Design and optimization of electrochemical microreactors for continuous electrosynthesis

The study focuses on the design and construction, as well as the theoretical and experimental optimization of electrochemical filter press microreactors for the electrosynthesis of molecules with a high added value. The main characteristics of these devices are firstly a high-specific electrochemical area to increase conversion and selectivity, and secondly the shape and size of themicrochannels designed for a uniform residence time distribution of the fluid. A heat exchanger is integrated into the microstructured electrode to rapidly remove (or supply) the heat required in exo- or endothermic reactions. The microreactors designed are used to perform-specific electrosynthesis reactions such as thermodynamically unfavorable reactions (continuous NADH regeneration), or reactions with high enthalpy changes

Magnitude bias of microlensed sources towards the Large Magellanic Cloud

There are lines of evidence suggesting that some of the observed microlensing events in the direction of the Large Magellanic Cloud (LMC) are caused by ordinary star lenses as opposed to dark Machos in the Galactic halo. Efficient lensing by ordinary stars generally requires the presence of one or more additional concentrations of stars along the line of sight to the LMC disk. If such a population behind the LMC disk exists, then the source stars (for lensing by LMC disk objects) will be drawn preferentially from the background population and will show systematic differences from LMC field stars. One such difference is that the (lensed) source stars will be farther away than the average LMC field stars, and this should be reflected in their apparent baseline magnitudes. We focus on red clump stars: these should appear in the color-magnitude diagram at a few tenths of a magnitude fainter than the field red clump. Suggestively, one of the two near-clump confirmed events, MACHO-LMC-1, is a few tenths of magnitude fainter than the clump.Comment: To appear in ApJ Letters. Shortened to match the accepted version, 8 pages plus 1 ps figur

Chemical Abundance Constraints on White Dwarfs as Halo Dark Matter

We examine the chemical abundance constraints on a population of white dwarfs in the Halo of our Galaxy. We are motivated by microlensing evidence for massive compact halo objects (Machos) in the Galactic Halo, but our work constrains white dwarfs in the Halo regardless of what the Machos are. We focus on the composition of the material that would be ejected as the white dwarfs are formed; abundance patterns in the ejecta strongly constrain white dwarf production scenarios. Using both analytical and numerical chemical evolution models, we confirm that very strong constraints come from Galactic Pop II and extragalactic carbon abundances. We also point out that depending on the stellar model, significant nitrogen is produced rather than carbon. The combined constraints from C and N give $\Omega_{WD} h < 2 \times 10^{-4}$ from comparison with the low C and N abundances in the Ly$\alpha$ forest. We note, however, that these results are subject to uncertainties regarding the nucleosynthesis of low-metallicity stars. We thus investigate additional constraints from D and $^4$He, finding that these light elements can be kept within observational limits only for \Omega_{WD} \la 0.003 and for a white dwarf progenitor initial mass function sharply peaked at low mass (2$M_\odot$). Finally, we consider a Galactic wind, which is required to remove the ejecta accompanying white dwarf production from the galaxy. We show that such a wind can be driven by Type Ia supernovae arising from the white dwarfs themselves, but these supernovae also lead to unacceptably large abundances of iron. We conclude that abundance constraints exclude white dwarfs as Machos. (abridged)Comment: Written in AASTeX, 26 pages plus 4 ps figure

Microscopic correlation between chemical and electronic states in epitaxial graphene on SiC(000-1)

We present energy filtered electron emission spectromicroscopy with spatial and wave-vector resolution on few layer epitaxial graphene on SiC$(000-1) grown by furnace annealing. Low energy electron microscopy shows that more than 80% of the sample is covered by 2-3 graphene layers. C1s spectromicroscopy provides an independent measurement of the graphene thickness distribution map. The work function, measured by photoelectron emission microscopy (PEEM), varies across the surface from 4.34 to 4.50eV according to both the graphene thickness and the graphene-SiC interface chemical state. At least two SiC surface chemical states (i.e., two different SiC surface structures) are present at the graphene/SiC interface. Charge transfer occurs at each graphene/SiC interface. K-space PEEM gives 3D maps of the k_|| pi - pi* band dispersion in micron scale regions show that the Dirac point shifts as a function of graphene thickness. Novel Bragg diffraction of the Dirac cones via the superlattice formed by the commensurately rotated graphene sheets is observed. The experiments underline the importance of lateral and spectroscopic resolution on the scale of future electronic devices in order to precisely characterize the transport properties and band alignments

