Palladium-Catalyzed Hydrophosphorylation of Alkynes <i>via</i> Oxidative Addition of HP(O)(OR)₂

Palladium-Catalyzed Hydrophosphorylation of Alkynes via Oxidative Addition of HP(O)(OR)2</sub

The First Platinum(0)-Catalyzed Regio- and Stereoselective Thiosilylation of Alkynes Using Disulfides and Disilanes: A New Strategy for Introducing Two Different Heteroatoms into Carbon−Carbon Unsaturated Bonds

The First Platinum(0)-Catalyzed Regio- and Stereoselective Thiosilylation of Alkynes Using Disulfides and Disilanes:  A New Strategy for Introducing Two Different Heteroatoms into Carbon−Carbon Unsaturated Bond

Air-Induced <i>anti</i>-Markovnikov Addition of Secondary Phosphine Oxides and H-Phosphinates to Alkenes

Air (oxygen) induces the addition of secondary phosphine oxides and H-phosphinates to alkenes to selectively produce the corresponding anti-Markovnikov adducts in good to high yields. Mechanistic studies show that the addition probably proceeds via a radical chain mechanism

Palladium-Catalyzed Asymmetric Hydrophosphorylation of Norbornenes

By using Josiphos ligands, palladium-catalyzed hydrophosphorylation of norbornenes with hydrogen phosphonates proceeded efficiently to give the corresponding phosphonates in high enantioselectivities

Palladium-Catalyzed Hydrophosphorylation of Alkynes <i>via</i> Oxidative Addition of HP(O)(OR)₂

Palladium-Catalyzed Hydrophosphorylation of Alkynes via Oxidative Addition of HP(O)(OR)2</sub

Palladium-Catalyzed Insertion of Isocyanides into P(O)−H Bonds: Selective Formation of Phosphinoyl Imines and Bisphosphinoylaminomethanes

Palladium and rhodium catalyzed the addition of H-phosphine oxides to isocyanides to selectively generate α-iminophosphine oxides and bisphosphinoylaminomethanes, respectively

Stereospecific Addition of H−P Bond to Alkenes: A Simple Method for the Preparation of (<i>R</i>_P)-Phenylphosphinates

A variety of functionalized optically pure (RP)-alkylphenylphosphinates are readily prepared by stereospecific radical or base-catalyzed additions of the easily available (RP)-menthyl phenylphosphinate to alkenes

Supporting_information_PDF – Supplemental material for Atom-efficient chlorination of benzoic acids with PCl₃ generating acyl chlorides

Supplemental material, Supporting_information_PDF for Atom-efficient chlorination of benzoic acids with PCl3 generating acyl chlorides by Jing Xiao and Li-Biao Han in Journal of Chemical Research</p

Air-Induced <i>anti</i>-Markovnikov Addition of Secondary Phosphine Oxides and H-Phosphinates to Alkenes

Air (oxygen) induces the addition of secondary phosphine oxides and H-phosphinates to alkenes to selectively produce the corresponding anti-Markovnikov adducts in good to high yields. Mechanistic studies show that the addition probably proceeds via a radical chain mechanism

Facile Oxidative Addition of the Phosphorous−Selenium Bond to Pd(0) and Pt(0) Complexes and Development of Pd-Catalyzed Regio- and Stereoselective Selenophosphorylation of Alkynes

Facile Oxidative Addition of the Phosphorous−Selenium Bond to Pd(0) and Pt(0) Complexes and Development of Pd-Catalyzed Regio- and Stereoselective Selenophosphorylation of Alkyne