3 research outputs found
Recommended from our members
Combining Process, Product and Genre on a Graduate EAP Writing Course 'Outside of the Disciplines'
In many British universities, EAP writing courses are taught 'outside of the disciplines', in a Language Centre. Learners from different disciplines are often taught together, learning generic writing skills that they are expected to apply to the specific contexts of their disciplines, often during concurrent studies. The resulting physical and conceptual separation of writing from the contexts of learning within the disciplines creates pedagogic challenges for teacher and learner alike. This article focuses on how we meet individual learners' needs on an EAP writing course by combining product, process and genre, and linking up with students' practices in their disciplines
Copolymerization of Ethylene and 1,4–Pentadiene: Structure Characterization and Reaction Mechanism
Copolymerization of ethylene and 1,4-pentadiene was conducted
by
using a homogeneous catalyst to understand the insertion mode of 1,4-pentadiene.
The polymer microstructure of the synthesized material was subjected
to structural characterization using quantitative NMR spectroscopy,
diffusometry, two-dimensional correlation spectroscopy, and selectively
refocused insensitive nuclei enhanced by polarization transfer (Sel-RINEPT).
The multimodal NMR characterization allows effective differentiation
of chain ends and backbone signals, filters irrelevant spectral information,
and provides site-specific information to achieve unambiguous structural
elucidation. The experimental results reveal that pentadiene has been
primarily converted to cis- and trans-dialkyl-substituted cyclohexane moieties along the polymer backbone
over the course of polymerization. The analysis also confirms that
unreacted pendant allyl groups from pentadiene remain at a concentration
that is significantly lower than the cyclic structures. In comparison
to the literature results, some discrepancies in structural assignment
have been identified and the results will be discussed. Detailed molecular
structure elucidation provides critical insights into advancing the
understanding of the reaction mechanism
Additional file 1: of The Objective Physical Activity and Cardiovascular Disease Health in Older Women (OPACH) Study
OPACH PA Questionnaire. (DOCX 351 kb