Harvesting Triplet Excitons with Exciplex Thermally Activated Delayed Fluorescence Emitters toward High Performance Heterostructured Organic Light-Emitting Field Effect Transistors

The utilization of triplet excitons plays a key role in obtaining high emission efficiency for organic electroluminescent devices. However, to date, only phosphorescent materials have been implemented to harvest the triplet excitons in the organic light-emitting field effect transistors (OLEFETs). In this work, we report the first incorporation of exciplex thermally activated delayed fluorescence (TADF) emitters in heterostructured OLEFETs to harvest the triplet excitons. By developing a new kind of exciplex TADF emitter constituted by m-MTDATA (4,4′,4″-tris­(<i>N</i>-3-methylphenyl-<i>N</i>-phenylamino)­triphenylamine) as the donor and OXD-7 (1,3-bis­[2-(4-<i>tert</i>-butylphenyl)-1,3,4-oxadiazo-5-yl]­benzene) as the acceptor, an exciton utilization efficiency of 74.3% for the devices was achieved. It is found that the injection barrier between hole transport layer and emission layer as well as the ratio between donor and acceptor would influence the external quantum efficiency (EQE) significantly. Devices with a maximum EQE of 3.76% which is far exceeding the reported results for devices with conventional fluorescent emitters were successfully demonstrated. Moreover, the EQE at high brightness even outperformed the result for organic light-emitting diode based on the same emitter. Our results demonstrate that the exciplex TADF emitters can be promising candidates to develop OLEFETs with high performance

Efficient Inorganic Perovskite Light-Emitting Diodes with Polyethylene Glycol Passivated Ultrathin CsPbBr₃ Films

Efficient inorganic perovskite light-emitting diodes (PeLEDs) with an ultrathin perovskite emission layer (∼30 nm) were realized by doping Lewis base polyethylene glycol (PEG) into CsPbBr₃ films. PEG in the perovskite films not only physically fills the crystal boundaries but also interacts with the perovskite crystals to passivate the crystal grains, reduce nonradiative recombination, and ensure efficient luminance and high efficiency. As a result, promoted brightness, current efficiency (CE), and external quantum efficiency (EQE) were achieved. The nonradiative decay rate of the PEG:CsPbBr₃ composite film is 1 order of magnitude less than that of the neat CsPbBr₃ film. After further optimization of the molar ratio between CsBr and PbBr₂, a peak CE of 19 cd/A, a maximum EQE of 5.34%, and a maximum brightness of 36600 cd/m² were achieved, demonstrating the interaction between PEG and the precursors. The results are expected to offer some helpful implications in optimizing the polymer-assisted PeLEDs with ultrathin emission layers, which might have potential application in see-through displays

Toward Highly Luminescent and Stabilized Silica-Coated Perovskite Quantum Dots through Simply Mixing and Stirring under Room Temperature in Air

Methylammonium (MA) lead halide (MAPbX₃, X = Cl, Br, I) perovskite quantum dots (PQDs) are very sensitive to environment (moisture, oxygen, and temperature), suffering from poor stability. To improve the stability, we synthesized silica-coated PQDs (SPQDs) by an improved ligand-assisted reprecipitation method through simply mixing and stirring under room temperature in air without adding water and catalyst, the whole process took only a few seconds. The photoluminescence (PL) spectra of the SPQDs can be tuned continuously from 460 to 662 nm via adjusting the composition proportion of precursors. The highest PL quantum yields (PLQYs) of blue-, green-, and red-emissive SPQDs are 56, 95, and 70%, respectively. The SPQDs show remarkably improved environmental and thermal stability compared to the naked PQDs because of effective barrier created by the coated silica between the core materials and the ambience. Furthermore, it is found that different light-emitting SPQDs can maintain their original PL properties after mixing of them and anion-exchange reactions have not happened. These attributes were then used to mix green- and yellow-emissive SPQDs with polystyrene (PS) to form color-converting layers for the fabrication of white light-emitting devices (WLEDs). The WLEDs exhibit excellent white light characteristics with CIE 1931 color coordinates of (0.31, 0.34) and color rendering index (CRI) of 85, demonstrating promising applications of SPQDs in lighting and displays