Engineering Reactions in Crystalline Solids: Radical Pairs in Crystals of Dialkyl 1,3-Acetonedicarboxylates

Crystalline dialkyl 1,3-acetonedicarboxylates give dialkyl succinates in high chemical yields by combination of α-carbonyl radical pairs produced by photochemical decarbonylation. It is proposed that the solid-state reaction depends on the exothermicity of two consecutive bond cleavage processes. It is also suggested that the efficiency of radical formation in the solid state is determined by the effect of substituents on bond dissociation energies and radical-stabilization abilities

Data for: The Upper Bound of Thin-film Composite Polyamide Membranes for Desalination

Data for: The Upper Bound of Thin-film Composite Polyamide Membranes for Desalinatio

Stereospecific Synthesis of Alkylidenecyclopropanes via Sequential Cyclopropene Carbomagnesation/1,3-Carbon Shift

Alkylidenecyclopropanes can be synthesized from enantiomerically enriched cyclopropene derivatives with >99% stereotransfer and good to excellent yield. The protocol comprises the stereoselective reaction of Grignard reagents with 1-alkoxymethyl-3-hydroxymethylcyclopropenes and a stereospecific [1,3] carbon shift reaction

sj-docx-2-amp-10.1177_25152459211070573 – Supplemental material for PsyBuilder: An Open-Source, Cross-Platform Graphical Experiment Builder for Psychtoolbox With Built-In Performance Optimization

Supplemental material, sj-docx-2-amp-10.1177_25152459211070573 for PsyBuilder: An Open-Source, Cross-Platform Graphical Experiment Builder for Psychtoolbox With Built-In Performance Optimization by Zhicheng Lin, Zhe Yang, Chengzhi Feng and Yang Zhang in Advances in Methods and Practices in Psychological Science</p

Stereospecific Synthesis of Alkylidenecyclopropanes via Sequential Cyclopropene Carbomagnesation/1,3-Carbon Shift

Alkylidenecyclopropanes can be synthesized from enantiomerically enriched cyclopropene derivatives with >99% stereotransfer and good to excellent yield. The protocol comprises the stereoselective reaction of Grignard reagents with 1-alkoxymethyl-3-hydroxymethylcyclopropenes and a stereospecific [1,3] carbon shift reaction

Supplementary Figure 1 from Nuclear Envelope Rupture Is Enhanced by Loss of p53 or Rb

Supplementary Figure 1. FACS analysis of cells with Rb or p53 depletion.</p

Stereospecific Synthesis of Alkylidenecyclopropanes via Sequential Cyclopropene Carbomagnesation/1,3-Carbon Shift

Alkylidenecyclopropanes can be synthesized from enantiomerically enriched cyclopropene derivatives with >99% stereotransfer and good to excellent yield. The protocol comprises the stereoselective reaction of Grignard reagents with 1-alkoxymethyl-3-hydroxymethylcyclopropenes and a stereospecific [1,3] carbon shift reaction

Total Synthesis of (±)-Herbertenolide by Stereospecific Formation of Vicinal Quaternary Centers in a Crystalline Ketone

The sesquiterpene (±)-herbertenolide was synthesized in seven steps from commercial 2-bromo-4-methylanisole. In the key step, two adjacent stereogenic quaternary centers were controlled by a highly chemoselective and stereospecific photodecarbonylation reaction of crystalline methyl-trans-3-(2-methyl-5-methoxyphenyl)-1,3-dimethyl-2-oxocyclohexancarboxylate (3). An efficient generation of radical pairs and the stereochemical control exerted by the solid state suggest that this reaction may become a useful synthetic method

sj-docx-1-amp-10.1177_25152459211070573 – Supplemental material for PsyBuilder: An Open-Source, Cross-Platform Graphical Experiment Builder for Psychtoolbox With Built-In Performance Optimization

Supplemental material, sj-docx-1-amp-10.1177_25152459211070573 for PsyBuilder: An Open-Source, Cross-Platform Graphical Experiment Builder for Psychtoolbox With Built-In Performance Optimization by Zhicheng Lin, Zhe Yang, Chengzhi Feng and Yang Zhang in Advances in Methods and Practices in Psychological Science</p

Total Synthesis of (±)-Herbertenolide by Stereospecific Formation of Vicinal Quaternary Centers in a Crystalline Ketone

The sesquiterpene (±)-herbertenolide was synthesized in seven steps from commercial 2-bromo-4-methylanisole. In the key step, two adjacent stereogenic quaternary centers were controlled by a highly chemoselective and stereospecific photodecarbonylation reaction of crystalline methyl-trans-3-(2-methyl-5-methoxyphenyl)-1,3-dimethyl-2-oxocyclohexancarboxylate (3). An efficient generation of radical pairs and the stereochemical control exerted by the solid state suggest that this reaction may become a useful synthetic method