4 research outputs found
Hierarchically Structured Ni Nanotube Array-Based Integrated Electrodes for Water Splitting
The development of
high-performance nonprecious electrocatalysts
for overall water splitting has attracted increasing attention but
remains a vital challenge. Herein, we report a ZnO-based template
method to fabricate Ni nanotube arrays (NTAs) anchored on nickel foil
for applications in the hydrogen evolution reaction (HER) and oxygen
evolution reaction (OER). On the basis of this precursor electrode,
the three-dimensional NiSe<sub>2</sub> NTAs of unique sandwich-like
coaxial structure have been fabricated by electrodeposition of NiSe<sub>2</sub> on Ni NTAs, which exhibits high performance toward the HER
in both acidic and alkaline media. The method based on Ni NTAs can
be readily extended to fabricate Ni<sub>2</sub>P NTAs by gas–solid
phosphorization for the HER, and NiFeO<sub><i>x</i></sub> NTAs by anodic codeposition of Ni and Fe for the OER. Consequently,
an alkaline electrolyzer has been constructed using NiFeO<sub><i>x</i></sub> NTAs and NiSe<sub>2</sub> NTAs as anode and cathode,
respectively, which can realize overall water splitting with a current
density of 100 mA cm<sup>–2</sup> at an overpotential of 510
mV
Highly Dispersed Mo<sub>2</sub>C Nanoparticles Embedded in Ordered Mesoporous Carbon for Efficient Hydrogen Evolution
The
development of non-noble metal-based electrocatalysts for the hydrogen
evolution reaction (HER) has attracted increasing attention over recent
years. As a promising HER catalyst candidate, the preparation of molybdenum
carbide requires high temperature for carbothermal reduction, which
often causes nanoparticles sintering, leading to low exposed active
sites. In this work, highly dispersed β-Mo<sub>2</sub>C nanoparticles
of approximately 5 nm embedded in ordered mesoporous carbon (Mo<sub>2</sub>C@OMC) have been synergistically synthesized. During the synthesis
process, the resol precursor for OMC template could serve as carbon
source for the formation of Mo<sub>2</sub>C and mitigate the sintering
of Mo<sub>2</sub>C nanoparticles. The resultant well-defined Mo<sub>2</sub>C possesses highly exposed active sites of approximately 26.5%
and exhibits an excellent performance for the HER in both acidic and
alkaline solutions. The synthetic procedure developed in this study
may be extended to fabricate other metal carbide@OMC nanocomposites
for the HER and other electrocatalytic applications
N,P-Doped Molybdenum Carbide Nanofibers for Efficient Hydrogen Production
Molybdenum (Mo) carbide-based
electrocatalysts are considered promising candidates to replace Pt-based
materials toward the hydrogen evolution reaction (HER). Among different
crystal phases of Mo carbides, although Mo<sub>2</sub>C exhibits the
highest catalytic performance, the activity is still restricted by
the strong Mo–H bonding. To weaken the strong Mo–H bonding,
creating abundant Mo<sub>2</sub>C/MoC interfaces and/or doping a proper
amount of electron-rich (such as N and P) dopants into the Mo<sub>2</sub>C crystal lattice are effective because of the electron transfer
from Mo to surrounding C in carbides and/or N/P dopants. In addition,
Mo carbides with well-defined nanostructures, such as one-dimensional
nanostructure, are desirable to achieve abundant catalytic active
sites. Herein, well-defined N,P-codoped Mo<sub>2</sub>C/MoC nanofibers
(N,P-Mo<sub><i>x</i></sub>C NF) were prepared by pyrolysis
of phosphomolybdic ([PMo<sub>12</sub>O<sub>40</sub>]<sup>3–</sup>, PMo<sub>12</sub>) acid-doped polyaniline nanofibers at 900 °C
under an Ar atmosphere, in which the hybrid polymeric precursor was
synthesized via a facile interfacial polymerization method. The experimental
results indicate that the judicious choice of pyrolysis temperature
is essential for creating abundant Mo<sub>2</sub>C/MoC interfaces
and regulating the N,P-doping level in both Mo carbides and carbon
matrixes, which leads to optimized electronic properties for accelerating
HER kinetics. As a result, N,P-Mo<sub><i>x</i></sub>C NF
exhibits excellent HER catalytic activity in both acidic and alkaline
media. It requires an overpotential of only 107 and 135 mV to reach
a current density of 10 mA cm<sup>–2</sup> in 0.5 M H<sub>2</sub>SO<sub>4</sub> and 1 M KOH, respectively, which is comparable and
even superior to the best of Mo carbide-based electrocatalysts and
other noble metal-free electrocatalysts