Enhanced Long-Term Stability of Organic Electrode Materials by a Trap Filler Strategy

The sensitivity of organic electrode materials to water and oxygen has long been the bottleneck of their further development. The residual and penetrative water and oxygen in electrochemical cells form electron traps that trigger irreversible side reactions, which is detrimental to their long-term stability. A trap filler strategy by introducing molecules with low ionization energy in a cell, bis­(pentamethylcyclopentadienyl)­cobalt­(II) (DMC) as an example, is demonstrated to deactivate traps spontaneously by donating electrons to traps without causing undesirable reactions with electrode materials. The electrode materials BthCz and AQCz, with lowest unoccupied molecular orbital levels above or near the electron traps (−3.6 to −3.8 eV), exhibit conspicuous stability increment of 68.6 and 26.3%, respectively, with the optimized DMC concentration of 5 × 10–4 M in acetonitrile electrolyte

Polarized Species in an Organic Semiconductor Laser

Meeting the challenge of direct electrically driven organic semiconductor lasers (OSLs), the design of OSL materials is being studied. Polarized species generally exist in conjugated organic materials and play an important role in the photophysics procedure; therefore, understanding these species is beneficial for designing novel OSL materials. Here, we use the amplified spontaneous emission effect as a medium to reveal a carbazole-benzothiadiazole-based polarized species induced by a charge transfer process. Spectroscopic analysis confirms that this polarized species that acted as a CT pair defect has a negative influence on the ASE stability and solid state fluorescent quantum yield. This inspires us to be cautious in terms of some specific molecular group combinations when designing OSL materials

Polarized Species in an Organic Semiconductor Laser

Meeting the challenge of direct electrically driven organic semiconductor lasers (OSLs), the design of OSL materials is being studied. Polarized species generally exist in conjugated organic materials and play an important role in the photophysics procedure; therefore, understanding these species is beneficial for designing novel OSL materials. Here, we use the amplified spontaneous emission effect as a medium to reveal a carbazole-benzothiadiazole-based polarized species induced by a charge transfer process. Spectroscopic analysis confirms that this polarized species that acted as a CT pair defect has a negative influence on the ASE stability and solid state fluorescent quantum yield. This inspires us to be cautious in terms of some specific molecular group combinations when designing OSL materials

Electrocleavage Synthesis of Solution-Processed, Imine-Linked, and Crystalline Covalent Organic Framework Thin Films

Developing a general, facile, and direct strategy for synthesizing thin films of covalent organic frameworks (COFs) is a major challenge in this field. Herein, we report an unprecedented electrocleavage synthesis strategy to produce imine-linked COF films directly on electrodes from electrolyte solutions at room temperature. This strategy enables the cathodic exfoliation of the COF powders to nanosheets by electrochemical reduction and protonation, followed by nanosheets migrating to the anode and reproducing the COF structures by anodic oxidation. Our method is adaptable with most imine-linked COFs by virtue of the low redox potential of the imine bonds, whereas the COF films possess high crystallinity and hierarchical porosity. We highlight these COF films as a superb platform for promoting mass transfer by demonstrating their extraordinarily rapid iodine adsorption with record-high rate constants

Data_Sheet_1_Validation of T-MoCA in the Screening of Mild Cognitive Impairment in Chinese Patients With Atrial Fibrillation.pdf

BackgroundAtrial fibrillation (AF) is associated with a high risk of mild cognitive impairment (MCI) and dementia. However, feasible and simple instruments that facilitate the regular assessment of cognitive status in patients with AF remain underdeveloped.MethodsCognitive function was first evaluated using telephone Montreal cognitive assessment (T-MoCA), and then patients were invited for an in-person interview for cognitive assessment using both Clinical Dementia Rating (CDR) and mini-mental status evaluation (MMSE). Using CDR = 0.5 as a reference standard, the ability of T-MoCA and MMSE to discriminate cognitive dysfunction, stratified by education level, was tested by receiver–operating curve (ROC) analysis. The net reclassification index was calculated for comparison between the performance of T-MoCA and MMSE.ResultsOne hundred and one patients completed both telephone and in-person interview. Thirty-five MCI patients were identified as MCI using the criteria of CDR = 0.5. The areas under the ROC curve of T-MoCA were 0.80 (0.71–0.89), 0.83 (0.71–0.95), and 0.85 (0.64–0.92) for all patients, patients with high educational level, and patients with low education level, respectively. The optimal threshold was achieved at 16/17 with a sensitivity of 85.7% and a specificity of 69.7% in overall patients, 15/16 with a sensitivity of 88.2% and a specificity of 64.5% in the low educational level patients, and 16/17 with a sensitivity of 77.8% and a specificity of 87.9% in the high educational level patients. Compared to the criterion MMSE ≤ 27 and MMSE norms for the elderly Chinese community, the stratified T-MoCA threshold improves correct classification by 23.7% (p = 0.033) and 30.3% (p = 0.020), respectively.ConclusionT-MoCA is a feasible and effective instrument for MCI screening in patients with AF.</p