128 research outputs found

    Investigation into the Diversity of the Asia-Pacific Region and Scope for Collaboration Report on Research Project

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    千葉大学人文社会科学研究科研究プロジェクト報告書第200

    Evaluating the cascading impacts of sea level rise and coastal flooding on emergency response spatial accessibility in Lower Manhattan, New York City

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    This paper describes a scenario-based approach for evaluating the cascading impacts of sea level rise (SLR) and coastal flooding on emergency responses. The analysis is applied to Lower Manhattan, New York City, considering FEMA’s 100- and 500-year flood scenarios and New York City Panel on Climate Change (NPCC2)’s high-end SLR projections for the 2050s and 2080s, using the current situation as the baseline scenario. Service areas for different response timeframes (3-, 5- and 8-minute) and various traffic conditions are simulated for three major emergency responders (i.e. New York Police Department (NYPD), Fire Department, New York (FDNY) and Emergency Medical Service (EMS)) under normal and flood scenarios. The modelling suggests that coastal flooding together with SLR could result in proportionate but non-linear impacts on emergency services at the city scale, and the performance of operational responses is largely determined by the positioning of emergency facilities and the functioning of traffic networks. Overall, emergency service accessibility to the city is primarily determined by traffic flow speed. However, the situation is expected to be further aggravated during coastal flooding, with is set to increase in frequency and magnitude due to SLR

    Supramolecular Hydrogels from In Situ Host–Guest Inclusion between Chemically Modified Cellulose Nanocrystals and Cyclodextrin

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    When grafted β-cyclodextrin is used as targeting sites, Pluronic polymers have been introduced on the surface of cellulose nanocrystals by means of inclusion interaction between β-cyclodextrin and hydrophobic segment of the polymer. Because of the steric stabilization effect, surface poly­(ethylene glycol) chains facilitate the dispersion and compatibility of nanocrystals, which also enhance the loading levels of nanocrystals in the hydrogel system. Meanwhile, uncovered poly­(ethylene glycol) segments render the participating inclusion of α-cyclodextrin for the architecture of in situ hydrogels. Surface grafting and inclusion reactions were proved by solid <sup>13</sup>C NMR and FTIR. Grafting efficiency of β-cyclodextrin and inclusion efficiency of Pluronic on the surface of nanocrystals were confirmed by UV spectroscopy and elemental analysis. A significant enhancement of the structural and thermal stability of in situ hydrogels with high loading levels of modified nanocrystals (>5.77 wt %) was observed by rheological analysis. Further study reveals the performance and behavior of hydrogels under a different pH environment. Finally, in situ hydrogels were used as drug carrier for in vitro release of doxorubicin and exhibit the behavior of prolonged drug release with special release kinetics

    Physical and/or Chemical Compatibilization of Extruded Cellulose Nanocrystal Reinforced Polystyrene Nanocomposites

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    Impressive mechanical properties and reinforcing capability make cellulose nanocrystal (CN) a promising candidate as biomass nanofiller for the development of polymer-based nanocomposites. With the recent announcement of large-scale CN production, the use of industrial processing techniques for the preparation of CN-reinforced nanocomposites, such as extrusion, is highly required. However, low thermal stability of sulfuric acid-prepared CN limits the processing since most polymeric matrices are processed at temperatures close to 200 °C or above. It has been proved that surface adsorption of polymers on CN as compatibilizer, such as hydrophilic polyoxyethylene (PEO), can improve its thermal stability due to the shielding and wrapping of PEO. However, the weak combination between CN and PEO allows the free movement of surface polymer, which can induce the self-aggregation of CN and microphase separation in composites especially during melt processing. Using carboxylation–amidation reaction, short chains poly­(ethylene glycol) (PEG) can be first grafted on the surface of the nanocrystals, and immobilize long PEO chains on modified nanocrystals through physical adsorption and entanglement. Two polymeric layers should further improve the thermal stability of CNs, and surface polymeric chains should provide significant dispersibility and compatibilization for extruded nanocomposites. Rheological analysis showed better PEO adsorption for PEG-grafted nanocrystals than pristine CN. Results from AFM and SEM revealed homogeneous dispersion and good compatibility of modified nanocrystals in PS matrix. Finally, the thermal, mechanical, and barrier properties of ensuing nanocomposites have been investigated to study the effect of physically and/or chemically modified nanocrystals

    Coupled modeling of storm surge and coastal inundation: a case study in New York City during Hurricane Sandy

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    In this paper we describe a new method of modeling coastal inundation arising from storm surge by coupling a widely used storm surge model (ADCIRC) and an urban flood inundation model (FloodMap). This is the first time the coupling of such models is implemented and tested using real events. The method offers a flexible and efficient procedure for applying detailed ADCIRC storm surge modeling results along the coastal boundary (with typical resolution of ∼100 m) to FloodMap for fine resolution inundation modeling ( 70 m). In further testing, we explored the effects of mesh resolution and roughness specification. Results agree with previous studies that fine resolution is essential for capturing intricate flow paths and connectivity in urban topography. While the specification of roughness is more challenging for urban environments, it may be empirically optimized. The successful coupling of ADCIRC and FloodMap models for fine-resolution coastal inundation modeling unlocks the potential for undertaking large numbers of probabilistically-based synthetic surge events for street-level risk analysis
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