Photonic quadrupole topological phases in zero-dimensional cavity with synthetic dimensions

Quadrupole topological insulator, which supports robust corner states, has been recently demonstrated in two-dimensional (2D) spatial lattices. Here, we design the first photonic quadrupole topological insulator in fully synthetic spaces with the utilization of 0D optical cavity. The frequency and orbital angular momentum (OAM) of light are used to form the 2D synthetic spaces. Four degenerate polarization states are mapped to the internal lattice sites within the unit cell. By suitably engineering the coupling between cavity modes with different frequencies, OAMs and polarizations, the ideal synthetic quadrupole topological insulators are obtained. By using the robust synthetic corner state, we present the possibility for achieving topological protection of multi-photon entangled states. Our designed synthetic photonic quadrupole topological insulators propose a unique platform to investigate higher-order topological phases in 0D system and possess potential applications in quantum information and communications

Moire quasi-bound states in the continuum

The novel physics of twisted bilayer graphene has motivated extensive studies of magic-angle flat bands hosted by moir\'e structures in electronic, photonic and acoustic systems. On the other hand, bound states in the continuum (BICs) have also attracted great attention in recent years because of their potential applications in the field of designing superior optical devices. Here, we combine these two independent concepts to construct a new optical state in a twisted bilayer photonic crystal slab, which is called as moir\'e quasi-BIC, and numerically demonstrate that such an exotic optical state possesses dual characteristics of moir\'e flat bands and quasi-BICs. To illustrate the mechanism for the formation of moir\'e flat bands, we develop an effective model at the center of the Brillouin zone and show that moir\'e flat bands could be fulfilled by balancing the interlayer coupling strength and the twist angle around the band edge above the light line. Moreover, by decreasing the twist angle of moir\'e photonic crystal slabs with flat bands, it is shown that the moir\'e flat-band mode at the Brillouin center gradually approaches a perfect BIC, where the total radiation loss from all diffraction channels is significantly suppressed. To clarify the advantage of moir\'e quasi-BICs, enhanced second-harmonic generation (SHG) is numerically proven with a wide-angle optical source. The efficiency of SHG assisted by designed moir\'e quasi-BICs can be greatly improved compared with that based on dispersive quasi-BICs with similar quality factors

Plasmon-induced strong interaction between chiral molecules and orbital angular momentum of light

Whether or not chiral interaction exists between the optical orbital angular momentum (OAM) and a chiral molecule remains unanswered. So far, such an interaction has not been observed experimentally. Here we present a T-matrix method to study the interaction between optical OAM and the chiral molecule in a cluster of nanoparticles. We find that strong interaction between the chiral molecule and OAM can be induced by the excitation of plasmon resonances. An experimental scheme to observe such an interaction has been proposed. Furthermore, we have found that the signal of the OAM dichroism can be either positive or negative, depending on the spatial positions of nanocomposites in the cross-sections of OAM beams. The cancellation between positive and negative signals in the spatial average can explain why the interaction has not been observed in former experiments

Machine-Learning Enhanced Enantioselective Single-Shot-Single-Molecule ac Stark Spectroscopy

Enantiodiscrimination with single-molecule and single-shot resolution is fundamental for the understanding of the fate and behavior of two enantiomers in chemical reactions, biological activity, and the function of drugs. However, molecular decoherence gives rise to spectral broadening and random errors, offering major problems for most chiroptical methods in arriving at single-shot-single-molecule resolution. Here, we introduce a machine-learning strategy to solve these problems. Specifically, we focus on the task of single-shot measurement of single-molecule chirality based on enantioselective ac Stark spectroscopy. We find that, in the large-decoherence region, where the ac Stark spectroscopy without machine learning fails to distinguish molecular chirality, in contrast, the machine-learning-assisted strategy still holds a high correct rate of up to about 90%. Beyond this overwhelming superiority, the machine-learning strategy also has considerable robustness against variation of the decoherence rates between the training and testing sets

Long-lived quantum speedup based on plasmonic hot spot systems

Long-lived quantum speedup serves as a fundamental component for quantum algorithms. The quantum walk is identified as an ideal scheme to realize the long-lived quantum speedup. However, one finds that the duration of quantum speedup is very short in real systems implementing quantum walk. The speedup can last only dozens of femtoseconds in the photosynthetic light-harvesting system, which was regarded as the best candidate for quantum information processing. Here, we construct one plasmonic system with two-level molecules embodied in the hot spots of one-dimensional nanoparticle chains to realize the long-lived quantum speedup. The coherent and incoherent coupling parameters in the system are obtained by means of Green's tensor technique. Our results reveal that the duration of quantum speedup in our scheme can exceed 500 fs under strong coherent coupling conditions, which is several times larger than that in the photosynthetic light-harvesting system. Our proposal presents a competitive scheme to realize the long-lived quantum speedup, which is very beneficial for quantum algorithms