A New Channel for the Detection of Planetary Systems Through Microlensing: II. Repeating Events

In the companion paper we began the task of systematically studying the detection of planets in wide orbits ($a > 1.5 R_E$) via microlensing surveys. In this paper we continue, focusing on repeating events. We find that, if all planetary systems are similar to our own Solar System, reasonable extensions of the present observing strategies would allow us to detect 3-6 repeating events per year along the direction to the Bulge. Indeed, if planetary systems with multiple planets are common, then future monitoring programs which lead to the discovery of thousands of stellar-lens events will likely discover events in which several different planets within a single system serve as lenses, with light curves exhibiting multiple repetitions. In this paper we discuss observing strategies to maximize the discovery of all wide-orbit planet-lens events. We also compare the likely detection rates of planets in wide orbits to those of planets located in the zone for resonant lensing. We find that, depending on the values of the planet masses and stellar radii of the lensed sources (which determine whether or not finite source size is important), and also on the sensitivity of the photometry used by observers, the detection of planets in wide orbits may be the primary route to the discovery of planets via microlensing. We also discuss how the combination of resonant and wide-orbit events can help us to learn about the distribution of planetary system properties (S 6.1). In addition, by determining the fraction of short-duration events due to planets, we indirectly derive information about the fraction of all short-duration events that may be due to low-mass MACHOs (S 6.2).Comment: 51 pages, 7 figures. To be published in the Astrophysical Journal, 20 February 1999. This completes the introduction to the discovery of planets in wide orbits begun in astro-ph/9808075, also to appear in ApJ on 20 February 199

Coexpression, copurification, crystallization and preliminary X-ray analysis of a complex of ARL2-GTP and PDE delta

The small GTPase ARL2 (from Mus musculus) and an effector protein, the δ subunit of human cGMP phosphodiesterase (hPDE δ), were coexpressed and copurified from Escherichia coli as a stable complex. Coexpression significantly increased the otherwise low yield of PDE δ production in E. coli. The complex, which contains ARL2 in the activated GTP-bound form, was crystallized in two forms. The first belongs to the monoclinic space group P21, with unit-cell parameters a = 48.1, b = 45.7, c = 74.7 Å, β = 94.0° and one complex (39 kDa) in the asymmetric unit. Cryocooled crystals diffract to 2.3 Å using synchrotron radiation. The micro-focused X-­ray beam at beamline ID13 (ESRF) allowed the use of very small crystals, which helped to overcome twinning and enabled the identification of a molecular-replacement solution. The second form recrystallized from the first one after several months. These crystals belong to the orthorhombic space group P212121, with unit-cell parameters a = 44.5, b = 65.4, c = 104.4 Å and one complex in the asymmetric unit. They diffracted to 1.8 Å using synchrotron radiation

Asymfast, a method for convolving maps with asymmetric main beams

We describe a fast and accurate method to perform the convolution of a sky map with a general asymmetric main beam along any given scanning strategy. The method is based on the decomposition of the beam as a sum of circular functions, here Gaussians. It can be easily implemented and is much faster than pixel-by-pixel convolution. In addition, Asymfast can be used to estimate the effective circularized beam transfer functions of CMB instruments with non-symmetric main beam. This is shown using realistic simulations and by comparison to analytical approximations which are available for Gaussian elliptical beams. Finally, the application of this technique to Archeops data is also described. Although developped within the framework of Cosmic Microwave Background observations, our method can be applied to other areas of astrophysics.Comment: 9 pages, 4 figures, Phys. Rev. D, in pres