136 research outputs found
Analisis Adopsi Inovasi Teknologi Pertanian Berbasis Padi di Sumatera Selatan dalam Perspektif Komunikasi
Analysis of Adoption of Agricultural Technology Innovation Rice-based Farming in Sumatra inthe perspective of communications. Assessment Institute of Agricultural Technology (AIAT) South Sumatrahas produced innovative rice-based farming technology in various agroecosystem. However, adoption ratesare still relatively low. Evaluation of four assessments aimed to identify the factors that predominantly affectthe adoption of technological innovation based local-specific farming rice and to know the level of adoption.This activity is carried out in OKI, East OKU and Banyuasin regencies with 67 respondents interviewedin July-September 2007. The results of this assessment showed that the factors that influence the adoption oftechnological innovations such as the level of selective exposure of technology innovation, cosmopolite,triability, complexity of technology and agricultural extension intensity. The average adoption index for thepacket of rice cultivation technology was 50.32%. As many as 93.02% of respondents have positive perceptionsof the researcher-extension AIAT South Sumatra as the communicator in delivering information technology.Most respondents (80%) expressed a desire to obtain agricultural information generated AIAT South Sumatra.Key words: Adoption, innovation, rice, communication Balai Pengkajian Teknologi Pertanian (BPTP) Sumatera Selatan sudah menghasilkan inovasi teknologipertanian berbasis padi di berbagai agroekosistem. Namun tingkat adopsinya masih relatif rendah. Evaluasi terhadapempat pengkajian ini bertujuan untuk mengidentifikasi faktor-faktor yang dominan mempengaruhi proses adopsiinovasi teknologi pertanian spesifik lokasi berbasis padi dan mengetahui tingkat adopsinya. Kegiatan ini dilakukan diKabupaten OKI, OKU Timur dan Banyuasin dengan mewawancarai 67 orang responden pada bulan Juli – September2007. Berdasarkan hasil analisis deskriptif kualitatif diketahui bahwa (1) adopsi inovasi teknologi budidaya tanamanpadi di Sumatera Selatan dipengaruhi oleh tingkat kebutuhan petani terhadap inovasi teknologi, sifat kekosmopolitanpetani, triabilitas dan kompleksitas teknologi dan intensitas pembinaan, (2) indeks adopsi inovasi petani terhadappaket teknologi budidaya padi kondisinya beragam tergantung pada jenis kegiatan, (3) petani di Sumatera Selatanumumnya memberikan apresiasi positif terhadap peneliti-penyuluh BPTP Sumatera Selatan, terlihat dari tingginyaminat petani untuk mendapatkan berbagai media informasi pertanian BPTP Sumatera Selatan, dan (4) temuankajian ini mengindikasikan faktor komunikasi memegang peran utama yang dapat mempengaruhi adopsi teknologi
Highly Enantioselective Hydrogenation of α-Dehydroamino Esters and Itaconates with Triphosphorous Bidentate Ligands and the Unprecedented Solvent Effect Thereof
An X-ray diffraction experiment revealed an interesting
triphosphorous bidentate coordination in a Pd(II) complex
of a phosphine-phosphoramidite ligand 1, which showed
excellent enantioselectivity (up to 99.4% ee) in Rh-catalyzed
hydrogenation of α-dehydroamino esters in acetone. A
dramatic solvent effect was found in the hydrogenation of
itaconates, which induces opposite chiralities of the product
with the same catalytic system by the use of different solvents
(e.g., 99.6% ee (R) in TFE vs 71.2% ee (S) in methyl ethyl
ketone)
Highly Enantioselective Hydrogenation of α-Dehydroamino Esters and Itaconates with Triphosphorous Bidentate Ligands and the Unprecedented Solvent Effect Thereof
An X-ray diffraction experiment revealed an interesting
triphosphorous bidentate coordination in a Pd(II) complex
of a phosphine-phosphoramidite ligand 1, which showed
excellent enantioselectivity (up to 99.4% ee) in Rh-catalyzed
hydrogenation of α-dehydroamino esters in acetone. A
dramatic solvent effect was found in the hydrogenation of
itaconates, which induces opposite chiralities of the product
with the same catalytic system by the use of different solvents
(e.g., 99.6% ee (R) in TFE vs 71.2% ee (S) in methyl ethyl
ketone)
A Hybrid Phosphorus Ligand for Highly Enantioselective Asymmetric Hydroformylation
A new hybrid phosphorus ligand has been prepared starting from chiral NOBIN (2-amino-2‘-hydroxy-1,1‘-binaphthyl). Excellent enantioselectivities (up to 99% ee) have been achieved in the
Rh-catalyzed asymmetric hydroformylations of styrene derivatives and vinyl acetate
Highly Enantioselective Hydrogenation of α-Dehydroamino Esters and Itaconates with Triphosphorous Bidentate Ligands and the Unprecedented Solvent Effect Thereof
An X-ray diffraction experiment revealed an interesting
triphosphorous bidentate coordination in a Pd(II) complex
of a phosphine-phosphoramidite ligand 1, which showed
excellent enantioselectivity (up to 99.4% ee) in Rh-catalyzed
hydrogenation of α-dehydroamino esters in acetone. A
dramatic solvent effect was found in the hydrogenation of
itaconates, which induces opposite chiralities of the product
with the same catalytic system by the use of different solvents
(e.g., 99.6% ee (R) in TFE vs 71.2% ee (S) in methyl ethyl
ketone)
Highly Efficient Synthesis of Chiral β-Amino Acid Derivatives via Asymmetric Hydrogenation
The Rh−TangPhos complex is an efficient hydrogenation catalyst for making chiral β-amino acid derivatives. With the Rh−TangPhos system,
high enantioselectivities (up to 99.6%) and turnover numbers have been obtained in the hydrogenation of E/Z isomeric mixtures of both
β-alkyl and β-aryl β-(acylamino)acrylates
Highly Enantioselective Cyclocarbonylation of Allylic Alcohols Catalyzed by Novel Pd-1,4-bisphosphine Complexes
Highly Enantioselective Cyclocarbonylation of
Allylic Alcohols Catalyzed by Novel
Pd-1,4-bisphosphine Complexe
Asymmetric Rh-Catalyzed Hydrogenation of Enamides with a Chiral 1,4-Bisphosphine Bearing Diphenylphosphino Groups
Asymmetric Rh-Catalyzed Hydrogenation
of Enamides with a Chiral
1,4-Bisphosphine Bearing
Diphenylphosphino Group
Highly Enantioselective Rhodium-Catalyzed Hydrogenation of Dehydroamino Acids with New Chiral Bisphosphinites
Highly Enantioselective
Rhodium-Catalyzed Hydrogenation of
Dehydroamino Acids with New Chiral
Bisphosphinite
Palladium-Catalyzed Homocoupling Reactions between Two Csp<sup>3</sup>−Csp<sup>3</sup> Centers
A novel palladium-catalyzed coupling reaction between two Csp3−Csp3 centers has been investigated. This protocol is initiated by the oxidative
addition of an α-halo carbonyl compound to a palladium(0) species, followed by the double transmetalation. The key dialkyl palladium intermediate
undergoes reductive elimination to form the desired coupling product
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