Observation of novel robust edge states without bulk-boundary correspondence in non-Hermitian quantum walks

Recently, the study of non-Hermitian physics has attracted considerable attention. The modified bulk-boundary correspondence has been proposed to understand topological edge states in non-Hermitian static systems. Here we report a new experimental observation of edge states in non-Hermitian periodically driven systems. Some unconventional edge states are found not to be satisfied with the bulk-boundary correspondence when the system belongs to the broken parity-time (PT) symmetric phase. The experiments are performed in our constructed non-Hermitian light quantum walk platform with left and right boundaries, where the beams outside system boundary are blocked subtly at the end of each step. The robust properties of these edge states against to static perturbations and disorder have also been demonstrated experimentally. The finding of robust edge states in broken PT-symmetric phase inspires us to explore a robust transport channel in ubiquitously complex systems with strong dissipation

Tunable Manipulation of Enantiomers by Vector Exceptional Points

It is very important to achieve controllable manipulations of enantiomers in the fields of chemistry and biology. Here, we propose a method for realizing the effect of separating and purifying the opposite enantiomers by changing the relative phase of the incident lights at different times based on photonic crystal slabs sustaining vector exceptional points. Our calculations show that the large gradient of chiral optical fields can be generated with two beams of lights illuminating the photonic crystal slab from opposite directions at the vector exceptional points, and the direction of enhanced chiral optical force can be adjusted by changing the relative phase for the two beams of circularly polarized lights, making the controllable capture and separation of enantiomers achievable. Furthermore, we demonstrate the feasibility and efficiency of this design based on particle tracking simulations. This kind of chiral reversal of the separated enantiomers driven by light based on vector exceptional points is unprecedented. Our findings provide a possible route toward enantiopure syntheses in controllable all-optical platforms

Competition of Chiroptical Effect Caused by Nanostructure and Chiral Molecules

The theory to calculate circular dichroism (CD) of chiral molecules in a finite cluster with arbitrarily disposed objects has been developed by means of T-matrix method. The interactions between chiral molecules and nanostructures have been investigated. Our studies focus on the case of chiral molecules inserted into plasmonic hot spots of nanostructures. Our results show that the total CD of the system with two chiral molecules is not sum for two cases when two chiral molecules inserted respectively into the hot spots of nanoparticle clusters as the distances among nanoparticles are small, although the relationship is established at the case of large interparticle distances. The plasmonic CD arising from structure chirality of nanocomposites depends strongly on the relative positions and orientations of nanospheroids, and are much greater than that from molecule-induced chirality. However, the molecule-induced plasmonic CD effect from the molecule-NP nanocomposites with special chiral structures can be spectrally distinguishable from the structure chirality-based optical activity. Our results provide a new theoretical framework for understanding the two different aspects of plasmonic CD effect in molecule-NP nanocomposites, which would be helpful for the experimental design of novel biosensors to realize ultrasensitive probe of chiral information of molecules by plasmon-based nanotechnology

Entanglement-Assisted Quantum Chiral Spectroscopy

The most important problem of spectroscopic chiral analysis is the enantioselective effects of the light-molecule interactions are inherently weak and severely reduced by the environment noises. Enormous efforts had been spent to overcome this problem by enhancing the symmetry break in the light-molecule interactions or reducing the environment noises. Here, we propose an alternative way to solve this problem by using frequency-entangled two-photon pairs as probe signals and detecting them in coincidence, i.e., using quantum chiral spectroscopy. For this purpose, we develop the theory of entanglement-assisted quantum chiral spectroscopy. Our results show that the quantum spectra of the left- and right-handed molecules are always distinguishable by suitably configuring the frequency-entangled two-photon pairs. In contrast, the classical spectra of the two enantiomers, where the broadband signal photon is frequency-uncorrelated with the idle one, become indistinguishable in the strong dissipation region. This offers our quantum chiral spectroscopy a great advantage over the classical chiral spectroscopy. Our work opens up an exciting area that exploring profound advantages of the quantum spectroscopy in chiral analysis

Topological Holography and Storage with Optical Knots and Links

After more than 70 years of development, holography has become an essential tool of modern optics in many applications. In fact, for various applications of different kinds of holographic techniques, stability and antijamming ability are very important. Here, optical topological structures are introduced into holographic technology, and an entirely new concept of optical topological holography is demonstrated to solve stability and antijamming problems. Based on the optical knots and links, the topological holography is not only developed in theory, but also demonstrated experimentally. In addition, a new topological holographic coding is established by regarding each knotted/linked topological structure as an information carrier. Due to the variety of knotted and linked structures and their characteristics of topological protection, such coding can have high capacity as well as robust properties. Furthermore, with writing the hologram into the liquid crystal, robust information storage of 3D topological holography is realized