, while the structural colors in the Janus particles can be employed for barcoding of the encapsulated liquid marbles. We believe that these small Janus particles have great potential as components for constructing intelligent interfacial objects

New Strategy for Surface Functionalization of Periodic Mesoporous Silica Based on meso-HSiO_1.5

Organic functionalization of periodic mesoporous silicas (PMSs) offers a way to improve their excellent properties and wide applications owing to their structural superiority. In this study, a new strategy for organic functionalization of PMSs is demonstrated by hydrosilylation of the recently discovered “impossible” periodic mesoporous hydridosilica, meso-HSiO_1.5. This method overcomes the disadvantages of present pathways for organic functionalization of PMSs with organosilica. Moreover, compared to the traditional functionalization on the surface of porous silicon by hydrosilylation, the template-synthesized meso-HSiO_1.5 is more flexible to access functional-groups-loaded PMSs with adjustable microstructures. The new method and materials will have wider applications based on both the structure and surface superiorities

Bioinspired Multifunctional Janus Particles for Droplet Manipulation

Inspired by the nipple arrays covering mosquitoes’ eyes and the heterogeneous textured bumps on beetles’ backs, we have developed a new kind of Janus particle with multiplexed features, such as different boss arrays and wettability compartmentalized on the same surface, and an anisotropic color and magnetic properties. The prepared Janus particles can be anchored at the air–water interface and act as a highly flexible barrier for preventing coalescence of water droplets. The incorporation of magnetic nanoparticles can give the Janus particles magnetic responsiveness for controlled transportation and coalescence of liquid marbles, while the structural colors in the Janus particles can be employed for barcoding of the encapsulated liquid marbles. We believe that these small Janus particles have great potential as components for constructing intelligent interfacial objects