Supplemental Material, jmr.18.0128-File003 - Fear of Detection and Efficacy of Prevention: Using Construal Level to Encourage Health Behaviors

Supplemental Material, jmr.18.0128-File003 for Fear of Detection and Efficacy of Prevention: Using Construal Level to Encourage Health Behaviors by Chethana Achar, Nidhi Agrawal and Meng-Hua Hsieh in Journal of Marketing Research</p

Structural Variations in Novel Silver(I) Complexes with Bitopic Pyrazole/<i>N</i>-Heterocyclic Carbene Ligands

The synthesis and structural characterization of several new silver complexes of L (L = a bidendate ligand of pyrazole and N-heterocyclic carbene) are described. The result shows that the choice of counterions, N-substitutions of L, and reaction conditions are crucial which lead to a variety of structural motifs, including novel metallomacrocycles [Ag2(μ-L)2]2+ with or without Ag···Ag close contact, a mononuclear [AgL2]+ complex, and a [LAg(NO3)]n coordination polymer. In particular, the nonbonding Ag···Ag distance and the overall geometry of the metallomacrocycles are controllable with different N-substitutions and counterions. All these complexes have been determined by X-ray diffraction. The solid-state aggregates are retained in solution as supported by the electrospray mass spectroscopic studies

Structural Variations in Novel Silver(I) Complexes with Bitopic Pyrazole/<i>N</i>-Heterocyclic Carbene Ligands

The synthesis and structural characterization of several new silver complexes of L (L = a bidendate ligand of pyrazole and N-heterocyclic carbene) are described. The result shows that the choice of counterions, N-substitutions of L, and reaction conditions are crucial which lead to a variety of structural motifs, including novel metallomacrocycles [Ag2(μ-L)2]2+ with or without Ag···Ag close contact, a mononuclear [AgL2]+ complex, and a [LAg(NO3)]n coordination polymer. In particular, the nonbonding Ag···Ag distance and the overall geometry of the metallomacrocycles are controllable with different N-substitutions and counterions. All these complexes have been determined by X-ray diffraction. The solid-state aggregates are retained in solution as supported by the electrospray mass spectroscopic studies